Essential Organic Chemistry (3rd Edition)
3rd Edition
ISBN: 9780321937711
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Question
Chapter 4.5, Problem 16P
Interpretation Introduction
Interpretation:
The compounds exist as enantiomers from the given list of compounds have to be identified.
Concept introduction:
Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity.
Enantiomers are stereoisomers of compounds having one asymmetric center, in which these isomers are non-superimposable mirror images of each other.
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5. Consider the following pairs of structures. Identify the relationship between them
(enantiomers, diastereomers, or identical compounds.
HOH2C
H OH H OH
HO H
Br
H3C
Н
H
H₂CH₂C CI
Br
H
CHO
CH3
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CH3
OH
OHC
Н
H OH H OH
Bell!!
H3C,
HO H
Н.С
H
CH₂CH3
CH3
CI
HỌ,H
CH₂OH
Br
are these enantiomers, diastereomers,
constitutional isomers, or not isomeric.
I
F
II
State how each pair of compounds is related. Are they enantiomers, diastereomers, constitutional isomers, or identical?
Chapter 4 Solutions
Essential Organic Chemistry (3rd Edition)
Ch. 4.1 - Draw the cis and trans isomers for the following:...Ch. 4.1 - Prob. 4PCh. 4.1 - Prob. 5PCh. 4.1 - Prob. 6PCh. 4.2 - Prob. 7PCh. 4.2 - Tamoxifen slows the growth of some breast tumors...Ch. 4.2 - Draw and label the E and Z isomers for each of the...Ch. 4.2 - Prob. 10PCh. 4.2 - Name each of the following:Ch. 4.2 - Draw the structure of (Z)-2,3-dimethyl-3-heptene.
Ch. 4.3 - Prob. 13PCh. 4.4 - Prob. 14PCh. 4.5 - Prob. 16PCh. 4.6 - Prob. 17PCh. 4.7 - Assign relative priorities to the groups or atoms...Ch. 4.7 - Name the following:Ch. 4.7 - Prob. 22PCh. 4.7 - Draw a perspective formula for each of the...Ch. 4.8 - Prob. 24PCh. 4.8 - Prob. 27PCh. 4.9 - Prob. 28PCh. 4.9 - Prob. 29PCh. 4.9 - Prob. 30PCh. 4.10 - Prob. 31PCh. 4.10 - Prob. 32PCh. 4.10 - Prob. 33PCh. 4.11 - Prob. 34PCh. 4.11 - a. Draw the stereoisomers of...Ch. 4.11 - Prob. 37PCh. 4.11 - Prob. 38PCh. 4.12 - Which of the following compounds has a...Ch. 4.12 - Draw all the stereoisomers for each of the...Ch. 4.12 - Limonene exists as two different stereoisomers....Ch. 4 - a. Draw three constitutional isomers with...Ch. 4 - Which of the following have an asymmetric center?...Ch. 4 - Prob. 45PCh. 4 - Prob. 46PCh. 4 - Of all the possible cyclooctanes that have one...Ch. 4 - Prob. 48PCh. 4 - Prob. 49PCh. 4 - Prob. 50PCh. 4 - Prob. 51PCh. 4 - Prob. 52PCh. 4 - Draw the stereoisomers of 2,4-dichlorohexane....Ch. 4 - Prob. 54PCh. 4 - Prob. 55PCh. 4 - Prob. 56PCh. 4 - Prob. 57PCh. 4 - Prob. 58PCh. 4 - Prob. 59PCh. 4 - Prob. 60PCh. 4 - Prob. 61PCh. 4 - Prob. 62PCh. 4 - Draw structures for each of the following: a....Ch. 4 - Prob. 64PCh. 4 - a. Draw all the isomers with molecular formula...Ch. 4 - Prob. 66PCh. 4 - Prob. 67PCh. 4 - Prob. 68PCh. 4 - Chloramphenicol is a broad-spectrum antibiotic...
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- 2. Identify whether each pair of compounds are enantiomers or diastereomers: OH OH OHarrow_forwardWhat is the percent enantiomeric excess (ee) of a mixture that has 86% of one enantiomer and 14% of the other? 100% 43% 4% O 14% O 72% 614%arrow_forwardIs this a diastereomeric pair or enantiomers?arrow_forward
- The following two molecules are? H. CH3 H3C CH Br CH2OH Br The same molecule Enantiomers Constitutional Isomers Diastereomersarrow_forward7) Which of the following terms best describes the pair of compounds shown: enantiomers,_ diastereomers, or the same compound? CH3 H C OH 3arrow_forwardWhich of the following compounds represent enantiomers: * CH,OH H OH CH H OH CH HO CH, HO H H H H CH, HO CH H,C H CH IV O Il and II O I and IV O Il and II O I and IVarrow_forward
- Do the following structures represent identical compounds or a pair of enantiomers?arrow_forward5. Consider the following pairs of structures. Identify the relationship between them (enantiomers, diastereomers, or identical compounds. он HO o CH,OH H,C H но CH,OH сон H HO. HO CH, HO,C CH COH HO,C, CO,H CO,H н онн он н онн он HOH,C сно OHC CH,OH Br CH,CH, H,CH,C CI CH OHarrow_forward8. Identify the following sets of compounds as enantiomers, diastereomers, or identical. Relationship Between Compounds (enantiomers, diastereomers, or identical)?arrow_forward
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