Principles of Instrumental Analysis
Principles of Instrumental Analysis
7th Edition
ISBN: 9781305577213
Author: Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher: Cengage Learning
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Chapter 12, Problem 12.5QAP
Interpretation Introduction

Interpretation:

Thickness of nickel foil required for the transmission of 35.8 % power of incident beam

of Cu kα line needs to be calculated where 8.90g/cm3 is the density of nickel. And the mass absorption coefficient of nickel is 49.2 cm2/g measured by Cu kα line.

Concept introduction:

Beer’s law will be used for the calculation of thickness of Ni foil. This formula is given as-

lnPoP=μMρx

Where,

Po= transmitted beam power

P = incident beam power

µM = mass absorption coefficient

ρ = density

x = sample thickness

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The mass absorbtion coefficient for Ni measured with Cu kalpha lines is 49.2 cm2 /g Calculate the thickness of a nickel foil that was found to transmit 47.8% of the incident power of a beam of Cu k alpha radiation The density of Ni is 8.90g/cm2.
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A 0.1860 g rock sample containing an unknown amount of Ca was dissolved in HCI and diluted to 100.0 mL. Aliquots of 5.00 mL from this solution were added to different volumes of a 2.08 µg/mL. Ca standard solution and diluted to 200.0 mL. The emission intensity of these solutions was measured using atomic emission spectroscopy. The results are shown in the table. Unknown volume (mL) Standard volume (mL) Final volume (mL) Emission Intensity 0.00 200.0 5.00 200.0 10.00 200.0 15.00 200.0 20.00 200.0 Find the weight percent of Ca in the rock sample and its uncertainty using the method of standard additions. weight percent: 5.00 5.00 5.00 5.00 5.00 8.27 x10-5 Incorrect % Ca .03 Incorrect 227.0 413.0 637.0 831.01 1021.0
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