Concept explainers
Interpretation:
The complete and detailed mechanism for the formation of the imine from the aldehyde in Equation 18-18 is to be drawn.
Concept introduction:
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Organic Chemistry: Principles and Mechanisms (Second Edition)
- The Gabriel synthesis of primary amines discussed in Chapter 20 involves hydrolysis under basic conditions to release the amine. As shown in the reactions below, the amine can also be released by (a) hydrolysis under acidic conditions and (b) treatment with hydrazine. Draw the complete, detailed mechanisms for these reactions.arrow_forwardAspirin (acetylsalicylic acid) is made by treating salicylic acid with acetic anhydride. Draw the complete, detailed mechanism for this reaction and draw the product.arrow_forwardDraw a complete, detailed mechanism for the following reaction. A key intermediate is provided.arrow_forward
- Draw the complete, detailed mechanism for the following reaction.arrow_forwardThe Gabriel–malonic ester synthesis, shown here, is used to make α-amino acids. Draw complete, detailed mechanisms for this set of reactions and draw the structure of the intermediate A.arrow_forwardAn imino chloride can be prepared from an amide according to the reaction shown here. Propose a mechanism for this reaction.arrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning