Inorganic Chemistry
5th Edition
ISBN: 9781292134147
Author: Housecroft, Catherine E.
Publisher: Pearson,
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Chapter 2, Problem 5P
Each of the following is a radical. For which does a Lewis structure correctly confirm this property: (a)
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Chapter 2 Solutions
Inorganic Chemistry
Ch. 2 - Draw Lewis structures to describe the bonding in...Ch. 2 - Use the Lewis structure model to deduce the type...Ch. 2 - Draw the resonance structures for the O3 molecule....Ch. 2 - 2.4 Draw Lewis structures for (a) , (b) ,(c) and...Ch. 2 - 2.5 Each of the following is a radical. For which...Ch. 2 - (a) Use VB theory to describe the bonding in the...Ch. 2 - 2.7 Use VB theory and Lewis structure model,...Ch. 2 - 2.8 Does VB theory indicate that the diatomic...Ch. 2 - 2.9 (a) Use MO theory to determine the bond order...Ch. 2 - Prob. 10P
Ch. 2 - Prob. 11PCh. 2 - Draw charge-separated resonance structures to give...Ch. 2 - Prob. 13PCh. 2 - In the following table, match a species in list 1...Ch. 2 - Using the data in table 2.2, determine which of...Ch. 2 - Prob. 16PCh. 2 - 2.17 Use the VSEPR model to predict the structures...Ch. 2 - 2.18 Use the VSEPR model to rationalize the...Ch. 2 - Determine the shapes of each of the following...Ch. 2 - 2.20 State whether you expect the following...Ch. 2 - 2.21 (a) Draw resonance structure for the CO,...Ch. 2 - Prob. 22PCh. 2 - Prob. 23PCh. 2 - Suggest reasons for the following observations....Ch. 2 - Prob. 25PCh. 2 - Prob. 26PCh. 2 - 2.27 (a) Write down the ions that are present in...Ch. 2 - 2.28 Assuming that VSEPR model can be applied...Ch. 2 - Critically compare the VB and MO treatments of the...Ch. 2 - The table below gives the average composition of...Ch. 2 - Carbon monoxide is a toxic pollutant which arises...Ch. 2 - 2.32 Volcanoes and deep sea hydrothermal vents are...
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- With reference to the “Chemistry Put to Work” box on explosives, (a) use bond enthalpies to estimate the enthalpy change for the explosion of 1.00 g of nitroglycerin. (b) Write a balanced equation for the decomposition of TNT. Assume that, upon explosion, TNT decomposes into N2(g), CO2(g), H2O(g), and C(s).arrow_forwardDraw the Lewis structure for (a) NO+ ion, (b) C2H4.arrow_forwardDraw a Lewis electron-dot symbol for (a) Ba; (b) Kr; (c) Br.arrow_forward
- Acetylene (C2H2) and nitrogen (N2) both contain a triplebond, but they differ greatly in their chemical properties.(a) Write the Lewis structures for the two substances. (b) By referring to Appendix C, look up the enthalpies of formationof acetylene and nitrogen. Which compound is more stable?(c) Write balanced chemical equations for the completeoxidation of N2 to form N2O5(g) and of acetylene to formCO2(g) and H2O(g). (d) Calculate the enthalpy of oxidationper mole for N2 and for C2H2 (the enthalpy of formationof N2O5(g) is 11.30 kJ/mol). (e) Both N2 and C2H2 possesstriple bonds with quite high bond enthalpies (Table 8.3).Calculate the enthalpy of hydrogenation per mole for bothcompounds: acetylene plus H2 to make methane, CH4;nitrogen plus H2 to make ammonia, NH3.arrow_forwardKeeping in mind that some elements violate the octet rule, draw a Lewis structure for each compound: (a) BCl 3; (b) SO 3.arrow_forwardIn addition to ammonia, nitrogen forms three other hydrides: hydrazine (N2H4), diazene (N2H2), and tetrazene (N4H4).(a) Use Lewis structures to compare the strength, length, and order of the nitrogen-nitrogen bonds in hydrazine, diazene, and N2.(b) Tetrazene (atom sequence H2NNNNH2) decomposes above 08C to hydrazine and nitrogen gas. Draw a Lewis structure for tetrazene, and calculate ΔH°rxn for this decomposition.arrow_forward
- Hydrazine, N2H4, burns in oxygen as follows: N2H4 + O2 → N2 + 2H2O [The bond energies in kJ/mol are: N-H = 388; N-N 163; N≡N 944; O-H 463; O=O 496] Draw the chemical structures of the reactants and products and give the formula to calculate enthalpy change in a reaction, ΔH.arrow_forwardCalculate the enthalpy change for the following reactions using the bond enthalpy given below. (Bond enthalpy/kJ : H−H = 436, C−H = 413, C=O = 799, O=O = 495, O−H = 463) (a) H2(g) + 1⁄2O2(g) → H2O(g) (b) CH4(g) + 2O2(g) → CO2(g) + 2H2O(l)arrow_forwardAcetylene 1C2H22 and nitrogen 1N22 both contain a triplebond, but they differ greatly in their chemical properties.(a) Write the Lewis structures for the two substances. (b) Byreferring to Appendix C, look up the enthalpies of formationof acetylene and nitrogen. Which compound is more stable?(c) Write balanced chemical equations for the completeoxidation of N2 to form N2O51g2 and of acetylene to formCO21g2 and H2O1g2. (d) Calculate the enthalpy of oxidationper mole for N2 and for C2H2 (the enthalpy of formationof N2O51g2 is 11.30 kJ>mol). (e) Both N2 and C2H2 possesstriple bonds with quite high bond enthalpies (Table 8.3).Calculate the enthalpy of hydrogenation per mole for bothcompounds: acetylene plus H2 to make methane, CH4;nitrogen plus H2 to make ammonia, NH3.arrow_forward
- An ionic compound of formula XY2 (X = cation with two positive charges, Y = anion with one negative charge) has the following mass composition: Mg 10.9%, Cl 31.8%, O57.3%. (a) What is the chemical formula and name of the compound? (b) Give the most probable Lewis structure for the ions contained in the compound.arrow_forward(b) Methyl azide, CH-N3 is a molecule that decomposes explosively. Draw a Lewis structure for CH3N3, showing formal charges and also sketch any possible resonance forms.arrow_forwardIn the vapor phase, BeCl2 exists as a discrete molecule. (a) Draw the Lewis structure of this molecule, using only single bonds. Does this Lewis structure satisfy the octet rule? (b) What other resonance structures are possible that satisfy the octet rule? (c) On the basis of the formal charges, which Lewis structure is expected to be dominant for BeCl2?arrow_forward
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