Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Textbook Question
Chapter 15, Problem 20Q
Consider the following two acids:
pKa1 = 2.98; pKa2 = 13.40
HO2CCH2CH2CH2CH2CO2H
Adipic acid
pKa1 = 4.41; pKa2 = 5.28
In two separate experiments the pH was measured during the titration of 5.00 mmol of each acid with 0.200 M NaOH. Each experiment showed only one stoichiometric point when the data were plotted. In one experiment the stoichiometric point was at 25.00 mL added NaOH, and in the other experiment the stoichiometric point was at 50.00 mL NaOH. Explain these results.
Expert Solution & Answer
Trending nowThis is a popular solution!
Students have asked these similar questions
There are many organic acids and bases in our cells, and their presence modifies the pH of the fluids inside them. It is useful to be able to assess the pH of solutions of acids and bases and to make inferences from measured values of the pH. A solution of equal concentrations of lactic acid and sodium lactate was found to have pH= 3.08. (a) What are the values of pKa and Ka of lactic acid? (b) What would the pH be if the acid had twice the concentration of the salt?
After removing the membranes from an eggshell, the shell is dried and its mass recorded as 5.613 g. The eggshell is transferred to a 250-mL beaker and dissolved in 25 mL of 6M HCl. After filtering, the solution containing the dissolved eggshell is diluted to 250 mL in a volumetric flask. A 10.00-mL aliquot is placed in a 125-mL Erlenmeyer flask and buffered to a pH of 10. Titrating with 0.04988 M EDTA requires 44.11 mL to reach the end point. Determine the amount of calcium in the eggshells as % w/w CaCO3.
You are supplied with the following:
NaCl (Mr = 58.443 g/mol)
2.5 M Tris-Cl, pH 8 oplossing / solution (1 Litre)
EDTA, sodium salt (Mr = 380.2 g/mol)
10 % Sodium dodecyl sulfate solution
Proteinase K solution (50 mg dissolved in 1 ml ddH2O)
You need a digestion buffer consisting of the following:
15 mM NaCl
75 mM Tris-Cl, pH 8
16 mM EDTA, pH 8
0.8 % Sodium dodecyl sulfate
0.75 mg/ml proteinase K
Calculate:
How will you prepare 500 ml of the digestion buffer? Show all your steps and calculations and remember to explain how exactly you will make it up.
Chapter 15 Solutions
Chemistry
Ch. 15 - What is meant by the presence of a common ion? How...Ch. 15 - Define a buffer solution. What makes up a buffer...Ch. 15 - One of the most challenging parts of solving...Ch. 15 - A good buffer generally contains relatively equal...Ch. 15 - Draw the general titration curve for a strong acid...Ch. 15 - Instead of the titration of a strong acid by a...Ch. 15 - Sketch the titration curve for a weak acid...Ch. 15 - Sketch the titration curve for a weak base...Ch. 15 - What is an acidbase indicator? Define the...Ch. 15 - Why does an indicator change from its acid color...
Ch. 15 - What are the major species in solution after...Ch. 15 - A friend asks the following: Consider a buffered...Ch. 15 - Mixing together solutions of acetic acid and...Ch. 15 - Sketch two pH curves, one for the titration of a...Ch. 15 - Sketch a pH curve for the titration of a weak acid...Ch. 15 - You have a solution of the weak acid HA and add...Ch. 15 - You have a solution of the weak acid HA and add...Ch. 15 - The common ion effect for weak acids is to...Ch. 15 - Prob. 12QCh. 15 - A best buffer has about equal quantities of weak...Ch. 15 - Consider the following pH curves for 100.0 mL of...Ch. 15 - An acid is titrated with NaOH. The following...Ch. 15 - Consider the following four titrations. i. 100.0...Ch. 15 - Figure 14-4 shows the pH curves for the titrations...Ch. 15 - Acidbase indicators mark the end point of...Ch. 15 - Consider the titration of 100.0 mL of 0.10 M...Ch. 15 - Consider the following two acids: pKa1 = 2.98;...Ch. 15 - How many of the following are buffered solutions?...Ch. 15 - Which of the following can be classified as buffer...Ch. 15 - A certain buffer is made by dissolving NaHCO3 and...Ch. 15 - A buffer is prepared by dissolving HONH2 and...Ch. 15 - Calculate the pH of each of the following...Ch. 15 - Calculate the pH of each of the following...Ch. 15 - Compare the percent dissociation of the acid in...Ch. 15 - Compare the percent ionization of the base in...Ch. 15 - Calculate the pH after 0.020 mole of HCl is added...Ch. 15 - Calculate the pH after 0.020 mole of HCl is added...Ch. 15 - Calculate the pH after 0.020 mole of NaOH is added...Ch. 15 - Calculate the pH after 0.020 mole of NaOH is added...Ch. 15 - Which of the solutions in Exercise 21 shows the...Ch. 15 - Prob. 34ECh. 15 - Calculate the pH of a solution that is 1.00 M HNO2...Ch. 15 - Calculate the pH of a solution that is 0.60 M HF...Ch. 15 - Calculate the pH after 0.10 mole of NaOH is added...Ch. 15 - Calculate the pH after 0.10 mole of NaOH is added...Ch. 15 - Calculate the pH of each of the following buffered...Ch. 15 - Calculate the pH of each of the following buffered...Ch. 15 - Calculate the pH of a buffered solution prepared...Ch. 15 - A buffered solution is made by adding 50.0 g NH4Cl...Ch. 15 - Calculate the pH after 0.010 mole of gaseous HCl...Ch. 15 - Calculate the pH after 0.15 mole of solid NaOH is...Ch. 15 - Some K2SO3 and KHSO3 are dissolved in 250.0 mL of...Ch. 15 - An aqueous solution contains dissolved C6H5NH3Cl...Ch. 15 - Calculate the mass of sodium acetate that must be...Ch. 15 - What volumes of 0.50 M HNO2 and 0.50 M NaNO2 must...Ch. 15 - Consider a solution that contains both C5H5N and...Ch. 15 - Calculate the ratio [NH3]/[NH4+] in...Ch. 15 - Carbonate buffers are important in regulating the...Ch. 15 - When a person exercises, muscle contractions...Ch. 15 - Consider the acids in Table 13-2. Which acid would...Ch. 15 - Consider the bases in Table 13-3. Which base would...Ch. 15 - Calculate the pH of a solution that is 0.40 M...Ch. 15 - Calculate the pH of a solution that is 0.20 M HOCl...Ch. 15 - Which of the following mixtures would result in...Ch. 15 - Which of the following mixtures would result in a...Ch. 15 - What quantity (moles) of NaOH must be added to 1.0...Ch. 15 - Calculate the number of moles of HCl(g) that must...Ch. 15 - Consider the titration of a generic weak acid HA...Ch. 15 - Sketch the titration curve for the titration of a...Ch. 15 - Consider the titration of 40.0 mL of 0.200 M HClO4...Ch. 15 - Consider the titration of 80.0 mL of 0.100 M...Ch. 15 - Consider the titration of 100.0 mL of 0.200 M...Ch. 15 - Consider the titration of 100.0 mL of 0.100 M...Ch. 15 - Lactic acid is a common by-product of cellular...Ch. 15 - Repeat the procedure in Exercise 61, but for the...Ch. 15 - Repeat the procedure in Exercise 61, but for the...Ch. 15 - Repeat the procedure in Exercise 61, but for the...Ch. 15 - Calculate the pH at the halfway point and at the...Ch. 15 - In the titration of 50.0 mL of 1.0 M methylamine,...Ch. 15 - You have 75.0 mL of 0.10 M HA. After adding 30.0...Ch. 15 - A student dissolves 0.0100 mole of an unknown weak...Ch. 15 - Two drops of indicator HIn (Ka = 1.0 109), where...Ch. 15 - Methyl red has the following structure: It...Ch. 15 - Potassium hydrogen phthalate, known as KHP (molar...Ch. 15 - A certain indicator HIn has a pKa of 3.00 and a...Ch. 15 - Which of the indicators in Fig. 14-8 could be used...Ch. 15 - Prob. 80ECh. 15 - Which of the indicators in Fig. 14-8 could be used...Ch. 15 - Prob. 82ECh. 15 - Estimate the pH of a solution in which bromcresol...Ch. 15 - Estimate the pH of a solution in which crystal...Ch. 15 - A solution has a pH of 7.0. What would be the...Ch. 15 - A solution has a pH of 4.5. What would be the...Ch. 15 - When a diprotic acid, H2A. is titrated with NaOH,...Ch. 15 - Consider die titration of 50.0 mL of 0.10 M H3A...Ch. 15 - Derive an equation analogous to the...Ch. 15 - a. Calculate the pH of a buffered solution that is...Ch. 15 - Tris(hydroxymethyl)aminomethane, commonly called...Ch. 15 - You make 1.00 L of a buffered solution (pH = 4.00)...Ch. 15 - You have the following reagents on hand: Solids...Ch. 15 - Prob. 94AECh. 15 - Phosphate buffers are important in regulating the...Ch. 15 - When a diprotic acid, H2A, is titrated with NaOH,...Ch. 15 - Consider the blood buffer system discussed in the...Ch. 15 - What quantity (moles) of HCl(g) must be added to...Ch. 15 - Prob. 99AECh. 15 - The following plot shows the pH curves for the...Ch. 15 - Calculate the volume of 1.50 102 M NaOH that must...Ch. 15 - Prob. 102AECh. 15 - A certain acetic acid solution has pH = 2.68....Ch. 15 - A 0.210-g sample of an acid (molar mass = 192...Ch. 15 - The active ingredient in aspirin is...Ch. 15 - One method for determining the purity of aspirin...Ch. 15 - A student intends to titrate a solution of a weak...Ch. 15 - A student titrates an unknown weak acid, HA, to a...Ch. 15 - A sample of a certain monoprotic weak acid was...Ch. 15 - The pigment cyanidin aglycone is one of the...Ch. 15 - Consider 1.0 L of a solution that is 0.85 M HOC6H5...Ch. 15 - What concentration of NH4Cl is necessary to buffer...Ch. 15 - Consider the following acids and bases: HCO2H Ka =...Ch. 15 - Consider a buffered solution containing CH3NH3Cl...Ch. 15 - Consider the titration of 150.0 mL of 0.100 M HI...Ch. 15 - Consider the titration of 100.0 mL of 0.100 M HCN...Ch. 15 - Consider the titration of 100.0 mL of 0.200 M...Ch. 15 - Consider the following four titrations (iiv): i....Ch. 15 - Another way to treat data from a pH titration is...Ch. 15 - A buffer is made using 45.0 mL of 0.750 M HC3H5O2...Ch. 15 - A 0.400-M solution of ammonia was titrated with...Ch. 15 - What volume of 0.0100 M NaOH must be added to 1.00...Ch. 15 - Consider a solution formed by mixing 50.0 mL of...Ch. 15 - Cacodylic acid, (CH3)2AsO2H, is a toxic compound...Ch. 15 - The titration of Na2CO3 with HCl bas the following...Ch. 15 - Consider the titration curve in Exercise 115 for...Ch. 15 - A few drops of each of the indicators shown in the...Ch. 15 - Malonic acid (HO2CCH2CO2H) is a diprotic acid. In...Ch. 15 - A buffer solution is prepared by mixing 75.0 mL of...Ch. 15 - A 10.00-g sample of the ionic compound NaA, where...Ch. 15 - Calculate the pH of a solution prepared by mixing...Ch. 15 - Consider a solution prepared by mixing the...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Write down the structure of glutamic acid in each pH range from acidic to basic. It is known that pKa1 = 2.5 pKa2 = 3.5 pKa3 = 8.7 and draw the titration curve of glutamic acid titrated with a strong base, such as NaOH.arrow_forwardI would need help with these problems, please show step by step: 1. A beaker containing 500.0 mL was determined to contain 0.150 M ammonia (NH3) and 0.150 M ammonium chloride NH4 To this solution was added 50.0 mL of 0.15 M hydrochloric acid (HCl). What was the change in pH of the ammonia, ammonium ion solution? 2. Calculate the isoelectric and isoionic pH of 0.010 M threonine? pK1 = 2.15, pK2 = 9.12 3. Find the pH of a 1.00 L aqueous solution containing 12.43 g of tris (FM 121.14) plus 4.67 g of tris hydrochloride ( FM 157.60) ? What would be the new pH after adding 12.0 mL of 1.00 M NaOH to this buffer?arrow_forwardConsider the titration of 50.00 ml of a solution of 0.2574 M of the fully protonated form of the diprotic amino acid glycine (pKa1 = 2.34, pKa2 = 9.60) with 0.3786 M KOH. What is the pH after the addition of 33.99 mL of the KOH solution?arrow_forward
- The first step in the procedure asks you to prepare five dilutions of the protein standard (BSA) in the range of 0.2 to 1.0 mg/ml. For each concentration, a volume of 1.0 mL should be prepared. Describe how you will prepare these standards using a stock solution of BSA that is 2.0 mg/ml.arrow_forwardAfter removing the membranes from an eggshell, the shell is dried and its mass recorded as 5.613 g. The eggshell is transferred to a 250-mL beaker and dissolved in 25 mL of 6 M HCl. After filtering, the solution containing the dissolved eggshell is diluted to 250 mL in a volumetric flask. A 10.00-mL aliquot is placed in a 125-mL Erlenmeyer flask and buffered to a pH of 10. Titrating with 0.04988 M EDTA requires 44.11 mL to reach the end point. Determine the amount of calcium in the eggshell as %w/w CaCO3.arrow_forwardI would need help with these questions step by step: Calculate the isoelectric and isoionic pH of 0.010 M threonine? pK1 = 2.15, pK2 = 9.12 Find the pH of a 1.00 L aqueous solution containing 12.43 g of tris (FM 121.14) plus 4.67 g of tris hydrochloride ( FM 157.60) ? What would be the new pH after adding 12.0 mL of 1.00 M NaOH to this buffer?arrow_forward
- I was given an excellent explanation to the following question, but I don't understand one part of the expert answer. Why is the concentration ratio the same for the calculation of pKa2? "The pKa values of a compound with two ionizable groups are pK1 =4.10 and pK2 between 7 and 10. A biochemist has 10 mL of a 1.0 M solution of this compound at a pH of 8.00. She adds 10.0 mL of1.00 M HCl, which changes the pH to 3.20. What is pK2?" I included the original answer. Thank you very much for your help.arrow_forwardGiven that C6H11COOH has a pKa = 4.8 and C6H11N + H3 has a pKa = 10.7, what pH would you make the water layer to cause both compounds to dissolve in it?arrow_forwardGiven a solution of 0.0025 M HC2H3O2, Ka = 1.8 x 10^-5 a. Calculate the pH of the solution. b. Calculate pKa. c. Calculate the Kb value for C2H3O2-.arrow_forward
- An unknown sample containing mixed alkali (naoh, nahco3, or na2co3) was analyzed using the double flask method. a 250 mg sample was dissolved in 250 ml co2 free water. a 20.0 ml aliquot of this sample required 11.3 ml of 0.009125 m hcl solution to reach the phenolphthalein end point. another 29.0 ml aliquot of the sample was titrated to the bromocresol green endpoint using 31.1 ml of the standard acid. how many millimoles of the components are there in the original solid samplearrow_forwardWrite the reaction of PCl5 with heavy water.arrow_forwardMola and Rity were tasked to analyze the acidity of a 10.0-mL fermented milk sample diluted with water in a 250-mL volumetric flask. Mola obtained a 15.0-mL aliquot of this solution, diluted it to 50.0 mL, and then titrated this diluted sample. Titration data were given to Rity and she found out that the 50.0-mL diluted sample contains 0.21 mmol of lactic acid. MW: Lactic Acid (90.08) Follow proper significant figure rulesa. What is the lactic acid concentration (in M) of the titrated sample? b. Determine the lactic acid content (in M) of the 10.0-mL fermented milk sample. c. What is the lactic acid concentration (in %w/v) of the 10.0-mL fermented milk sample?arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY
Acid-base Theories and Conjugate Acid-base Pairs; Author: Mindset;https://www.youtube.com/watch?v=hQLWYmAFo3E;License: Standard YouTube License, CC-BY
COMPLEXOMETRIC TITRATION; Author: Pikai Pharmacy;https://www.youtube.com/watch?v=EQxvY6a42Dw;License: Standard Youtube License