(a)
Interpretation:
Thepurpose of washing of crude n-butyl bromide with sodium bicarbonate needs to be explained.
Concept Introduction:
The
(b)
Interpretation:
The reason for the undesirable wash of the crude halide with aqueous sodium hydroxide needs to be explained.
Concept Introduction:
The alkyl halide: n-butyl bromide is formed by the reaction of n-butyl alcohol with
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Chapter 21 Solutions
EBK A SMALL SCALE APPROACH TO ORGANIC L
- 1. Arrange the test samples in order of increasing reactivity with sodium bicarbonate? Explain briefly -Ethanoic acid, Butanoic acid, Benzoic acid 2. Arrange the test samples in order of increasing solubility in water? Explain briefly. -Ethylamine, Diethylamine, Aniline 3. Arrange the test samples in order of increasing basicity? Explain briefly. -NaOH, Ethylamine, Anilinearrow_forwardWhen bromophenol blue is dissolved in citrate buffer, would the pH of the citrate buffer change or not? Why does this happen? Explain your answer.arrow_forward1. What type of reaction explains the solubility of phenol in Sodium Hydroxide? Explain the organic product formed 2. How do the reactions of phenol samples with FeCl3 compare? Which structural component of the phenols account for the observation? 3. What compound is the precipitate formed in the Bromine water test? 4. Write the reaction formed in the formation of phenolphthalein. Identify the functional group in phenolphthalein , which is responsible for the indicator property. 5. What is the significance of Millon's test?arrow_forward
- You have already dissolved the reagent in distilled water, although the pH is less than the target pH. What accounts for this discrepancy in pH?arrow_forward1. A compound of molecular formula C5H100 forms a yellow precipitate with reagent and a yellow precipitate with reagents for the iodoform test. 2,4-dinitrophenylhydrazine a) Draw the structural formulae on a piece of paper, take a picture of them and upload the image below. b) Name the two (2) compounds that fit these tests.arrow_forwardHow do the reactions of phenol samples with FeCl3compare? Which structural component of the phenols account for the observation? 2. What compound is the precipitate formed in the Bromine water test? 3. Write the reaction formed in the formation of phenolphthalein. Identify the functional group in phenolphthalein, which is responsible for the indicator property. 4. What is the significance of Millon's test?arrow_forward
- 1. In between water and 10% HCl, aniline and diethylamine is more soluble in what solvent? Explain and show the chemical reaction involved. 2. In between water and 10% NaOH, benzoic acid and phenol is more soluble in what solvent? Explain and show the chemical reaction involved.arrow_forward1. Arrange the test samples in order of increasing acidity? Explain briefly. -Ethanoic acid, Butanoic acid, Benzoic acid, Salicylic acid 2. Arrange the test samples in order of increasing reactivity with sodium bicarbonate? Explain briefly -Ethanoic acid, Butanoic acid, Benzoic acid 3. Arrange the test samples in order of increasing solubility in water? Explain briefly. -Ethylamine, Diethylamine, Aniline 4. Arrange the test samples in order of increasing basicity? Explain briefly. -NaOH, Ethylamine, Anilinearrow_forward2. What happens when you add hydrochloric acid to sodium carbonate? 3. What happens if we use phenolphthalein for the standardization of HCl with sodium carbonate? 4..arrow_forward
- Sodium Borohydride + Vanillin Explain why the product is soluble in aqueous NaOH, but precipitates upon addition of HCl?arrow_forwardAqueous sodium bicarbonate was used to wash the crude n-butyl bromide.a. What was the purpose of this wash? Give equations.b. Why would it be undesirable to wash the crude halide with aqueous sodium hydroxide?arrow_forward1. outline a procedure for separating a mixture of naphthalene (a neutral compound), toluic acid (an acidic compound), and p-bromoaniline (a basic compound). Assume that toluic acid and p-bromoaniline are completely insoluble in water. 2. The solubility of Lorazepam (a tranquilizer found in Emotival , Lorax, Wypax, and other prescription medicines) is 0.08mg/mL and 2.62mg/mL, in water and chloroform, respectively. Estimate the partition coefficient of lorazepam between chloroform and water. 3. The solubility of benzoic acid at 25 degrees Celsius in water and diethyl ether is 3.35 mg/mL and 0.353 g/mL, respectively. Estimate the percent recovery of benzoic acid in the organic phase, if a solution of benzoic acid in water is extracted with an equivalent volume of ether. [HINT-pay attention to the units] 4. The solubilities of cholesterol in water and chloroform are 0.550mg/100mL and 1.00g/5.25mL, respectively. Estimate the partition coefficient of cholesterol between chloroform and…arrow_forward