Use a mechanistic approach to provide the major product(s) for each of the following reactions. Be sure to indicate alternative mechanisms if applicable. HN- a. + SOCI₂ 2)+ OH 2 b. + K₂CO3 2)+ H₂O/EtOH
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- Complete the following tree of reactions by providing their major products: HCI i. BH3 ii. NaOH, H₂O2, H₂O 03, (CH3)2S H+, H₂O Br₂ H₂, Pd/C CH₂CO3H Br₂, H₂O modellen H+, CH3OH1) Complete the following reaction and provide a detailed, step-by-step mechanism for the process. HBr 2) Provide the structure of the major organic product in the reactions below. HI CH3 win H3C. CH3 CH₂CH3 HCI Xero H₂C CH3 HBrEthers/Aldehydes/Ketones SynthesisPrepare the following compounds from any simple alkyl halide having four carbons or less,cyclohexane, and/or benzene. You may also use ethylene oxide (oxacyclopropane). SHOW ALLSTEPS AND REAGENTS with arrows.
- a) Using your knowledge of organic reaction mechanisms, explain the formation of EACH product (A,B) in the following reaction. This will require you to write out MULTIPLE mechanisms (i.e. each product comes from a different reaction pathway). Hint: all reaction pathways start from the same intermediate: NaH is a strong base but cannot deprotonate an sp3 C-H bond! OH он 1) NaH (0.5 equiv) Br + 2) H20 A B b) Briefly explain why there is no epoxide (formed via an intramolecular substitution reaction) in the product mixture of the above reaction?ucf.edu/courses/1379813/quizzes). Question 12 Identify the major product from the following series of reactions. 1. NaOEt 1. NaOEt 2. CH3CH2CI OEt 2. H30*, Quendch 3. H30*, Heat но он HO H.1. Complete the following reactions by writing the missing product, reactants, or starting material. 1) Hg(OAc)2/H20 2) NaBH,/NAOH 1) Hg(OAc)/PHCH,OH 2) NABH/NAOH 1) BH3 2) PCC он 1) 9-BBN 2) H2O2/NAOH 1) 9-BBN (1 equiv) 2) H2O/NAOH 1)9-BBN (1 equiv) 2) H2O/NAOH
- Provide the major organic product of the following reaction. H CH,CH₂I (excess)Fill in necessary products reactants or reagants of these reactions. Please note the existence of enantionmers in some cases.Consider the reaction scheme below. (a) Name the reagent and conditions necessary for steps I to VI above. (b) Write balanced equations for step I to VI above. elow. 4. Consider the reaction scheme below. CH, CH CH₂CI III --------ပုံ CH₂OH CHÍNH, VI CH₂NHCOCH,CH, (a) Name the reagent and conditions necessary for steps I to VI above. (b) Write balanced equations for step I to VI above.
- Place the best reagent and conditions in the bins for each of the following reactions. One of the bins require 2 choices, as indicated by the larger bin. (Stoichiometry is omitted.) OFOLE OH 2 ok. NH₂ OH CI 1. NaCl CH3OH OH of NH₂ NaBH₁ CH₂CO₂ Na CH₂ MgBr Answer Bank CH, ONa SOCI₂ LiAlH CrO₂ (CH3)2 CuLi NaN3 H₂O+ iPrMgBr CH3NH₂In each reaction box, place the best reagent and conditions from the list provided. 1) Br 2) 3) 4) DEET (the active ingredient in over the counter insect repellant) 5) Answer Bank Mg, Et,0 HN(CH, CH, ), (1 equiv.) H,O* CH,COOH CH,CH,NH, CH,CH, Br NH(CH,CH,),(2 cquiv.) НСООСH, H,CO НСООН CH, CH, OH NaCN NaNH, Br,, FeBr, SOCI, CO,1. Write organic products of the following reactions. Show stereochemistry where appropriate. Br₂ H₂O H₂O H₂SO4 1. BH3: THF 2. H₂O2, NaOH