Concept explainers
(a)
Interpretation:
The ester formed on treating 2-propanol with CH3CH2COOH in the presence of H2SO4 should be determined.
Concept Introduction:
The reaction which results in the formation of at least one ester along with water on heating acids with alcohols is said to be esterification.
Answer to Problem 56P
Explanation of Solution
The reaction which results in the formation of at least one ester along with water on heating acids with alcohols is said to be esterification.
The general reaction is written as:
Thus, the reaction between CH3CH2COOH (propanoic acid) and 2-propanol is:
(b)
Interpretation:
The ester formed on treating 2-propanol with following in the presence of H2SO4 should be determined:
Concept Introduction:
The reaction which results in the formation of at least one ester along with water on heating acids with alcohols is said to be esterification.
Answer to Problem 56P
Explanation of Solution
The reaction which results in the formation of at least one ester along with water on heating acids with alcohols is said to be esterification.
The general reaction is written as:
Thus, the reaction between CH3(CH2)10COOH (dodoecanoic acid) and 2-propanol is:
(c)
Interpretation:
The ester formed on treating 2-propanol with HCO2H in the presence of H2SO4 should be determined.
Concept Introduction:
The reaction which results in the formation of at least one ester along with water on heating acids with alcohols is said to be esterification.
Answer to Problem 56P
Explanation of Solution
The reaction which results in the formation of at least one ester along with water on heating acids with alcohols is said to be esterification.
The general reaction is written as:
Thus, the reaction between HCO2H (formic acid) and 2-propanol is:
(d)
Interpretation:
The ester formed on treating 2-propanol with following in the presence of H2SO4 should be determined:
Concept Introduction:
The reaction which results in the formation of at least one ester along with water on heating acids with alcohols is said to be esterification.
Answer to Problem 56P
Explanation of Solution
The reaction which results in the formation of at least one ester along with water on heating acids with alcohols is said to be esterification.
The general reaction is written as:
Thus, the reaction between 4-methoxybenzoic acid and 2-propanol is:
Want to see more full solutions like this?
Chapter 17 Solutions
General, Organic, and Biological Chemistry - 4th edition
- Classify each alkyl halide as 1°, 2°, or 3°. CH3 c. CHg-C-CHCH3 ČH3 ČI CH;CH2CH,CH,CH2-Br b. d. a.arrow_forwardWhich is a thiol? CH3 HS SH b. HO. CH3 H.CS CHa CH C. H. d. భిగింగడి 工 a.arrow_forwardOH 15. CH3-C-H ÓCH, The compound above is an example of a(n) a. acetal b. ketal O c. hemiacetal d. hemiketal e. none of the abovearrow_forward
- Show how to bring about each conversion in good yield. a. b. C6H5 Cl OH COOH C6H5 COOHarrow_forward8 What ester is formed when each carboxylic acid is treated with 2-propanol [(CH 3) 2CHOH] in the presence of H 2SO 4?arrow_forward7 8 11 12 me CH3 H3C 3-butylpropanoate 2-butoxypropane propyl-2-butanoate 2-butylpropanoate H₂ C CH3arrow_forward
- 18. Ketone reduction Dicyclohexyl ketone Reduce the ketone. 1. NaBH4, ethanol 2. H3O+ H OH Dicyclohexylmethanol (88%) (a 2° alcohol)arrow_forwardWhat is the major product of the following reaction? 1. BF; 2. H0 CH; CHarrow_forwardDoes the equilibrium favor the reactants or products in each substitution reaction? a. CH;CH2-NH2 Br CH;CH2-Br + "NH2 b. "CN CN + I-arrow_forward
- Draw out each compound to clearly show what groups are bonded to the carbonyl carbon. Label each compound as a ketone or aldehyde. a. CH 3CH 2CHO b. CH 3CH 2COCH 3 c. (CH 3) 3CCOCH 3 d. (CH 3CH 2) 2CHCHOarrow_forwardWhat is the reduction product of the following compound with H2/Pd? A 2-propyl-1-cyclohexanol B 2-propenyl-1-cyclohexanol C2-propylcyclohexanone D 1-propyl-2-cyclohexanol What is the oxidation product of this compound? H' A ethanoic acid acetic acid propanoic acid D propanone What is the oxidation product of this compound? A 3,4-dimethylpentanoic acid B 2,3-dimethylpentanoic acid C2,3-dimethylpentanone 3,4-dimethylpentanonearrow_forwardDetermine the products of each carboxylic acid reaction. a. CH3-CH -C-OH + NaOH b. CH;-CH2-CH;-C-OH + CH — CH, —Сн, — онarrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY