Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
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Textbook Question
Chapter 19, Problem 23QAP
Sketch the geometry of
(a) [Zn(NH3)2Cl2](tetrahedral)
(b) cis-[Co(H2O)4Cl2]+
(c) tans-[Pt(NH3)2Br2]2+
(d) tans-[Ni(ox)2(OH)2]3-
(e) [Au(CN)Br]+
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Chapter 19 Solutions
Chemistry: Principles and Reactions
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- For any of the following that can exist as isomers, state thetype of isomerism and draw the structures: (a) [Co(NH3)5Cl]Br2 (b) [Pt(CH3NH2)3Cl]Br (c) [Fe(H2O)4(NH3)2]2+arrow_forwardGive the proper name for each of the following compounds: (a) Pt(NH3)2Cl2 (b) [Rh(NH3)5Cl]Cl2 (c) [Co(NH3)6](NO3)3 (d) [Co(H2O)4]SO4 (e) [Co(NH3)4(OH2)2](BF4)5 (f) [Fe(H2O)6]Br2 (g) Na3[Fe(CN)6] · 2 H2O (h) Na4[Fe(CN)6] (i) Ni(CO)4 (j) [Cu(NH3)4]SO4 (k) [Pt(en)2](ClO4)2 (l) Co(NH3)2(Cl)(Br)(CH3CO2)arrow_forwardGive the proper name for each of the following compounds: (d) [Co(H2O)4]SO4 (e) [Co(NH3)4(OH2)2](BF4)5 (f) [Fe(H2O)6]Br2 (g) Na3[Fe(CN)6] · 2 H2O (h) Na4[Fe(CN)6] (i) Ni(CO)4 (j) [Cu(NH3)4]SO4 (k) [Pt(en)2](ClO4)2 (l) Co(NH3)2(Cl)(Br)(CH3CO2)arrow_forward
- The orbital occupancies for the d orbitals of several com-plex ions are diagrammed below. (a) Which diagram corresponds to the orbital occupancy of thecobalt ion in [Co(CN)₆]³⁻? (b) If diagram D depicts the orbital occupancy of the cobalt ionin [CoF₆]ⁿ, what is the value of n? (c) [NiCl₄]²⁻ is paramagnetic and [Ni(CN)₄]²⁻ is diamagnetic.Which diagrams correspond to the orbital occupancies of thenickel ions in these species? (d) Diagram C shows the orbital occupancy of V²⁺ in the octa-hedral complex VL₆. Can you determine whether L is a strong-or weak-field ligand? Explain.arrow_forwardTransition metals, located in the center of the periodic table,have many essential uses as elements and form many importantcompounds as well. Calculate the molecular mass of thefollow-ing transition metal compounds:(a) [Co(NH₃)₆]Cl₃ (b) [Pt(NH₃)₄BrCl]Cl₂ (c) K₄[V(CN)₆] (d) [Ce(NH₃)₆][FeCl₄]₃arrow_forwardWhich of the following can exhibit geometric isomersim? [Zn(NH3)2Cl2] tetrahedral [Pt(NH3)2Cl2] square planar All of these can exhibit geometric isomerism. [Cu(NH3)5Cl]2+ [Cu(NH3)4]2+ square planararrow_forward
- Assign a systematic name to each of the following chemical compounds:(a) NH4[Cr(NH3)2(NCS)4](b) [Tc(CO)5]I(c) K[Mn(CN)5](d) [Co(NH3)4(OH2)Cl]Br2arrow_forwardDraw orbital-energy splitting diagrams and use the spec-trochemical series to show the orbital occupancy for each of thefollowing (assuming that H₂O is a weak-field ligand):(a) [MoCl₆]³⁻(b) [Ni(H₂O)₆]²⁺(c) [Ni(CN)₄]²⁻arrow_forwardGive systematic names for the following formulas:(a) K[Ag(CN)2] (b) Na2[CdCl4] (c) [Co(NH3)4(H2O)Br]Br2arrow_forward
- Which of these compounds is expected to be colorless? (A) K4[Fe(CN)6] (B) K4[Co(CN)6] (C) K2[Ni(CN)4] (D) K2[Zn(CN)4]arrow_forwardWhich of the following species has a transition metal ion with do electronic configuration? O [Fe(CN)613- O [Mo(NH3)613+ O [COF613- [Co(H2O)6]2+arrow_forwardWould you expect [Co(CN)6] 3- to be a powerful or weak oxidizing agent? Explain.arrow_forward
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