For the reaction NH2SO2OH + H2O → NH4HSO4 In aqueous solution at 80.35oC, the following constants were observed at the indicated ionic strength μ x103 k (L/mol hr) 5.06 1.07 11.21 1.02 15.85 0.976 22.94 0.886 From these data ascertain: a.) the valence of the reacting ions and b.) the rate constant for the primary salt effect.
For the reaction NH2SO2OH + H2O → NH4HSO4 In aqueous solution at 80.35oC, the following constants were observed at the indicated ionic strength μ x103 k (L/mol hr) 5.06 1.07 11.21 1.02 15.85 0.976 22.94 0.886 From these data ascertain: a.) the valence of the reacting ions and b.) the rate constant for the primary salt effect.
Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter5: Introduction To Chemical Equilibrium
Section: Chapter Questions
Problem 5.42E
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For the reaction
NH2SO2OH + H2O → NH4HSO4
In aqueous solution at 80.35oC, the following constants were observed at the indicated ionic strength
μ x103 k (L/mol hr)
5.06 1.07
11.21 1.02
15.85 0.976
22.94 0.886
From these data ascertain:
a.) the valence of the reacting ions and
b.) the rate constant for the primary salt effect.
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