Essential University Physics: Volume 2 (3rd Edition)
Essential University Physics: Volume 2 (3rd Edition)
3rd Edition
ISBN: 9780321976420
Author: Richard Wolfson
Publisher: PEARSON
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Chapter 37, Problem 45P
To determine

The ionic cohesive energy of LiCl crystal.

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The crystal structure of sodium chloride (NaCI) is face centered cubic. If the minimum separation between the Na* and Cl ion is 'r', then assuming the lattice only upto the two nearest neighbouring ions, the Madelung constant will be -0.8665 0.8665 -1.7476. O 1.7476
The ionic crystal of NaCl has an fcc structure as shown below with the position of the Cl atom located at : (0 0 0); (½ ½ 0); ( ½ 0 %) and (0 ½) and Na atom is located at : (½ ½½) + fcc translation. The following are the physical data of NaCl: - Ionic radius Na = 0.98 A, Cl ion radius 1.81 A Atomic mass of Na = 22.99 amu, Atomic mass of Cl = 35.45 amu NaCl bulk modulus = 2.40 x 1010 N/m - Madelung's constant = 1.75 Young's modulus in the direction [100] = 5 x 1010 Nm-2 Debye temperature = 281 K - State the structural factors of NaCl, F in fNa and fCl (f = atomic scattering factor). Also determine the condition (h k 1) so that the value of F = 0.
Suppose a pure Si crystal has 5 × 1028 atoms m-3. It is doped by 1 ppm concentration of pentavalent As. Calculate the number of electrons and holes. Given that ni =1.5 × 1016 m-3.

Chapter 37 Solutions

Essential University Physics: Volume 2 (3rd Edition)

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