It should be identified for the unprepared compounds by using the Heck reaction. Concept introduction: Suzuki reaction: A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent . Heck reaction: A reaction that breaks the double bond of an alkene and then joins the fragments .

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Answer 1

Question

Chapter 12, Problem 36P

(a)

Interpretation Introduction

Interpretation:

It should be identified for the unprepared compounds by using the Heck reaction.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

(b)

Interpretation Introduction

Interpretation:

The starting material and the suitable compound should be identified which can be prepared from Heck reaction.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

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Q2. Classify the following reactions to: 1. Wagner- Meerwein rearrangement 2. Pinacolic Rearrangement 3. Beckmann Rearrangement 4. Baeyer-Villiger Rearrangement 5. Wolff Rearrangement H,SO4 1. OH OH Ag(I) 2. NO NO OH H,SO4 NH 3. OH H;C, H,SO, + H,O H 4. H;C CH, CH3 HO H,SO4 5. OH OH NH,OH H,SO4 NH 6. A

Which of the following compounds cannot be prepared by a Heck reaction? a. For those compounds that can be prepared by a Heck reaction, what starting materials are required?

a. Which of the following compounds cannot be prepared by a Heck reaction?b. For those compounds that can be prepared by a Heck reaction, what starting materials are required?

Answer 2

Question

Chapter 12, Problem 36P

(a)

Interpretation Introduction

Interpretation:

It should be identified for the unprepared compounds by using the Heck reaction.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

(b)

Interpretation Introduction

Interpretation:

The starting material and the suitable compound should be identified which can be prepared from Heck reaction.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Expert Solution & Answer

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Answer 3

Question

Chapter 12, Problem 36P

(a)

Interpretation Introduction

Interpretation:

It should be identified for the unprepared compounds by using the Heck reaction.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

(b)

Interpretation Introduction

Interpretation:

The starting material and the suitable compound should be identified which can be prepared from Heck reaction.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Expert Solution & Answer

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See solution

Answer 4

Question

Chapter 12, Problem 36P

(a)

Interpretation Introduction

Interpretation:

It should be identified for the unprepared compounds by using the Heck reaction.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

(b)

Interpretation Introduction

Interpretation:

The starting material and the suitable compound should be identified which can be prepared from Heck reaction.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Expert Solution & Answer

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Answer 5

Chapter 12, Problem 36P

(a)

Interpretation Introduction

Interpretation:

It should be identified for the unprepared compounds by using the Heck reaction.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

(b)

Interpretation Introduction

Interpretation:

The starting material and the suitable compound should be identified which can be prepared from Heck reaction.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Answer 6

Chapter 12, Problem 36P

(a)

Interpretation Introduction

Interpretation:

It should be identified for the unprepared compounds by using the Heck reaction.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Answer 7

Chapter 12, Problem 36P

(a)

Interpretation Introduction

Interpretation:

It should be identified for the unprepared compounds by using the Heck reaction.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The starting material and the suitable compound should be identified which can be prepared from Heck reaction.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The starting material and the suitable compound should be identified which can be prepared from Heck reaction.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 12.1 - Prob. 1P Ch. 12.2 - Which is more reactive an organolithium compound...Ch. 12.2 - Prob. 3P Ch. 12.3 - PROBLEM 6♦ Explain why tertiary alkyl halides...Ch. 12.3 - Muscalure is the sex attractant of the common...Ch. 12.3 - Prob. 8P Ch. 12.3 - Prob. 9P Ch. 12.3 - Prob. 10P Ch. 12.4 - Prob. 13P Ch. 12.4 - Prob. 14P

Solution Summary: The author explains that Suzuki reaction couples an aryl halide with an Organoboron reagent. Heck reaction breaks the double bond of an alkene and joins the fragments.

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Chapter 12 Solutions