7. Using the values of Ka given below Acid Acetic Benzoic Carbonic H₂CO3 Chlorous Cyanic Formic Formula CH COOH C.HSCOOH Mix#1 Hydrocyanic HCN Hydrofluoric HF Mix #2 HCIO₂ Mix#1 HOCN b) pH = 1.20 Mix #2 HCOOH K₁ 1.8 x 10-5 6.5 × 10-5 Acid Kal = 4.3 x 10-7 1.1 x 10-2 Acid 2.0 × 10 1.8 x 104 4.9 × 10-10 3.5 x 104 pKa Acid Hypobromous HOBr Hypochlorous HOCI Hypoiodous HOI Oxalic Sulfurous Formula Base Base H₂C₂O4 6 HC₂04 H₂SO3 For each pH: - Pick the best two pairs of compounds that could be mixed to create a buffer of the desired pH HSO3 (Each mix must contain two complete neutral compounds, NOT JUST IONS!) State the base/acid ratio that would be needed. - For each pH, note the pair that would create the best buffer. a) pH = 3.50 K₁ 2.8 × 10⁹ 2.9 × 10-8 2.3 × 10-11 Kal = 5.9 × 10- 2 K₁2=6.4 x 10- 5 Kal = 1.7 x 10- 2 K₁2=6.4 x 10- 8 B/A Ratio B/A Ratio pKa Best? Best?

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter20: Carboxylic Acids And Nitriles
Section20.3: Biological Acids And The Henderson–hasselbalch Equation
Problem 5P: Calculate the percentages of dissociated and undissociated forms present in the following solutions:...
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c) pH = 9.00
Mix#1
Mix #2
Acid
Base
B/A
Ratio
Best?
8. What mass of sodium benzoate should you add to 150.0mL of a 0.15M benzoic
acid solution to obtain a buffer with a pH of 4.25?
Transcribed Image Text:c) pH = 9.00 Mix#1 Mix #2 Acid Base B/A Ratio Best? 8. What mass of sodium benzoate should you add to 150.0mL of a 0.15M benzoic acid solution to obtain a buffer with a pH of 4.25?
7. Using the values of Ka given below
Acid
K₁
Acetic
1.8 x 10-5
Benzoic
Carbonic
Chlorous
Cyanic
Formic
Hydrocyanic HCN
Hydrofluoric HF
Mix#1
Formula
CH₂COOH
C6H5COOH
H₂CO3
HCIO₂
Mix #2
HOCN
Mix#1
HCOOH
b) pH = 1.20
Mix #2
6.5 × 10-5
Kal = 4.3 x
10-7
1.1 x 10-2
Acid
2.0 × 10-4
Acid
1.8 x 104
4.9 × 10-10
3.5 x 104
pKa
Acid
Hypobromous HOBr
Hypochlorous HOCI
Hypoiodous
HOI
Oxalic
Sulfurous
Formula
Base
H₂C₂O4
Base
HC₂04
H₂SO3
HSO3
For each pH:
- Pick the best two pairs of compounds that could be mixed to create a buffer of the
desired pH
K₂
2.8 × 10⁹
(Each mix must contain two complete neutral compounds, NOT JUST IONS!)
State the base/acid ratio that would be needed.
- For each pH, note the pair that would create the best buffer.
a) pH = 3.50
2.9 × 10-8
2.3 × 10-11
Kal = 5.9 × 10-
2
K₁2= 6.4 x 10-
5
Kal = 1.7 x 10
2
K2=6.4 x 10-
8
B/A
Ratio
B/A
Ratio
pKa
Best?
Best?
Transcribed Image Text:7. Using the values of Ka given below Acid K₁ Acetic 1.8 x 10-5 Benzoic Carbonic Chlorous Cyanic Formic Hydrocyanic HCN Hydrofluoric HF Mix#1 Formula CH₂COOH C6H5COOH H₂CO3 HCIO₂ Mix #2 HOCN Mix#1 HCOOH b) pH = 1.20 Mix #2 6.5 × 10-5 Kal = 4.3 x 10-7 1.1 x 10-2 Acid 2.0 × 10-4 Acid 1.8 x 104 4.9 × 10-10 3.5 x 104 pKa Acid Hypobromous HOBr Hypochlorous HOCI Hypoiodous HOI Oxalic Sulfurous Formula Base H₂C₂O4 Base HC₂04 H₂SO3 HSO3 For each pH: - Pick the best two pairs of compounds that could be mixed to create a buffer of the desired pH K₂ 2.8 × 10⁹ (Each mix must contain two complete neutral compounds, NOT JUST IONS!) State the base/acid ratio that would be needed. - For each pH, note the pair that would create the best buffer. a) pH = 3.50 2.9 × 10-8 2.3 × 10-11 Kal = 5.9 × 10- 2 K₁2= 6.4 x 10- 5 Kal = 1.7 x 10 2 K2=6.4 x 10- 8 B/A Ratio B/A Ratio pKa Best? Best?
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