Using infrared spectroscopy, how can salicylic acid be difterentiated trom acetylsalicylic acid (aspirin)? Acetylsalicylic acid will have two carbonyl (C=O) stretches at approximately 1) 1700 cm1. It will possess one C=O stretch at about 1680 cm-1 for the carboxyl group which is present in both and one unique carbonyl stretch at 1725 cm 1 for the ester functional group. Salicylic acid will have two carbonyl (C=O) stretches at approximately 1700 2) cm. It will possess one C=O stretch at about 1680 cm for the carboxyl group which is present in both and one unique carbonyl stretch at 1725 cm1 for the ester functional group. 3) Acetylsalicylic acid and salicylic acid cannot be differentiated via IR spectroscopy as they have all the same stretches present. 4) Salicylic acid will have a unique aliphatic sp3-hybridized C-H at approximately 3150-3050 cm

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter12: Structure Determination: Mass Spectrometry And Infrared Spectroscopy
Section12.SE: Something Extra
Problem 42AP: The mass spectrum (a) and the infrared spectrum (b) of another unknown hydrocarbon are shown....
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Using infrared spectroscopy, how can salicylic acid be differentiated from
acetylsalicylic acid (aspirin)?
Acetylsalicylic acid will have two carbonyl (C=O) stretches at approximately
1)
1700 cm1. It will possess one C=O stretch at about 1680 cm1 for the
carboxyl group which is present in both and one unique carbonyl stretch at
1725 cm 1
for the ester functional group.
ст
Salicylic acid will have two carbonyl (C=O) stretches at approximately 1700
2)
cm. It will possess one C=O stretch at about 1680 cm for the carboxyl
group which is present in both and one unique carbonyl stretch at 1725 cm1
for the ester functional group.
3) Acetylsalicylic acid and salicylic acid cannot be differentiated via IR
spectroscopy as they have all the same stretches present.
3
4) Salicylic acid will have a unique aliphatic sp-hybridized C-H at approximately
3150-3050 cm 1.
Transcribed Image Text:Using infrared spectroscopy, how can salicylic acid be differentiated from acetylsalicylic acid (aspirin)? Acetylsalicylic acid will have two carbonyl (C=O) stretches at approximately 1) 1700 cm1. It will possess one C=O stretch at about 1680 cm1 for the carboxyl group which is present in both and one unique carbonyl stretch at 1725 cm 1 for the ester functional group. ст Salicylic acid will have two carbonyl (C=O) stretches at approximately 1700 2) cm. It will possess one C=O stretch at about 1680 cm for the carboxyl group which is present in both and one unique carbonyl stretch at 1725 cm1 for the ester functional group. 3) Acetylsalicylic acid and salicylic acid cannot be differentiated via IR spectroscopy as they have all the same stretches present. 3 4) Salicylic acid will have a unique aliphatic sp-hybridized C-H at approximately 3150-3050 cm 1.
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