Organic Chemistry
4th Edition
ISBN: 9780073402772
Author: Janice G. Smith
Publisher: MCG
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Textbook Question
Chapter 11, Problem 11.4P
Give the structures corresponding to each of the following names.
a.
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4d. polysubstituted benzene
HO-
O2N
NO2
NH2
NO2
What is the IUPAC name for the molecule shown?
0₂N
0000
3-ethoxy-1-nitrocyclohexane
1-ethoxy-3-nitrohexane
1-ethoxy-3-nitrocyclohexane
1-ethoxy-3-nitrohexane
c. 2-hexene +HCI/H₂O →
d. 3-methyl-1-pentyne + 2 moles HCI/H₂O →
Chapter 11 Solutions
Organic Chemistry
Ch. 11 - Draw structures for the three alkynes having...Ch. 11 - Prob. 11.2PCh. 11 - Give the IUPAC name for each compound.Ch. 11 - Give the structures corresponding to each of the...Ch. 11 - Prob. 11.5PCh. 11 - Prob. 11.6PCh. 11 - Which bases can deprotonate acetylene? The pKa...Ch. 11 - Draw the organic products formed when each alkyne...Ch. 11 - Prob. 11.9PCh. 11 - Problem 11.9 Draw the products formed when is...
Ch. 11 - Explain the following result. Although alkenes...Ch. 11 - Problem 11.11 Draw the keto tautomer of each...Ch. 11 - Prob. 11.13PCh. 11 - a Draw two different enol tautomers of...Ch. 11 - Prob. 11.15PCh. 11 - Prob. 11.16PCh. 11 - Prob. 11.17PCh. 11 - Problem. 11.17 Show how , and can be used to...Ch. 11 - Prob. 11.19PCh. 11 - Draw the products of each reaction. a. b.Ch. 11 - Prob. 11.21PCh. 11 - Problem 11.21 Use retrosynthetic analysis to show...Ch. 11 - Prob. 11.23PCh. 11 - Give the IUPAC name for each compound. a. b.Ch. 11 - Prob. 11.25PCh. 11 - 11.25 Answer the following questions about...Ch. 11 - Prob. 11.27PCh. 11 - Give the IUPAC name for each alkyne.Ch. 11 - Prob. 11.29PCh. 11 - Which of the following pairs of compounds...Ch. 11 - Prob. 11.31PCh. 11 - 11.30 How is each compound related to A? Choose...Ch. 11 - Prob. 11.33PCh. 11 - Prob. 11.34PCh. 11 - Prob. 11.35PCh. 11 - 11.33 Draw the products formed when is treated...Ch. 11 - Draw the products formed when 3-hexyne is treated...Ch. 11 - Prob. 11.38PCh. 11 - Prob. 11.39PCh. 11 - What alkynes give each of the following ketones as...Ch. 11 - Prob. 11.41PCh. 11 - 11.37 What alkyne gives each compound as the only...Ch. 11 - Prob. 11.43PCh. 11 - Draw the structure of compounds A-E in the...Ch. 11 - Prob. 11.45PCh. 11 - Prob. 11.46PCh. 11 - 11.42 What reactions are needed to convert alcohol...Ch. 11 - Prob. 11.48PCh. 11 - Prob. 11.49PCh. 11 - 11.45 Explain the following statement. Although ...Ch. 11 - Draw a stepwise mechanism for the following...Ch. 11 - Prob. 11.52PCh. 11 - Prob. 11.53PCh. 11 - Prob. 11.54PCh. 11 - Prob. 11.55PCh. 11 - Synthesize each compound from acetylene. You may...Ch. 11 - Prob. 11.57PCh. 11 - Prob. 11.58PCh. 11 - 11.55 Devise a synthesis of the ketone, , from ...Ch. 11 - 11.56 Devise a synthesis of each compound using ...Ch. 11 - Prob. 11.61PCh. 11 - Prob. 11.62PCh. 11 - 11.60 Draw a stepwise mechanism for the following...Ch. 11 - Draw a stepwise mechanism for the following...Ch. 11 - Prob. 11.65PCh. 11 - Write a stepwise mechanism for each of the...Ch. 11 - Prob. 11.67PCh. 11 - 11.65 Explain why an optically active solution of ...
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- What is the name of the structure shown. O a. 3-propyl-6-ethylcyclohept-1-yne O b. 7-allyl-4-ethylcyclohept-1-yne O c. 3-allyl-6-ethylcyclohept-1-yne O d. 3-propyl-6-ethylcyclohept-1-enearrow_forwardGive the IUPAC name for the chemical in the attached image. [click on attachment to view image if you don't see it] CH3CH₂CH₂CH₂CHCH₂CH₂CH₂CH3 CH3CH₂CH₂ O A. 2,2,5,6-tetraethylhexane B. 2,2,5-triethyloctane O C. 3,6-diethyl-3-methylnonane CH₂CH3 D. 3-ethyl-3-methyl-6-propyldecane CH3arrow_forwarda. The following compounds have the same molecular formula as benzene. How many monobrominated products could each form? 1. HC‚CC‚CCH2CH3 2. CH2“CHC‚CCH“CH2 b. How many dibrominated products could each of the preceding compounds form? (Do not include stereoisomers.) c. How many dibrominated products could each of the compounds form if stereoisomers are included?arrow_forward
- What is the IUPAC name for the following compound? CH₂CH₂ C CH3-CH₂-CH-CH₂-CH-CH-CH-CH₂ CI CH3 Select one: O A. 3,7-dichloro-5-ethyl-6-methyloctane O B. 2-chloro-3-methyl-4-(2-chlorobutyl) hexane O C. 2,6-dichloro-4-ethyl-3-methyloctane O D. 3-chloro-5-(2-chloro-1-methylpropyl) heptane OE. 2,3,4,6-dichloroethylmethyoctanearrow_forwardWhich of the following names are/is incorrect? O 3-Methyl-2-ethylcyclohexene All 6-Ethylcycloheptene O 1-Methylcyclopent-2-ene O 1-Methylpent-1-enearrow_forwardWhat is the general molecular formula of an acyclic alkane? a) CnHzn c) C₂H₂n-2 b) C,Hzn+z d) CH20-4arrow_forward
- a. What hydrocarbon with molecular formula C4H10 forms only two monochlorinated products? Both products are achiral. b. What hydrocarbon with the same molecular formula as in part a forms three monochlorinated products? One is achiral and two are chiral.arrow_forward2 H3C H₂ CH H₂C. CH₂ CH3 6-chloro-4-ethyl-3-hexanone 4-chloroethyl-3-hexanone 4-ethyl-6-chloro-3-hexanone 6-chloro-3-octanonearrow_forwardWhich of the following reagents would be used as a chemical test for the presence of alkenes and alkynes? O a. Br2 O b. H2O О с. HCl O d. CH3OHarrow_forward
- Which compound is a structural isomer of the following organic compound? Н Н HH Н-c-c-o-С-С I Н Н НН CH3 H3C HHHH ТТТ н-с-с-с-с-OH IIII нннн SH CH3 CH3 0 0 Oc Н3С O+ H3C. Н Н нннн о н-с-с-с-с-с-н ННННarrow_forwardProvide the correct IUPAC name for the compound shown here. SEP 27 3- Delete H₂C. CH3 tv CH₂ CH3 -CH₂ CH3 4- 6- 1- 2- 5- di cyclo iso tri tert- sec- hept pent eth hex meth prop ene ane yne yl A 33159 ))) Warrow_forwardPhenol + Br2/H2Oarrow_forward
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