Concept explainers
(a)
Interpretation:
The ketone obtained by hydrolysis and decarboxylation of the given
Concept introduction:
The final products of acetoacetic ester synthesis are
(b)
Interpretation:
The ketone obtained by hydrolysis and decarboxylation of the given
Concept introduction:
The final products of acetoacetic ester synthesis are ketones, specially substituted derivatives of acetone. In acetoacetic ester synthesis, substituents are added to the enolate ion of acetoacetic ester. Then, hydrolysis takes place followed by decarboxylation to give alkylated derivatives of acetone.
(c)
Interpretation:
The ketone obtained by hydrolysis and decarboxylation of the given
Concept introduction:
The final products of acetoacetic ester synthesis are ketones, specially substituted derivatives of acetone. In acetoacetic ester synthesis, substituents are added to the enolate ion of acetoacetic ester. Then, hydrolysis takes place followed by decarboxylation to give alkylated derivatives of acetone.
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Organic Chemistry (9th Edition)
- How would you synthesize diketones starting from acetoacetic ester?arrow_forwardDraw the product you would expect from the reaction of benzoic acid with 3-methyl-1-butanol. p-toluenesulfonic acid is the catalyst in the reactionsarrow_forwardDraw the products of the following hydrolysis. Н CH2 "CHз О—Н Нзс Нarrow_forward
- 5. Make the following via acetoacetic ester synthesis. شد کاarrow_forwardName the product of the esterification reaction of the two compounds shown here HO, HO O benzyl propanoate O propyl benzoate O benzyl butanoate O butyl benzoatearrow_forwarddescribe how steric and electronic effects influence the postion of equilibrium when the electrophilic center of an aldehyde or ketone is under nucleophilic attack.arrow_forward
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- Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning