EBK ORGANIC CHEMISTRY-PRINT COMPANION (
4th Edition
ISBN: 9781119776741
Author: Klein
Publisher: WILEY CONS
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Chapter 12, Problem 50PP
Interpretation Introduction
Interpretation: The
Concept introduction: Oxidation takes place because of the removal of electrons whereas reduction takes place as a result of the addition of electrons. The oxidized component becomes positively charged and the reduced component becomes negatively charged.
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In the following reaction, determine whether the alkyne has been oxidized, reduced, or neither. (Hint: First look at each carbon atom separately and then look at the net change for
the alkyne as a whole.) Try to determine the answer without calculating oxidation states and then use the calculations to see if your intuition was correct.
H2SO4, H2O
H9SO4
The first carbon atom (with two added bonds to O) has been oxidized and the second carbon atom (with two added bonds to H) has also been oxidized. Overall, the alkyne
has been oxidized.
The first carbon atom (with two added bonds to O) has been reduced and the second carbon atom (with two added bonds to H) has also been reduced. Overall, the alkyne
has been reduced.
The first carbon atom (with two added bonds to O) has been oxidized and the second carbon atom (with two added bonds to H) has been reduced. Overall, the alkyne does
not undergo a net change in oxidation state and is, therefore, neither reduced nor oxidized.
The first carbon…
When you react ammonia with a halogenated alkane, will you get only one organic product? Why or why not? (I am not concerned or talking about inorganic products.)
Why does Hammett Equation only apply to meta and para substituted rings and not others? Explain
Chapter 12 Solutions
EBK ORGANIC CHEMISTRY-PRINT COMPANION (
Ch. 12.1 - Prob. 1LTSCh. 12.1 - Prob. 1PTSCh. 12.1 - Prob. 2ATSCh. 12.1 - Prob. 3CCCh. 12.2 - Prob. 4CCCh. 12.3 - Prob. 8CCCh. 12.3 - Prob. 9CCCh. 12.4 - Prob. 3LTSCh. 12.4 - Prob. 10PTSCh. 12.4 - Prob. 11ATS
Ch. 12.4 - Prob. 4LTSCh. 12.4 - Prob. 12PTSCh. 12.4 - Prob. 13ATSCh. 12.6 - Prob. 14CCCh. 12.6 - Prob. 5LTSCh. 12.6 - Prob. 15PTSCh. 12.6 - Prob. 16PTSCh. 12.7 - Prob. 18CCCh. 12.9 - Prob. 6LTSCh. 12.9 - Prob. 19PTSCh. 12.9 - Prob. 20ATSCh. 12.9 - Prob. 21CCCh. 12.10 - Prob. 7LTSCh. 12.10 - Prob. 22PTSCh. 12.10 - Prob. 23ATSCh. 12.13 - Prob. 8LTSCh. 12.13 - Prob. 24PTSCh. 12.13 - Prob. 25ATSCh. 12.13 - Prob. 26CCCh. 12.13 - Prob. 9LTSCh. 12.13 - Prob. 27PTSCh. 12.13 - Prob. 28ATSCh. 12 - Prob. 29PPCh. 12 - Prob. 30PPCh. 12 - Prob. 31PPCh. 12 - Prob. 32PPCh. 12 - Prob. 33PPCh. 12 - Prob. 34PPCh. 12 - Prob. 35PPCh. 12 - Prob. 36PPCh. 12 - Prob. 37PPCh. 12 - Prob. 38PPCh. 12 - Prob. 39PPCh. 12 - Prob. 40PPCh. 12 - Prob. 41PPCh. 12 - Prob. 42PPCh. 12 - Prob. 43PPCh. 12 - Prob. 44PPCh. 12 - Prob. 45PPCh. 12 - Prob. 46PPCh. 12 - Prob. 47PPCh. 12 - Prob. 48PPCh. 12 - Prob. 49PPCh. 12 - Prob. 50PPCh. 12 - Prob. 51PPCh. 12 - Prob. 52PPCh. 12 - Prob. 53ASPCh. 12 - Prob. 54ASPCh. 12 - Prob. 55ASPCh. 12 - Prob. 62IPCh. 12 - Prob. 64IPCh. 12 - Prob. 65IPCh. 12 - Prob. 66IPCh. 12 - Prob. 67IPCh. 12 - Prob. 68IPCh. 12 - Prob. 69IPCh. 12 - Prob. 74IP
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