The validation corresponding to the fact that the synthesis of m − ethylbenzenesulfonic acid using Friedel-Crafts alkylation of benzenesulfonic acid is successful or not is to be predicted. The alternative synthesis is to be proposed in the case of an unsuccessful reaction. Concept introduction: Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride (Lewis acid). This alkylation reaction comes under the category of electrophilic aromatic substitution.

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Answer 1

Question

Chapter 17.16B, Problem 17.46P

Interpretation Introduction

Interpretation:

The validation corresponding to the fact that the synthesis of m−ethylbenzenesulfonic acid using Friedel-Crafts alkylation of benzenesulfonic acid is successful or not is to be predicted. The alternative synthesis is to be proposed in the case of an unsuccessful reaction.

Concept introduction:

Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride (Lewis acid). This alkylation reaction comes under the category of electrophilic aromatic substitution.

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provide a possible synthesis for the following reaction

To synthesize m-ethylbenzenesulfonic acid, a student attempted the Friedel–Crafts alkylation of benzenesulfonic acid with bromoethane. Do you predict that this reaction was successful? If not, propose an alternative synthesis.

Please explain the synthesis. Identify SN1, SN2, E1, E2, nucleophiles and ekectrophiles.

Answer 2

Question

Chapter 17.16B, Problem 17.46P

Interpretation Introduction

Interpretation:

The validation corresponding to the fact that the synthesis of m−ethylbenzenesulfonic acid using Friedel-Crafts alkylation of benzenesulfonic acid is successful or not is to be predicted. The alternative synthesis is to be proposed in the case of an unsuccessful reaction.

Concept introduction:

Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride (Lewis acid). This alkylation reaction comes under the category of electrophilic aromatic substitution.

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Answer 3

Question

Chapter 17.16B, Problem 17.46P

Interpretation Introduction

Interpretation:

The validation corresponding to the fact that the synthesis of m−ethylbenzenesulfonic acid using Friedel-Crafts alkylation of benzenesulfonic acid is successful or not is to be predicted. The alternative synthesis is to be proposed in the case of an unsuccessful reaction.

Concept introduction:

Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride (Lewis acid). This alkylation reaction comes under the category of electrophilic aromatic substitution.

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Answer 4

Question

Chapter 17.16B, Problem 17.46P

Interpretation Introduction

Interpretation:

The validation corresponding to the fact that the synthesis of m−ethylbenzenesulfonic acid using Friedel-Crafts alkylation of benzenesulfonic acid is successful or not is to be predicted. The alternative synthesis is to be proposed in the case of an unsuccessful reaction.

Concept introduction:

Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride (Lewis acid). This alkylation reaction comes under the category of electrophilic aromatic substitution.

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Answer 5

Chapter 17.16B, Problem 17.46P

Interpretation Introduction

Interpretation:

The validation corresponding to the fact that the synthesis of m−ethylbenzenesulfonic acid using Friedel-Crafts alkylation of benzenesulfonic acid is successful or not is to be predicted. The alternative synthesis is to be proposed in the case of an unsuccessful reaction.

Concept introduction:

Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride (Lewis acid). This alkylation reaction comes under the category of electrophilic aromatic substitution.

Answer 6

Chapter 17.16B, Problem 17.46P

Interpretation Introduction

Interpretation:

The validation corresponding to the fact that the synthesis of m−ethylbenzenesulfonic acid using Friedel-Crafts alkylation of benzenesulfonic acid is successful or not is to be predicted. The alternative synthesis is to be proposed in the case of an unsuccessful reaction.

Concept introduction:

Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride (Lewis acid). This alkylation reaction comes under the category of electrophilic aromatic substitution.

Answer 7

Chapter 17.16B, Problem 17.46P

Interpretation Introduction

Interpretation:

The validation corresponding to the fact that the synthesis of m−ethylbenzenesulfonic acid using Friedel-Crafts alkylation of benzenesulfonic acid is successful or not is to be predicted. The alternative synthesis is to be proposed in the case of an unsuccessful reaction.

Concept introduction:

Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride (Lewis acid). This alkylation reaction comes under the category of electrophilic aromatic substitution.

Answer 8

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Answer 11

Ch. 17.1 - Prob. 17.1P Ch. 17.2 - Prob. 17.2P Ch. 17.3 - Prob. 17.3P Ch. 17.4 - Use resonance forms to show that the dipolar sigma...Ch. 17.6A - Prob. 17.5P Ch. 17.6A - Prob. 17.6P Ch. 17.6B - Propose a mechanism for the brommation of...Ch. 17.6B - Prob. 17.8P Ch. 17.6B - Prob. 17.9P Ch. 17.7 - Prob. 17.10P

Solution Summary: The author explains that Friedel-Crafts alkylation is not a successful method for the synthesis of m-ethylbenzenesulfonic

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Chapter 17 Solutions