TReview lopicS] TRelerences Nitrogen dioxide, NO2, decomposes upon heating to form nitric oxide and oxygen according to the following equation: 2NO2 (9) → 2NO(9) + O2 (g) At the beginning of an experiment, the concentration of nitrogen dioxide in a reaction vessel was 0.1103 mol/L. After 69.0 s, the concentration decreased to 0.1067 mol/L. What is the average rate of decomposition of NO2 during this time interval in mol/(L-s)? Average rate = mol/(L-s)

TReview lopicS] TRelerences Nitrogen dioxide, NO2, decomposes upon heating to form nitric oxide and oxygen according to the following equation: 2NO2 (9) → 2NO(9) + O2 (g) At the beginning of an experiment, the concentration of nitrogen dioxide in a reaction vessel was 0.1103 mol/L. After 69.0 s, the concentration decreased to 0.1067 mol/L. What is the average rate of decomposition of NO2 during this time interval in mol/(L-s)? Average rate = mol/(L-s)

Chemistry for Engineering Students

4th Edition

ISBN:9781337398909

Author:Lawrence S. Brown, Tom Holme

Publisher:Lawrence S. Brown, Tom Holme

Chapter4: Stoichiometry

Section: Chapter Questions

Problem 4.87PAE

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4.65 Using the web, find out how lead “poisons” the catalyst in a catalytic converter.
A student set up an experiment for six different trials of the reaction between 1.00-M aqueous acetic acid, CH3COOH, and solid sodium hydrogen carbonate, NaHCO3. CH3COOH(aq) + NaHCO3(s) NaCH3CO2(aq) + CO2(g) + H2O() The volume of acetic acid was kept constant, but the mass of sodium bicarbonate increased with each trial. The results of the tests are shown in the figure. (a) In which trial(s) is the acetic acid the limiting reactant? (b) In which trial(s) is sodium bicarbonate the limiting reactant? (c) Explain your reasoning in parts (a) and (b).
A common demonstration in chemistry courses involves adding a tiny speck of manganese(IV) oxide to a concentrated hydrogen peroxide (H2O2) solution. Hydrogen peroxide decomposes quite spectacularly under these conditions to produce oxygen gas and steam (water vapor). Manganese(IV) oxide is a catalyst for the decomposition of hydrogen peroxide and is not consumed in the reaction. Write the balanced equation for the decomposition reaction of hydrogen peroxide.
Many cereals are made with high moisture content so that the cereal can be formed into various shapes before it is dried. A cereal product containing 58% H2O by mass is produced at the rate of 1000. kg/h. What mass of water must be evaporated per hour if the final product contains only 20.% water?
Ethanol, C2H5OH, is a gasoline additive that can be produced by fermentation of glucose. C6H12O62C2H5OH+2CO2 (a) Calculate the mass (g) of ethanol produced by the fermentation of 1.000 lb glucose. (b) Gasohol is a mixture of 10.00 mL ethanol per 90.00 mL gasoline. Calculate the mass (in g) of glucose required to produce the ethanol in 1.00 gal gasohol. Density of ethanol = 0.785 g/mL. (c) By 2022, the U. S. Energy Independence and Security Act calls for annual production of 3.6 1010 gal of ethanol, no more than 40% of it produced by fermentation of corn. Fermentation of 1 ton (2.2 103 lb) of corn yields approximately 106 gal of ethanol. The average corn yield in the United States is about 2.1 105 lb per 1.0 105 m2. Calculate the acreage (in m2) required to raise corn solely for ethanol production in 2022 in the United States.
Carbon monoxide burns readily in oxygen to form carbon dioxide. 2 CO(g) + O2(g) 2 CO2(g) The box on the left represents a tiny portion of a mixture of CO and O2. If these molecules react to form CO2, What should the contents of the box on the right look like?
list at least three quantities that must be conserved in chemical reactions.
3.88 One Step in the enrichment of uranium for use in nuclear power plants involves the reaction of UO2 with hydro- fluoric acid (HF) solution. The products are solid UF4 and water. Write a balanced chemical equation for this reaction.
The metals industry was a major source of air pollution years ago. One common process involved roasting metal sulfides in the air 2 PbS(s) + 3 O2(g) 2 PbO(s) + 2 SO2(g) If 2.50 mol of PbS is heated in air, what amount of O2 is required for complete reaction? What amounts of PbO and SO2 are expected?
4.21 Ammonium nitrate, NH4NO3, will decompose explosively to form N2, O2, and H2O, a fact that has been exploited in terrorist bombings. What mass of nitrogen is formed by the decomposition of 2.6 kg of ammonium nitrate?
DDT (molar mass = 354.49 g/mol) was a widely used insecticide that was banned from use in the United States in 1973. This ban was brought about due to the persistence of DDT in many different ecosystems, leading to high accumulations of the substance in many birds of prey. The insecticide was shown to cause a thinning of egg shells, pushing many birds toward extinction. If a 20-L drum of DDT was spilled into a pond, resulting in a DDT concentration of 8.75 105 M, how long would it take for the levels of DDT to reach a concentration of 1.41 107 M (a level that is generally assumed safe in mammals)? Assume the decomposition of DDT is a first-order process with a half-life of 56.0 days.
On Easter Sunday, April 3, 1983, nitric acid spilled from a tank car near downtown Denver, Colorado. The spill was neutralized with sodium carbonate: 2HNO3(aq)+Na2CO3(aq)2NaNO3(aq)+H2O(l)+CO2(g) a. Calculate H for this reaction. Approximately 2.0 104 gal nitric acid was spilled. Assume that the acid was an aqueous solution containing 70.0% HNO3 by mass with a density of 1.42 glcm3. What mass of sodium carbonate was required for complete neutralization of the spill, and what quantity of heat was evolved? (Hf for NaNO3(aq) = 467 kJ/mol) b. According to The Denver Post for April 4, 1983, authorities feared that dangerous air pollution might occur during the neutralization. Considering the magnitude of H, what was their major concern?

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