Chemical Principles: The Quest for Insight
Chemical Principles: The Quest for Insight
7th Edition
ISBN: 9781464183959
Author: Peter Atkins, Loretta Jones, Leroy Laverman
Publisher: W. H. Freeman
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Chapter 6, Problem 6D.2AST
Interpretation Introduction

Interpretation:

The Ka and pKa value of 0.20 M aqueous solution of crotonic acid has to be calculated

Concept introduction:

pH definition:

The concentration of hydrogen ion is measured using pH scale.  The acidity of aqueous solution is expressed by pH scale.

The pH of a solution is defined as the negative base-10 logarithm of the hydrogen or hydronium ion concentration.

  pH=-log[H3O+]

On rearranging, the concentration of hydrogen ion [H+] can be calculated using pH as follows,

  [H+]=10-pH

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Determine the pH of each of the following solutions (Ka and Kb values can be found in the appendices of your textbook or online):  (a) 0.045 M hypochlorous acid;  (b) 0.0068 M phenol;  (c) 0.080 M hydroxylamine.
The active ingredient of bleach such as Clorox is sodium hypochlorite (NaClO). Its conjugate acid, hypochlorous acid (HClO), has a Ka of 3.0 × 10–8. (a) The undiluted bleach contains roughly 1 M NaClO.Calculate the pH of 1 M NaClO solution.  (b) Some applications require extremely diluted bleach solution, such as swimming pools. Suppose the solution in (a) is diluted by 10,000-fold. Calculate the pH of the diluted solution, and demonstrate that you can still neglect the autoionization of water in your calculation.  (c) Suppose the solution in (a) is diluted by 1 million-fold, briefly explain how your approach willbe different. Write the equation with [H3O+] as the unknown, but you do not need to solve it.
The active ingredient of bleach such as Clorox is sodium hypochlorite (NaClO). Its conjugate acid, hypochlorous acid (HClO), has a Ka of 3.0 × 10–8. (a)The undiluted bleach contains roughly 1 M NaClO. Calculate the pH of 1 M NaClO solution.  (b)Some applications require extremely diluted bleach solution, such as swimming pools. Suppose the solution in (a) is diluted by 10,000 -fold. Calculate the pH of the diluted solution, and demonstrate that you can still neglect the autoionization of water in your calculation.  (c)Suppose the solution in (a) is diluted by 1million-fold, briefly explain how your approach will be different. Write the equation with [H3O+] as the unknown, but you do not need to solve it.

Chapter 6 Solutions

Chemical Principles: The Quest for Insight

Ch. 6 - Prob. 6A.5ECh. 6 - Prob. 6A.6ECh. 6 - Prob. 6A.7ECh. 6 - Prob. 6A.8ECh. 6 - Prob. 6A.9ECh. 6 - Prob. 6A.10ECh. 6 - Prob. 6A.11ECh. 6 - Prob. 6A.12ECh. 6 - Prob. 6A.13ECh. 6 - Prob. 6A.14ECh. 6 - Prob. 6A.15ECh. 6 - Prob. 6A.16ECh. 6 - Prob. 6A.17ECh. 6 - Prob. 6A.18ECh. 6 - Prob. 6A.19ECh. 6 - Prob. 6A.20ECh. 6 - Prob. 6A.21ECh. 6 - Prob. 6A.22ECh. 6 - Prob. 6A.23ECh. 6 - Prob. 6A.24ECh. 6 - Prob. 6B.1ASTCh. 6 - Prob. 6B.1BSTCh. 6 - Prob. 6B.2ASTCh. 6 - Prob. 6B.2BSTCh. 6 - Prob. 6B.3ASTCh. 6 - Prob. 6B.3BSTCh. 6 - Prob. 6B.1ECh. 6 - Prob. 6B.2ECh. 6 - Prob. 6B.3ECh. 6 - Prob. 6B.4ECh. 6 - Prob. 6B.5ECh. 6 - Prob. 6B.6ECh. 6 - Prob. 6B.7ECh. 6 - Prob. 6B.8ECh. 6 - Prob. 6B.9ECh. 6 - Prob. 6B.10ECh. 6 - Prob. 6B.11ECh. 6 - Prob. 6B.12ECh. 6 - Prob. 6C.1ASTCh. 6 - Prob. 6C.1BSTCh. 6 - Prob. 6C.2ASTCh. 6 - Prob. 6C.2BSTCh. 6 - Prob. 6C.3ASTCh. 6 - Prob. 6C.3BSTCh. 6 - Prob. 6C.1ECh. 6 - Prob. 6C.2ECh. 6 - Prob. 6C.3ECh. 6 - Prob. 6C.4ECh. 6 - Prob. 6C.5ECh. 6 - Prob. 6C.6ECh. 6 - Prob. 6C.7ECh. 6 - Prob. 6C.8ECh. 6 - Prob. 6C.9ECh. 6 - Prob. 6C.10ECh. 6 - Prob. 6C.11ECh. 6 - Prob. 6C.12ECh. 6 - Prob. 6C.13ECh. 6 - Prob. 6C.14ECh. 6 - Prob. 6C.15ECh. 6 - Prob. 6C.16ECh. 6 - Prob. 6C.17ECh. 6 - Prob. 6C.18ECh. 6 - Prob. 6C.19ECh. 6 - Prob. 6C.20ECh. 6 - Prob. 6C.21ECh. 6 - Prob. 6C.22ECh. 6 - Prob. 6D.1ASTCh. 6 - Prob. 6D.1BSTCh. 6 - Prob. 6D.2ASTCh. 6 - Prob. 6D.2BSTCh. 6 - Prob. 6D.3ASTCh. 6 - Prob. 6D.3BSTCh. 6 - Prob. 6D.4ASTCh. 6 - Prob. 6D.4BSTCh. 6 - Prob. 6D.5ASTCh. 6 - Prob. 6D.5BSTCh. 6 - Prob. 6D.6ASTCh. 6 - Prob. 6D.6BSTCh. 6 - Prob. 6D.1ECh. 6 - Prob. 6D.2ECh. 6 - Prob. 6D.3ECh. 6 - Prob. 6D.4ECh. 6 - Prob. 6D.5ECh. 6 - Prob. 6D.6ECh. 6 - Prob. 6D.7ECh. 6 - Prob. 6D.8ECh. 6 - Prob. 6D.9ECh. 6 - Prob. 6D.11ECh. 6 - Prob. 6D.12ECh. 6 - Prob. 6D.13ECh. 6 - Prob. 6D.14ECh. 6 - Prob. 6D.15ECh. 6 - Prob. 6D.16ECh. 6 - Prob. 6D.17ECh. 6 - Prob. 6D.18ECh. 6 - Prob. 6D.19ECh. 6 - Prob. 6D.20ECh. 6 - Prob. 6D.21ECh. 6 - Prob. 6D.22ECh. 6 - Prob. 6E.1ASTCh. 6 - Prob. 6E.1BSTCh. 6 - Prob. 6E.2ASTCh. 6 - Prob. 6E.2BSTCh. 6 - Prob. 6E.3ASTCh. 6 - Prob. 6E.1ECh. 6 - Prob. 6E.2ECh. 6 - Prob. 6E.3ECh. 6 - Prob. 6E.4ECh. 6 - Prob. 6E.5ECh. 6 - Prob. 6E.6ECh. 6 - Prob. 6E.7ECh. 6 - Prob. 6E.8ECh. 6 - Prob. 6E.9ECh. 6 - Prob. 6E.10ECh. 6 - Prob. 6E.11ECh. 6 - Prob. 6E.12ECh. 6 - Prob. 6E.13ECh. 6 - Prob. 6E.14ECh. 6 - Prob. 6E.15ECh. 6 - Prob. 6E.16ECh. 6 - Prob. 6E.17ECh. 6 - Prob. 6E.18ECh. 6 - Prob. 6F.1ASTCh. 6 - Prob. 6F.1BSTCh. 6 - Prob. 6F.2ASTCh. 6 - Prob. 6F.2BSTCh. 6 - Prob. 6F.1ECh. 6 - Prob. 6F.2ECh. 6 - Prob. 6F.3ECh. 6 - Prob. 6F.4ECh. 6 - Prob. 6F.5ECh. 6 - Prob. 6F.6ECh. 6 - Prob. 6F.7ECh. 6 - Prob. 6F.9ECh. 6 - Prob. 6F.10ECh. 6 - Prob. 6G.1ASTCh. 6 - Prob. 6G.1BSTCh. 6 - Prob. 6G.2ASTCh. 6 - Prob. 6G.2BSTCh. 6 - Prob. 6G.3ASTCh. 6 - Prob. 6G.3BSTCh. 6 - Prob. 6G.4ASTCh. 6 - Prob. 6G.4BSTCh. 6 - Prob. 6G.1ECh. 6 - Prob. 6G.3ECh. 6 - Prob. 6G.4ECh. 6 - Prob. 6G.5ECh. 6 - Prob. 6G.6ECh. 6 - Prob. 6G.7ECh. 6 - Prob. 6G.8ECh. 6 - Prob. 6G.9ECh. 6 - Prob. 6G.11ECh. 6 - Prob. 6G.12ECh. 6 - Prob. 6G.13ECh. 6 - Prob. 6G.14ECh. 6 - Prob. 6G.15ECh. 6 - Prob. 6G.16ECh. 6 - Prob. 6G.19ECh. 6 - Prob. 6G.20ECh. 6 - Prob. 6H.1ASTCh. 6 - Prob. 6H.1BSTCh. 6 - Prob. 6H.2ASTCh. 6 - Prob. 6H.2BSTCh. 6 - Prob. 6H.3ASTCh. 6 - Prob. 6H.3BSTCh. 6 - Prob. 6H.4ASTCh. 6 - Prob. 6H.4BSTCh. 6 - Prob. 6H.5ASTCh. 6 - Prob. 6H.5BSTCh. 6 - Prob. 6H.1ECh. 6 - Prob. 6H.3ECh. 6 - Prob. 6H.9ECh. 6 - Prob. 6H.10ECh. 6 - Prob. 6H.15ECh. 6 - Prob. 6H.16ECh. 6 - Prob. 6H.21ECh. 6 - Prob. 6H.22ECh. 6 - Prob. 6H.23ECh. 6 - Prob. 6H.24ECh. 6 - Prob. 6H.25ECh. 6 - Prob. 6H.26ECh. 6 - Prob. 6H.27ECh. 6 - Prob. 6H.28ECh. 6 - Prob. 6H.29ECh. 6 - Prob. 6H.30ECh. 6 - Prob. 6H.31ECh. 6 - Prob. 6H.32ECh. 6 - Prob. 6I.1ASTCh. 6 - Prob. 6I.1BSTCh. 6 - Prob. 6I.2ASTCh. 6 - Prob. 6I.2BSTCh. 6 - Prob. 6I.3ASTCh. 6 - Prob. 6I.3BSTCh. 6 - Prob. 6I.4ASTCh. 6 - Prob. 6I.4BSTCh. 6 - Prob. 6I.1ECh. 6 - Prob. 6I.2ECh. 6 - Prob. 6I.3ECh. 6 - Prob. 6I.4ECh. 6 - Prob. 6I.5ECh. 6 - Prob. 6I.6ECh. 6 - Prob. 6I.7ECh. 6 - Prob. 6I.8ECh. 6 - Prob. 6I.9ECh. 6 - Prob. 6I.10ECh. 6 - Prob. 6I.11ECh. 6 - Prob. 6I.12ECh. 6 - Prob. 6J.1ASTCh. 6 - Prob. 6J.1BSTCh. 6 - Prob. 6J.2ASTCh. 6 - Prob. 6J.2BSTCh. 6 - Prob. 6J.1ECh. 6 - Prob. 6J.2ECh. 6 - Prob. 6J.3ECh. 6 - Prob. 6J.4ECh. 6 - Prob. 6J.9ECh. 6 - Prob. 6J.10ECh. 6 - Prob. 6J.11ECh. 6 - Prob. 6J.15ECh. 6 - Prob. 6J.17ECh. 6 - Prob. 6K.1ASTCh. 6 - Prob. 6K.1BSTCh. 6 - Prob. 6K.2ASTCh. 6 - Prob. 6K.2BSTCh. 6 - Prob. 6K.1ECh. 6 - Prob. 6K.2ECh. 6 - Prob. 6K.3ECh. 6 - Prob. 6K.4ECh. 6 - Prob. 6K.5ECh. 6 - Prob. 6K.6ECh. 6 - Prob. 6K.7ECh. 6 - Prob. 6K.8ECh. 6 - Prob. 6L.1ASTCh. 6 - Prob. 6L.1BSTCh. 6 - Prob. 6L.2ASTCh. 6 - Prob. 6L.2BSTCh. 6 - Prob. 6L.3ASTCh. 6 - Prob. 6L.3BSTCh. 6 - Prob. 6L.1ECh. 6 - Prob. 6L.2ECh. 6 - Prob. 6L.3ECh. 6 - Prob. 6L.4ECh. 6 - Prob. 6L.5ECh. 6 - Prob. 6L.7ECh. 6 - Prob. 6L.9ECh. 6 - Prob. 6M.1ASTCh. 6 - Prob. 6M.1BSTCh. 6 - Prob. 6M.2ASTCh. 6 - Prob. 6M.2BSTCh. 6 - Prob. 6M.3ASTCh. 6 - Prob. 6M.3BSTCh. 6 - Prob. 6M.4ASTCh. 6 - Prob. 6M.4BSTCh. 6 - Prob. 6M.1ECh. 6 - Prob. 6M.2ECh. 6 - Prob. 6M.9ECh. 6 - Prob. 6M.10ECh. 6 - Prob. 6N.1ASTCh. 6 - Prob. 6N.1BSTCh. 6 - Prob. 6N.2ASTCh. 6 - Prob. 6N.2BSTCh. 6 - Prob. 6N.3BSTCh. 6 - Prob. 6N.4ASTCh. 6 - Prob. 6N.4BSTCh. 6 - Prob. 6N.1ECh. 6 - Prob. 6N.2ECh. 6 - Prob. 6N.5ECh. 6 - Prob. 6N.6ECh. 6 - Prob. 6N.7ECh. 6 - Prob. 6N.9ECh. 6 - Prob. 6N.10ECh. 6 - Prob. 6N.11ECh. 6 - Prob. 6N.12ECh. 6 - Prob. 6N.21ECh. 6 - Prob. 6N.23ECh. 6 - Prob. 6O.1ASTCh. 6 - Prob. 6O.1BSTCh. 6 - Prob. 6O.2ASTCh. 6 - Prob. 6O.2BSTCh. 6 - Prob. 6O.3ASTCh. 6 - Prob. 6O.3BSTCh. 6 - Prob. 6O.4ASTCh. 6 - Prob. 6O.4BSTCh. 6 - Prob. 6O.1ECh. 6 - Prob. 6O.2ECh. 6 - Prob. 6O.3ECh. 6 - Prob. 6O.4ECh. 6 - Prob. 6O.5ECh. 6 - Prob. 6O.6ECh. 6 - Prob. 6O.7ECh. 6 - Prob. 6O.8ECh. 6 - Prob. 6O.9ECh. 6 - Prob. 6O.10ECh. 6 - Prob. 6O.11ECh. 6 - Prob. 6O.12ECh. 6 - Prob. 6O.13ECh. 6 - Prob. 6O.14ECh. 6 - Prob. 6O.15ECh. 6 - Prob. 6O.16ECh. 6 - Prob. 6.1ECh. 6 - Prob. 6.3ECh. 6 - Prob. 6.4ECh. 6 - Prob. 6.5ECh. 6 - Prob. 6.6ECh. 6 - Prob. 6.8ECh. 6 - Prob. 6.9ECh. 6 - Prob. 6.10ECh. 6 - Prob. 6.11ECh. 6 - Prob. 6.12ECh. 6 - Prob. 6.13ECh. 6 - Prob. 6.14ECh. 6 - Prob. 6.25ECh. 6 - Prob. 6.40ECh. 6 - Prob. 6.41ECh. 6 - Prob. 6.43ECh. 6 - Prob. 6.45ECh. 6 - Prob. 6.46ECh. 6 - Prob. 6.47ECh. 6 - Prob. 6.51ECh. 6 - Prob. 6.53ECh. 6 - Prob. 6.65ECh. 6 - Prob. 6.75ECh. 6 - Prob. 6.77E
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