. A third spectrophotometric method for the quantitative analysis of Pb in blood yields an Ssamp Of 0.193 when a 1.00 mL sample of blood is diluted to 5.00 mL. A second 1.00 mL sample of blood is spiked with 1.00 µL of a 1560-ppb Pb external standard and diluted to 5.00 mL yielding an Sapike of 0.419. What is the concentration of Pb in the original sample of blood?
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- A second spectrophotometric method for the quantitative analysis of Pb2+ in blood yields an Ssamp of 0.712 for a 5.00 mL sample of blood. After spiking the blood sample with 5.00 μL of a 1560 ppb Pb2+ external standard, an Sspike of 1.546 is measured. What is the concentration of Pb2+ in the original sample of blood?3c. A solution containing 2.50 mM X (analyte) and 1.20 mM S (standard) gave peak areas of 2509 and 7132 respectively, in a chromatographic analysis. Then, 1.00 mL of 6.00 mM S was added to 5.00 mL of unknown X and the mixture was diluted to 10.0 mL. This solution gave peak areas of 4016 and 3138 for X and S, respectively. Calculate i. the response factor for the analyte ii. the concentration of S (mM) in the 10.0 mL of mixed solutioniii. the concentration of X (mM) in the 10.0 mL of mixed solutioniv. the concentration of X in the original unknown solutionA spectrophotometric method for the quantitative determination of the concentration ofPb2+ in blood yields an Ssamp of 0.133 for a 1 mL sample of blood that has been diluted to 6 mL. A second sample is spiked with 1 µL of a 1467 ppb Pb2+ standard and diluted to 6 mL, yielding an Sspike of 0.491. Determine the concentration of Pb2+ in the original sample of blood.
- Internal standard. A solution containing 3.47 mM X (analyte) and 1.72 mM S (standard) gave peak areas of 3 473 and 10 222, respectively, in a chromatographic analysis. Then 1.00 mL of 8.47 mM S was added to 5.00 mL of unknown X, and the mixed solution was diluted to 10.0 mL. This solution gave peak areas of 5 428 and 4 431 for X and S, respectively. (a) Find the response factor for X relative to S in Equation 5-9. (b) Find [S] (mM) in the 10.0 mL of mixed solution. (c) Find [X] (mM) in the 10.0 mL of mixed solution.(d) Find [X] in the original unknown.Internal standard (As , Cs ), analyte with known concentration (Ax , Cx ) In a chromatographic equipment, a solution containing 0.006727 X and 0.008331 M S give peak area of Ax= 2316 and As= 207. To analyze an unknown sample, 5.0mL of 0.008331M S was added to 5.0mL of X, and the mixture was diluted to 50.0mL. This mixture gave a chromatography spectrum with area Ax= 3206 and As= 200. Find Cx.A freshwater sample containing Ca2+ and Mg2+ will be analyzed using EDTA titration. The EDTA titrant was standardized by dissolving 0.5005g of CaCO3 (99.00% purity) in 100.0mL. A 10.00-mL aliquot was then titrated using 24.93 mL of EDTA titrant to the Eriochrome Black T endpoint. A sample with a volume of 250.00 mL is titrated with 20.32 mL of the EDTA titrant in an ammonia buffer at pH 10.00. Another 250.00 mL sample was then treated with NaOH to precipitate Mg(OH)2 and was then titrated at pH 13.00 with 10.43 mL using the same EDTA solution. FW: CaCO3 (100.09 g/mol) & MgCO3 (84.314 g/mol) Questions: Find concentration of EDTA titrant in M. Calculate the Amount of CaCO3 and MgCO3 in the sample. Express your answers in moles and ppm of each compound.
- A freshwater sample containing Ca2+ and Mg2+ will be analyzed using EDTA titration. The EDTA titrant was standardized by dissolving 0.5005g of CaCO3 (99.00% purity) in 100.0mL. A 10.00-mL aliquot was then titrated using 24.93 mL of EDTA titrant to the Eriochrome Black T endpoint. A sample with a volume of 250.00 mL is titrated with 20.32 mL of the EDTA titrant in an ammonia buffer at pH 10.00. Another 250.00 mL sample was then treated with NaOH to precipitate Mg(OH)2 and was then titrated at pH 13.00 with 10.43 mL using the same EDTA solution. FW: CaCO3 (100.09 g/mol) & MgCO3 (84.314 g/mol) a. What is the concentration of the EDTA titrant? b. Calculate the Amount of CaCO3 and MgCO3 in the sample. Express your answers in ppm of each compound. mol Ca2+ = _____ mol mol Mg2+ = _____ mol [Ca2+] = ______ ppm CaCO3 [Mg2+] = ______ ppm CaCO3A freshwater sample containing Ca2+ and Mg2+ will be analyzed using EDTA titration. The EDTA titrant was standardized by dissolving 0.5005g of CaCO3 (99.00% purity) in 100.0mL. A 10.00-mL aliquot was then titrated using 24.93 mL of EDTA titrant to the Eriochrome Black T endpoint. A sample with a volume of 250.00 mL is titrated with 20.32 mL of the EDTA titrant in an ammonia buffer at pH 10.00. Another 250.00 mL sample was then treated with NaOH to precipitate Mg(OH)2 and was then titrated at pH 13.00 with 10.43 mL using the same EDTA solution. FW: CaCO3 (100.09 g/mol) & MgCO3 (84.314 g/mol) c. What is the total hardness of the water sample expressed as ppm CaCO3. Total hardness = ____ ppm CaCO34- A sample containing H2C204 had a purity equal to 90.50% (w/w). An unknown mass of this sample was dissolved in water and transferred to a 50.00 mL flask. An aliquot of 25.00 mL was transferred to an erlenmeyer flask and 50.00 mL of a 0.2000 mol L^-1 NaOH solution were added. %3 Excess NaOH was titrated with 0.09000 mol L^-1 HCI solution using 2.000 mL. Calculate the mass (g) of the sample used. Data: H = 1.008 C= 12.01 O = 16.00
- A freshwater sample containing Ca2+ and Mg2+ will be analyzed using EDTA titration. The EDTA titrant was standardized by dissolving 0.5005g of CaCO3 (99.00% purity) in 100.0mL. A 10.00-mL aliquot was then titrated using 24.93 mL of EDTA titrant to the Eriochrome Black T endpoint. A sample with a volume of 250.00 mL is titrated with 20.32 mL of the EDTA titrant in an ammonia buffer at pH 10.00. Another 250.00 mL sample was then treated with NaOH to precipitate Mg(OH)2 and was then titrated at pH 13.00 with 10.43 mL using the same EDTA solution. FW: CaCO3 (100.09 g/mol) & MgCO3 (84.314 g/mol) a. What is the concentration of the EDTA titrant?In a chromatography experiment, a solution containing 0.083 7 M X and 0.066 6 M S gave peak areas of AX = 423 and AS 5 347. (Areas are measured in arbitrary units by the instrument.) To analyze the unknown, 10.0 mL of 0.146 M S were added to 10.0 mL of unknown, and the mixture was diluted to 25.0 mL in a volumetric flask. This mixture gave the chromatogram in Figure 5-8, with peak areas AX = 553 and AS = 582. Find the concentration of X in the unknown.A freshwater sample containing Ca2+ and Mg2+ will be analyzed using EDTA titration. The EDTA titrant was standardized by dissolving 0.5005g of CaCO3 (99.00% purity) in 100.0mL. A 10.00-mL aliquot was then titrated using 24.93 mL of EDTA titrant to the Eriochrome Black T endpoint. A sample with a volume of 250.00 mL is titrated with 20.32 mL of the EDTA titrant in an ammonia buffer at pH 10.00. Another 250.00 mL sample was then treated with NaOH to precipitate Mg(OH)2 and was then titrated at pH 13.00 with 10.43 mL using the same EDTA solution. FW: CaCO3 (100.09 g/mol) & MgCO3 (84.314 g/mol) Question: What is the concentration of EDTA titrant in M?