Organic Chemistry
12th Edition
ISBN: 9781118875766
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Textbook Question
Chapter 17, Problem 18P
Give an IUPAC systematic or common name for each of the following compounds:
(a)
(b)
(c)
(d)
(e)
(f)
(g)
(h)
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Students have asked these similar questions
Phenylethanol can be oxidised to phenylethanal or phenylethanoic acid, depending
on the reagents used (both the alcohol and the aldehyde are of interest for their
antimicrobial properties, while the acid is used to treat type II hyperammonemia):
A
(a)
(b)
(c)
CoH,CH,CHO
phenylethanal
B
C6H5CH₂CH₂OHC₂H₂CH₂CO₂H
phenylethanol
Suggest reagents (shown as A and B in the scheme above) that could be
used to carry out the oxidation of the alcohol to the aldehyde and the acid,
respectively.
C6H5CH₂-
Suggest two other syntheses of phenylethanoic acid, in each case indicating
the starting materials and other reagents required, but not giving details of
mechanism. One of your proposed syntheses must start with a compound
which only contains seven carbon atoms (the acid product contains eight
carbon atoms).
phenylethanoic acid
Phenylethanal can be converted to a hydrate in the presence of aqueous
acid, though the position of equilibrium is very far to the left:
H
H+/H₂O
OH
C6H5CH₂-C-H
OH
Explain why…
Write IUPAC names for these compounds.
(a)
Cl
(b)
(c)
NO2
COOH
COOH
OH
Name the following using IUPAC system of nomenclature:
(a) CH2 (Cl) CH (NH2) CHO
(b) CH3 C (Br) CH2 CH (F) COOH
Br
Chapter 17 Solutions
Organic Chemistry
Ch. 17 - Practice Problem 17.1 Give an IUPAC systematic...Ch. 17 - Prob. 2PPCh. 17 - Practice Problem 17.3 Write structural formulas...Ch. 17 - Practice Problem 17.4
Show how each of the...Ch. 17 - Practice Problem 17.5
Show how you could prepare...Ch. 17 - Practice Problem 17.6
(a) Which of the carboxylic...Ch. 17 - Prob. 7PPCh. 17 - Prob. 8PPCh. 17 - Practice Problem 17.9
Esters can also be...Ch. 17 - Prob. 10PP
Ch. 17 - Prob. 11PPCh. 17 - Practice Problem 17.12
What products would you...Ch. 17 - Practice Problem 17.13 (a) Provide the reagents...Ch. 17 - Prob. 14PPCh. 17 - Practice Problem 17.15 Using decarboxylation...Ch. 17 - Practice Problem 17.16 Diacyl peroxides, ,...Ch. 17 - Prob. 17PCh. 17 - Give an IUPAC systematic or common name for each...Ch. 17 - Prob. 19PCh. 17 - Prob. 20PCh. 17 - 17.21 What major organic product would you expect...Ch. 17 - Prob. 22PCh. 17 - Prob. 23PCh. 17 - Prob. 24PCh. 17 - Prob. 25PCh. 17 - 17.26 What products would you expect to obtain...Ch. 17 - Write structural formulas for the major organic...Ch. 17 - 17.28 Indicate reagents that would accomplish each...Ch. 17 - Write structural formulas for the major organic...Ch. 17 - Prob. 30PCh. 17 - Prob. 31PCh. 17 - Prob. 32PCh. 17 - 17.33 On heating,...Ch. 17 - Prob. 34PCh. 17 - Prob. 35PCh. 17 - 17.36 Show how pentanoic acid can be prepared from...Ch. 17 - 17.37 The active ingredient of the insect...Ch. 17 - Prob. 38PCh. 17 - Prob. 39PCh. 17 - Give stereochemical formulas for compounds AQ:...Ch. 17 - 17.41 -Glyceraldehyde can be transformed into...Ch. 17 - Prob. 42PCh. 17 - Prob. 43PCh. 17 - 17.44 Given here are the NMR spectra and carbonyl...Ch. 17 - 17.45 Compound Y dissolves slowly when warmed...Ch. 17 - Prob. 46PCh. 17 - Prob. 47PCh. 17 - Prob. 48PCh. 17 - Prob. 49PCh. 17 - Prob. 50PCh. 17 - Prob. 51PCh. 17 - 17.52 Starting with 1-naphthol, suggest an...Ch. 17 - Suggest a synthesis of ibuprofen (Section 5.11)...Ch. 17 - Prob. 54PCh. 17 - Prob. 55PCh. 17 - Prob. 1LGPCh. 17 - Prob. 2LGPCh. 17 - Prob. 3LGPCh. 17 - Prob. 4LGP
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