Organic Chemistry (9th Edition)
9th Edition
ISBN: 9780321971371
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 14.12, Problem 14.24P
Interpretation Introduction
Interpretation: The mechanism for the formation of the cyclised intermediate as shown in figure
Concept introduction: Steps for writing a correct mechanism are shown below.
- The atoms that contain double bond or those containing cations act as electrophiles.
- The atoms with lone pair act as nucleophiles.
- Identify the electrophiles site in the given compound.
- Draw the arrow starting from the correct site and ending at the correct site.
To determine: The mechanism for the formation of the cyclised intermediate as shown in figure
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
The overall reactants in Equation 8-3 are R
and
ucts are Nu-R and L. The carbocation (R*) that appears in the reaction mecha-
nism (Equation 8-2) is the only intermediate.
In the S1 mechanism shown here, (a) identify each species as an overall
reactant, overall product, or intermediate, then (b) sum the steps to yield the
overall reaction.
:Br:
+ Br:
11
:I:
+
One reason to distinguish intermediates from overall reactants and products is to
know which species in the mechanism can be isolated.
W
2:47 AM
K
61°F Clear
10/21/2021
mechanism's for this reaction
C.
Ph
CH3
CH3
steps
OH
H3C
'N'
Ph
H
On
Show the mechanism of that
ои
Br 2
Моде
њ
Br
Lon
-Br
reaction
Chapter 14 Solutions
Organic Chemistry (9th Edition)
Ch. 14.2C - Rank the given solvents in decreasing order of...Ch. 14.2D - Prob. 14.2PCh. 14.2D - In the presence of 18-crown-6, potassium...Ch. 14.3B - Give a common name (when possible) and a...Ch. 14.3C - Prob. 14.5PCh. 14.3C - Name the following heterocyclic ethers.Ch. 14.4 - Propose a fragmentation to account for each...Ch. 14.5 - Prob. 14.8PCh. 14.5 - Prob. 14.9PCh. 14.6 - Prob. 14.10P
Ch. 14.7 - Explain why bimolecular condensation is a poor...Ch. 14.7 - Prob. 14.12PCh. 14.7 - Prob. 14.13PCh. 14.8 - Prob. 14.14PCh. 14.8 - Prob. 14.15PCh. 14.8 - Prob. 14.16PCh. 14.10A - Prob. 14.17PCh. 14.10A - Prob. 14.18PCh. 14.10B - Prob. 14.19PCh. 14.11B - Show how you would accomplish the following...Ch. 14.11B - Prob. 14.21PCh. 14.12 - Prob. 14.22PCh. 14.12 - Prob. 14.23PCh. 14.12 - Prob. 14.24PCh. 14.13 - Prob. 14.25PCh. 14.13 - Prob. 14.26PCh. 14.14 - Prob. 14.27PCh. 14.15 - Give the expected products of the following...Ch. 14 - Write structural formulas for the following...Ch. 14 - Give common names for the following compounds. a....Ch. 14 - Give IUPAC names for the following compounds. a....Ch. 14 - Glycerol (propane-1,2,3-triol) is a viscous syrup...Ch. 14 - Prob. 14.33SPCh. 14 - Show how you would make the following ethers,...Ch. 14 - (A true story.) An inexperienced graduate student...Ch. 14 - Prob. 14.36SPCh. 14 - a. Show how you would synthesize the pure (R)...Ch. 14 - a. Predict the values of m/z and the structures of...Ch. 14 - The following reaction resembles the...Ch. 14 - Prob. 14.40SPCh. 14 - Prob. 14.41SPCh. 14 - Prob. 14.42SPCh. 14 - Give the structures of the intermediates...Ch. 14 - Prob. 14.44SPCh. 14 - Show how you would synthesize the following ethers...Ch. 14 - Prob. 14.46SPCh. 14 - Prob. 14.47SPCh. 14 - Prob. 14.48SPCh. 14 - An acid-catalyzed reaction was carried out using...Ch. 14 - Propylene oxide is a chiral molecule. Hydrolysis...Ch. 14 - Prob. 14.51SPCh. 14 - Prob. 14.52SPCh. 14 - Prob. 14.53SPCh. 14 - Prob. 14.54SPCh. 14 - In 2012, a group led by Professor Masayuki Satake...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- In an SN2 mechanism, how does it work, what are all of the steps, transition state and all final products?arrow_forwardAfter running various experiments, you determine that the mechanism for the following reaction is bimolecular. CI <+ + OH + CI Using this information, draw the correct mechanism in the space below. Cl. Add/Remove step X 5 C Click and drag to start drawing a structure.arrow_forwardComplicated reaction mechanisms can be broken down into elementary steps. For each elementary step shown below, add arrows to show electron movement. i Add mechanism arrows. Harrow_forward
- What are the major products? Please show the mechanismarrow_forwardGive the reaction mechanism for the following subparts in clear handwritten!arrow_forwardCH4 Cl2 CH3CI + HCI > What are the three discrete steps in the mechanism of the chlorination reaction pictured above? Give your answer in the box below in this format: Step 1, Step 2, Step 3arrow_forward
- I want the mechanism for this “Nef reaction”arrow_forwardcollege level chemistry, image attached. order of reactions, 1st or 2nd order + explain, show all workarrow_forwardStep 3: Complete the structure and add curved arrows. Select Draw Templates More / 3 H C acetal 2° gem-diol hemiacetal O 1° gem-diol H : 0 H H Erase 2 Q Select the choice that best describes the final structure. 11 Step 4: Complete the structure. Select Draw Templates More G C H O H 1 H H Erase Q 2 Qarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
Organic Chemistry: A Guided Inquiry
Chemistry
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Cengage Learning