(a) The room temperature and pressure measured rate constants (kobs) for ligand substitution in the square planar platinum(II) complex shown below are given in the Table. By drawing an appropriate diagram to show how the reaction proceeds, explain the trend seen for kobs. Predict what would happen to kobs for chloride substitution if the reaction was performed at high pressure. +ך PENH₂ Kobs NH₂ + X N OMe H2 -NH2 ✗ Table Kobs x 103 / M¹ s¨¹ X 0.45 CH- 3.7 Br 107 I- *ך
(a) The room temperature and pressure measured rate constants (kobs) for ligand substitution in the square planar platinum(II) complex shown below are given in the Table. By drawing an appropriate diagram to show how the reaction proceeds, explain the trend seen for kobs. Predict what would happen to kobs for chloride substitution if the reaction was performed at high pressure. +ך PENH₂ Kobs NH₂ + X N OMe H2 -NH2 ✗ Table Kobs x 103 / M¹ s¨¹ X 0.45 CH- 3.7 Br 107 I- *ך
Chemistry: An Atoms First Approach
2nd Edition
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Steven S. Zumdahl, Susan A. Zumdahl
Chapter20: Transition Metals And Coordination Chemistry
Section: Chapter Questions
Problem 6Q: Four different octahedral chromium coordination compounds exist that all have the same oxidation...
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