Chapter 14, Problem 14E.1P

(a)

Interpretation Introduction

The $\pi$ value for ${\left({\text{CH}}_{\text{2}}\right)}_{\text{6}}{\text{CH}}_{\text{3}}$ has to be predicted.

Interpretation:

Concept introduction:

Micelle is a type of aggregates which is formed by surfactants.  The surfactant molecules have two parts one polar and another nonpolar part.  The polar part is a hydrophilic and nonpolar part is hydrophobic.  The shape of micelles depends on the concentration of surfactants and nature of the medium.  The hydrophobic part has hydrophobic interaction with other molecules.

(b)

Interpretation Introduction

Interpretation:

The graph of $\log K_1$ against $\pi$ has to be drawn.  Whether the relation is linear or not has to be identified. The slope and intercept on the $\log K_1$ axis have to be stated when the plot is linear relationship.

Concept introduction:

As mentioned in the concept introduction in part (a).

(c)

Interpretation Introduction

Interpretation:

The value of $K_1$ for the case of $\text{R}=\text{H}$ in the compound $\left(6\right)$ has to be calculated.

Concept introduction:

As mentioned in the concept introduction in part (a).