3. The first reaction is not stereoselective. Draw only the R isomer (A) and then reduce the carbonyl with Red Al (B). Draw the structure of A and B. OTMS TiCl4 H Mukaiyama Rxn 1. RedAl 2. Acid workup A B

3. The first reaction is not stereoselective. Draw only the R isomer (A) and then reduce the carbonyl with Red Al (B). Draw the structure of A and B. OTMS TiCl4 H Mukaiyama Rxn 1. RedAl 2. Acid workup A B

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter14: Elimination

Section: Chapter Questions

Problem 16E

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Concept explainers

Alkanes and Cycloalkanes

Alkanes are saturated organic compounds which are made up of C and H atoms. Alkanes have the general formula of CnH2n+2. Alkane contains sp3 hybridized carbon atoms with four sigmas (σ) bonds & every hydrogen atom is connected with one of the carbon atoms. The size of the alkane could be determined by the number of carbon atoms located in it.

Question

3. The first reaction is not stereoselective. Draw only the R isomer (A) and then reduce the
carbonyl with Red Al (B). Draw the structure of A and B.
OTMS
H
TiCl4
Mukaiyama Rxn
1. RedAl
2. Acid workup
A
B

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