(a)
Interpretation: The work of the given isothermal reversible expansion of
Concept introduction: The process in which the temperature of the system does not change and remains constant is known as isothermal process.
Van der Waals states that real gases are more compressible as compared to ideal gases. Thus, the van der Waal’s gas equation with respect to pressure of a gas is given as,
(b)
Interpretation: The affect of the parameter
Concept introduction: The perfect gas equation of state is consistent with Boyle’s law, Charles’s law and also with
The final volume of any perfect gas for the adiabatic expansion is calculated by the expression,
Want to see the full answer?
Check out a sample textbook solutionChapter 2 Solutions
Atkins' Physical Chemistry
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY