Concept explainers
a.
Interpretation:
Structure of a D-aldotriose has to be given.
Concept Introduction:
Simplest carbohydrates are known as monosaccharides. They contain three to six carbons generally in a chain form with a carbonyl group present in the terminal or the adjacent carbon atom from the terminal. Monosaccharides that have the carbonyl group at the terminal carbon atom
The number of carbon atoms present in the chain characterize the monosaccharide. They are given below.
- Carbon chain with three carbon atoms is triose.
- Carbon chain with four carbon atoms is tetrose.
- Carbon chain with five carbon atoms is as pentose.
- Carbon chain with six carbon atoms is as hexose.
A carbon atom that is bonded to four different groups is known as a chiral carbon atom. This can rotate the plane polarized light. D- and L- isomers of monosaccharide can be identified by looking into the chiral center that is farther from the carbonyl group. In a Fischer projection, if the
b.
Interpretation:
Structure of a L-ketohexose has to be given.
Concept Introduction:
Refer part “a.”.
c.
Interpretation:
Structure of a four-carbon aldonic acid has to be given.
Concept Introduction:
Carbohydrates also undergo oxidation. Monosaccharides that are aldoses contains an
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Principles of General, Organic, Biological Chemistry
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