Interpretation:
The values of logarithm of
Concept introduction:
Combination formula is a possible way of grouping of distinguishable objects into various subsystems. The equation for combination formula is as follows:
Where,
•
If the value of
Answer to Problem 17.57E
For
Explanation of Solution
The Stirling’s approximation for large value of
For
For
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Chapter 17 Solutions
Physical Chemistry
- Consider a system similar to the one in Figure 16.8, except that it contains six particles instead of four. What is the probability of having all the particles in only one of the two boxes in the case? Compare this with the similar probability for the system of four particles that we have derived to be equal to 18 . What does this comparison tell us about even larger systems?arrow_forwardEvaluate Lz for 3px, Compare it to the answer in Example 11.25, and explain the difference in the answers.arrow_forwardCan you help me, please?arrow_forward
- What is the value of n from Hückel's rule for each of the following compounds? Harrow_forwardConsider the molecules: CH2=CH-CH=CH-CH=CH-CH=CH-CH=CH2. let’s assume that the 10 electrons that make up the double bonds can exist everywhere along the carbon chains. The electrons can then be considered as particles in a box; the ends of the molecule correspond to the boundaries of the box with a finite or zero potential energy inside. In this “molecular box”, 2 electrons can occupy an energy level. What are quantum states that the electrons from this molecule can occupy in the ground state? What’s the smallest frequency of light that can excite the electron? Briefly explain why. Note that the length of a C-C bond is about 1.54A and the length of a C=C bond is 1.34A to allow you to estimate the length of the “molecular box”arrow_forward
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