Essential Organic Chemistry (3rd Edition)
3rd Edition
ISBN: 9780321937711
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 10.4, Problem 9P
Interpretation Introduction
Interpretation:
The mass spectra of 1-chloropropane has to be drawn.
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Sketch the mass spectrum expected for 1-chloropropane.
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What molecular ions will be present in a mass spectrum of 2-chloropropane,(CH3)2CHCl ?
Chapter 10 Solutions
Essential Organic Chemistry (3rd Edition)
Ch. 10.1 - Prob. 1PCh. 10.2 - What would distinguish the mass spectrum of...Ch. 10.2 - Prob. 3PCh. 10.3 - Prob. 5PCh. 10.3 - Suggest possible molecular formulas for a compound...Ch. 10.3 - Prob. 7PCh. 10.4 - Prob. 8PCh. 10.4 - Prob. 9PCh. 10.5 - Prob. 10PCh. 10.5 - Prob. 11P
Ch. 10.6 - Identify the ketone responsible for the mass...Ch. 10.6 - Prob. 13PCh. 10.8 - Prob. 14PCh. 10.8 - Prob. 15PCh. 10.12 - Which will occur at a larger wavenumber: a. a C :...Ch. 10.13 - Which will occur at a larger wavenumber: a. the C...Ch. 10.13 - Prob. 18PCh. 10.13 - Prob. 19PCh. 10.13 - Which will show an O 8 H stretch at a larger...Ch. 10.14 - Prob. 21PCh. 10.14 - Prob. 22PCh. 10.15 - Prob. 23PCh. 10.15 - Prob. 24PCh. 10.17 - Prob. 25PCh. 10.18 - Prob. 26PCh. 10.18 - Prob. 27PCh. 10.19 - Prob. 28PCh. 10.19 - Prob. 29PCh. 10.22 - How many signals would you expect to see in the 1H...Ch. 10.22 - Prob. 31PCh. 10.22 - Prob. 32PCh. 10.23 - Where would you expect to find the 1H NMR signal...Ch. 10.24 - Prob. 34PCh. 10.25 - Prob. 35PCh. 10.25 - Prob. 36PCh. 10.25 - Prob. 37PCh. 10.26 - Prob. 38PCh. 10.26 - Which of the following compounds is responsible...Ch. 10.27 - Prob. 40PCh. 10.27 - Prob. 41PCh. 10.27 - The 1H NMR spectra of two carboxylic acids with...Ch. 10.28 - Prob. 43PCh. 10.28 - Prob. 44PCh. 10.28 - Prob. 45PCh. 10.28 - Describe the 1H NMR spectrum you would expect for...Ch. 10.28 - Identify the compound with molecular formula...Ch. 10.29 - Prob. 48PCh. 10.29 - Prob. 49PCh. 10.29 - Identify the compound with a molecular formula of...Ch. 10 - In the mass spectrum of the following compounds,...Ch. 10 - For each of the following pairs of compounds,...Ch. 10 - Draw the structure of a saturated hydrocarbon that...Ch. 10 - Prob. 54PCh. 10 - Prob. 55PCh. 10 - How could you use UV spectroscopy to distinguish...Ch. 10 - Prob. 57PCh. 10 - Predict the relative intensities of the molecular...Ch. 10 - Prob. 59PCh. 10 - List the following compounds in order from highest...Ch. 10 - How can 1H NMR be used to prove that the addition...Ch. 10 - There are four esters with molecular formula...Ch. 10 - Prob. 63PCh. 10 - Prob. 64PCh. 10 - Each of the IR spectra presented here is...Ch. 10 - Prob. 66PCh. 10 - Five compounds are shown for each of the following...Ch. 10 - Prob. 68PCh. 10 - Prob. 69PCh. 10 - Phenolphthalein is an acidbase indicator. In...Ch. 10 - Which one of the following five compounds produced...Ch. 10 - Prob. 72PCh. 10 - Prob. 73PCh. 10 - Prob. 74PCh. 10 - How could 1H NMR distinguish between the compounds...Ch. 10 - Prob. 76PCh. 10 - Prob. 77PCh. 10 - The 1H NMR spectra of three isomers with molecular...Ch. 10 - The 1H NMR spectra of three isomers with molecular...Ch. 10 - Identify the following compounds. (Relative...Ch. 10 - An alkyl halide reacts with an alkoxide ion to...Ch. 10 - Determine the structure of a compound with...
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- There is mass spectrum. What is the molecule compound name?arrow_forwardDefine Mass spectrum of 2-chloropropane [(CH3)2CHCl]arrow_forwardIs the compound giving rise to the mass spectrum shown here more likely to contain sulfur, bromine, or chlorine? Explain. 100 80 - 60- 40 20 40 80 120 160 m/z Relative abundance -유arrow_forward
- c) The mass spectrum of 2,3-dibromopentane (CH; CHBr CHBr CH₂ CH3) includes the following peaks. Mass number (m/z) Relative abundance 15 29 107 109 199 201 203 i. What is the mass number of molecular ion, [CH; CHBr CHBr CH₂ CH₂]? Show your working. ii. Identify the molecular formula (including isotopic composition where relevant) of the 6 peaks. a b d 22 e f Mass number (m/z) 15 29 107 109 199 100 39 44 45 0.3 0.6 0.3 201 203 Molecule formula [CH₂]arrow_forwardThe following figure shows the mass spectrum of a hydrocarbon. i. Propose a molecular formula for this compound assuming that the molecular ion can be detected. ii. Draw the structural formulae of all possible isomers of this hydrocarbon.arrow_forwardBriefly explain the principles of APCI mass spectrometryarrow_forward
- Using the rule of 13, what is a possible formula for M=113 (100%) on a mass spectrum? all of the above are possible molecular formulas CH130 CH15Narrow_forwardWhich of the following compounds gives this mass spectrum and explain why it is so?arrow_forwardMass spectrometry is often used to both identify and quantify compounds. What is different between mass spectra with changing concentrations of a compound? How would you design a method (i.e. what would you need) to both identify and quantify a compound using mass spectrometry?arrow_forward
- The molecular weight of compound D is calculated to be 359.22 g/mol., However, the mass spectrum contains two peakS, with m/z 358.02 and m/z @360.02, in a approximately a 1:1 ratio. Explain this observation. HTML Editorgarrow_forward4. Halogenated compounds are particularly easy to identify by their mass spectra because chlorine and bromine occur naturally as mixtures of two abundant isotopes. Chlorine occurs as "CI (75.8%) and "CI (24.2%). Ignore the presence of "C isotopes. For the compound, C,H,Cl;: a) At what masses do the molecular ions occur? b)What are the percentages of cach molecular ion?arrow_forwardExplain what can be determined from the following mass spectrum. M* = 123 Relative Intensity 100- 80 9 20 0-mmm 25 50 wytrwytatyt||||||qqıbıkm 75 m/7 100 125arrow_forward
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