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- 2NO2(g) + F2(g) -> NO2F(g) H°rxn = -284 kJ/molrxn NO2(g) and F2(g) can reactto produce NO2F(g), as represented above. A proposed mechanism for the reaction has two elementary steps, as shown below. Step 1: NO2 + F2 -> NO2F + F (slow) Step 2: NO2 + F -> NO2F (fast) a.) Write a rate law for the overall reaction that is consistent with the proposed mechanism. b.) On the incomplete reaction energy diagram below, draw a curve that shows the following two details. The relative activation energies for the two elementary steps The enthalpy change of the overall reaction Can all of them be solved please, and thank you very much!step1) 2a--->b+c step 2) b+a---->d what is the overall reaction resulting from the mechanism.2ClO2(aq) + 2OH-(aq) ClO3-(aq) + ClO2-(aq) + H2O(l) The above reaction was studied (at a particular temperature) and the following data (for rate = -d[ClO2]/dt) were obtained: [ClO2]0 [OH-]0 Initial Rate (mol/L) (mol/L) (mol L-1 s-1) 0.170 0.170 1.43 0.340 0.085 2.87 0.340 0.170 5.74 hello, i am confused about the order of clo2 given the data above. When 1 use rate 1 and 2 given thier respective clo2 intial concentrations, i get first order for clo2, but when i use rate 1 and rate 3 and thier respective clo2 intial concentrations, i get an order of 2 for clo2. so which order is correct for clo2 given this data? first order or second order?
- In a hydrocarbon solution, the gold compound (CH3)3AUPH3 decomposes into ethane (C2H6) and a different gold compound, (CH3)AUPH3. The following mechanism has been proposed for the decomposition of (CH3)3AUPH3: Step 1: (CH3)3 AuPH; (CH3);Au + PH3 (fast) Step 2: (CH3)3 Au 4, C,H, + (CH;)Au (slow) Step 3: (CH3)Au + PH3 (CH3)AUPH3 (fast) (a) What is the overall reaction? (b) What are the inter- mediates in the mechanism? (c) What is the molecular- ity of each of the elementary steps? (d) What is the rate- determining step? (e) What is the rate law predicted by this mechanism? (f) What would be the effect on the reac- tion rate of adding PH3 to the solution of (CH3)3AUPH3?Which of the following is the rate determining step for this reaction: HBr Tui H-Br Br: A OA B C D O O O O Br: B C DOutline a detailed mechanism for the reaction below. Identify the abbreviation for the reaction mechanism. OH H PO4
- Which molecule is a reaction intermediate in the mechanism of the reaction shown below? a. OH 人士 O b. O O d. l 1. OH MgBr (2 equiv.) 2. H3O+a) Balance the reaction formula for the following reaction: CH3COOH + 2C5H2O → 2C5H11OCOCH3 + H2O b) Draw your own reaction mechanism for the reaction.Explain the steps of the mechanism of reaction
- The activation energy for the gas phase decomposition of t-butyl bromide is 170 kJ.(CH3)3CBr(CH3)2C=CH2 + HBrThe rate constant at 523 K is 0.000209 /s. The rate constant will be ?????? /s at 565 K.please write de materials for the steps 1-4 , for the step 4 please show also de mechanism. please write de answer indicating the arrows to be able to understand better the mechanism, and the name of the reactions, thank youFirst three sub-parts are solved Rate information was obtained for the following reaction at 25°C and 33°C; Cr(H2O)6 3+ + SCN¯ ---> Cr(H2O)5NCS2+ + H2O(l) Initial Rate [Cr(H2O)6 3+] [SCN-] @ 25°C 2.0x10-11 1.0x10-4 0.10 2.0x10-10 1.0x10-3 0.10 9.0x10-10 2.0x10-3 0.15 2.4x10-9 3.0x10-3 0.20 @ 33°C 1.4x10-10 1.0x10-4 0.20 a) Write a rate law consistent with the experimental data. b) What is the value of the rate constant at 25°C? c) What is the value of the rate constant at 33°C? d) What is the activation energy for this reaction? e) Can a 4th order reaction occur?