The equations that corresponds to the expected products of given enamination alkylation and the final products expected after hydrolysis of the iminium salts are to be stated Concept introduction: In Stork enamine alkylation, an enamine adds to the α , β -unsaturated carbonyl compounds. This reaction is similar to Michael addition. Hydrolysis of the enamine gives ketone .

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 22, Problem 22.78SP

(a)

Interpretation Introduction

Interpretation:

The equations that corresponds to the expected products of given enamination alkylation and the final products expected after hydrolysis of the iminium salts are to be stated

Concept introduction:

In Stork enamine alkylation, an enamine adds to the α,β-unsaturated carbonyl compounds. This reaction is similar to Michael addition. Hydrolysis of the enamine gives ketone.

(b)

Interpretation Introduction

Interpretation:

The equations that corresponds to the expected products of given enamination alkylation and the final products expected after hydrolysis of the iminium salts are to be stated

Concept introduction:

In Stork enamine alkylation, an enamine adds to the α,β-unsaturated carbonyl compounds. This reaction is similar to Michael addition. Hydrolysis of the enamine gives ketone.

(c)

Interpretation Introduction

Interpretation:

The equations that corresponds to the expected products of given enamination alkylation and the final products expected after hydrolysis of the iminium salts are to be stated

Concept introduction:

In Stork enamine alkylation, an enamine adds to the α,β-unsaturated carbonyl compounds. This reaction is similar to Michael addition. Hydrolysis of the enamine gives ketone.

(d)

Interpretation Introduction

Interpretation:

The equations that corresponds to the expected products of given enamination alkylation and the final products expected after hydrolysis of the iminium salts are to be stated

Concept introduction:

In Stork enamine alkylation, an enamine adds to the α,β-unsaturated carbonyl compounds. This reaction is similar to Michael addition. Hydrolysis of the enamine gives ketone.

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Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 22, Problem 22.78SP

(a)

Interpretation Introduction

Interpretation:

The equations that corresponds to the expected products of given enamination alkylation and the final products expected after hydrolysis of the iminium salts are to be stated

Concept introduction:

In Stork enamine alkylation, an enamine adds to the α,β-unsaturated carbonyl compounds. This reaction is similar to Michael addition. Hydrolysis of the enamine gives ketone.

(b)

Interpretation Introduction

Interpretation:

The equations that corresponds to the expected products of given enamination alkylation and the final products expected after hydrolysis of the iminium salts are to be stated

Concept introduction:

In Stork enamine alkylation, an enamine adds to the α,β-unsaturated carbonyl compounds. This reaction is similar to Michael addition. Hydrolysis of the enamine gives ketone.

(c)

Interpretation Introduction

Interpretation:

The equations that corresponds to the expected products of given enamination alkylation and the final products expected after hydrolysis of the iminium salts are to be stated

Concept introduction:

In Stork enamine alkylation, an enamine adds to the α,β-unsaturated carbonyl compounds. This reaction is similar to Michael addition. Hydrolysis of the enamine gives ketone.

(d)

Interpretation Introduction

Interpretation:

The equations that corresponds to the expected products of given enamination alkylation and the final products expected after hydrolysis of the iminium salts are to be stated

Concept introduction:

In Stork enamine alkylation, an enamine adds to the α,β-unsaturated carbonyl compounds. This reaction is similar to Michael addition. Hydrolysis of the enamine gives ketone.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 22, Problem 22.78SP

(a)

Interpretation Introduction

Interpretation:

The equations that corresponds to the expected products of given enamination alkylation and the final products expected after hydrolysis of the iminium salts are to be stated

Concept introduction:

In Stork enamine alkylation, an enamine adds to the α,β-unsaturated carbonyl compounds. This reaction is similar to Michael addition. Hydrolysis of the enamine gives ketone.

(b)

Interpretation Introduction

Interpretation:

The equations that corresponds to the expected products of given enamination alkylation and the final products expected after hydrolysis of the iminium salts are to be stated

Concept introduction:

In Stork enamine alkylation, an enamine adds to the α,β-unsaturated carbonyl compounds. This reaction is similar to Michael addition. Hydrolysis of the enamine gives ketone.

(c)

Interpretation Introduction

Interpretation:

The equations that corresponds to the expected products of given enamination alkylation and the final products expected after hydrolysis of the iminium salts are to be stated

Concept introduction:

In Stork enamine alkylation, an enamine adds to the α,β-unsaturated carbonyl compounds. This reaction is similar to Michael addition. Hydrolysis of the enamine gives ketone.

(d)

Interpretation Introduction

Interpretation:

The equations that corresponds to the expected products of given enamination alkylation and the final products expected after hydrolysis of the iminium salts are to be stated

Concept introduction:

In Stork enamine alkylation, an enamine adds to the α,β-unsaturated carbonyl compounds. This reaction is similar to Michael addition. Hydrolysis of the enamine gives ketone.

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 22, Problem 22.78SP

(a)

Interpretation Introduction

Interpretation:

The equations that corresponds to the expected products of given enamination alkylation and the final products expected after hydrolysis of the iminium salts are to be stated

Concept introduction:

In Stork enamine alkylation, an enamine adds to the α,β-unsaturated carbonyl compounds. This reaction is similar to Michael addition. Hydrolysis of the enamine gives ketone.

(b)

Interpretation Introduction

Interpretation:

The equations that corresponds to the expected products of given enamination alkylation and the final products expected after hydrolysis of the iminium salts are to be stated

Concept introduction:

In Stork enamine alkylation, an enamine adds to the α,β-unsaturated carbonyl compounds. This reaction is similar to Michael addition. Hydrolysis of the enamine gives ketone.

(c)

Interpretation Introduction

Interpretation:

The equations that corresponds to the expected products of given enamination alkylation and the final products expected after hydrolysis of the iminium salts are to be stated

Concept introduction:

In Stork enamine alkylation, an enamine adds to the α,β-unsaturated carbonyl compounds. This reaction is similar to Michael addition. Hydrolysis of the enamine gives ketone.

(d)

Interpretation Introduction

Interpretation:

The equations that corresponds to the expected products of given enamination alkylation and the final products expected after hydrolysis of the iminium salts are to be stated

Concept introduction:

In Stork enamine alkylation, an enamine adds to the α,β-unsaturated carbonyl compounds. This reaction is similar to Michael addition. Hydrolysis of the enamine gives ketone.

Expert Solution & Answer

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Answer 5

Chapter 22, Problem 22.78SP

(a)

Interpretation Introduction

Interpretation:

The equations that corresponds to the expected products of given enamination alkylation and the final products expected after hydrolysis of the iminium salts are to be stated

Concept introduction:

In Stork enamine alkylation, an enamine adds to the α,β-unsaturated carbonyl compounds. This reaction is similar to Michael addition. Hydrolysis of the enamine gives ketone.

(b)

Interpretation Introduction

Interpretation:

The equations that corresponds to the expected products of given enamination alkylation and the final products expected after hydrolysis of the iminium salts are to be stated

Concept introduction:

In Stork enamine alkylation, an enamine adds to the α,β-unsaturated carbonyl compounds. This reaction is similar to Michael addition. Hydrolysis of the enamine gives ketone.

(c)

Interpretation Introduction

Interpretation:

The equations that corresponds to the expected products of given enamination alkylation and the final products expected after hydrolysis of the iminium salts are to be stated

Concept introduction:

In Stork enamine alkylation, an enamine adds to the α,β-unsaturated carbonyl compounds. This reaction is similar to Michael addition. Hydrolysis of the enamine gives ketone.

(d)

Interpretation Introduction

Interpretation:

The equations that corresponds to the expected products of given enamination alkylation and the final products expected after hydrolysis of the iminium salts are to be stated

Concept introduction:

In Stork enamine alkylation, an enamine adds to the α,β-unsaturated carbonyl compounds. This reaction is similar to Michael addition. Hydrolysis of the enamine gives ketone.

Answer 6

Chapter 22, Problem 22.78SP

(a)

Interpretation Introduction

Interpretation:

The equations that corresponds to the expected products of given enamination alkylation and the final products expected after hydrolysis of the iminium salts are to be stated

Concept introduction:

In Stork enamine alkylation, an enamine adds to the α,β-unsaturated carbonyl compounds. This reaction is similar to Michael addition. Hydrolysis of the enamine gives ketone.

Answer 7

Chapter 22, Problem 22.78SP

(a)

Interpretation Introduction

Interpretation:

The equations that corresponds to the expected products of given enamination alkylation and the final products expected after hydrolysis of the iminium salts are to be stated

Concept introduction:

In Stork enamine alkylation, an enamine adds to the α,β-unsaturated carbonyl compounds. This reaction is similar to Michael addition. Hydrolysis of the enamine gives ketone.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The equations that corresponds to the expected products of given enamination alkylation and the final products expected after hydrolysis of the iminium salts are to be stated

Concept introduction:

In Stork enamine alkylation, an enamine adds to the α,β-unsaturated carbonyl compounds. This reaction is similar to Michael addition. Hydrolysis of the enamine gives ketone.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The equations that corresponds to the expected products of given enamination alkylation and the final products expected after hydrolysis of the iminium salts are to be stated

Concept introduction:

In Stork enamine alkylation, an enamine adds to the α,β-unsaturated carbonyl compounds. This reaction is similar to Michael addition. Hydrolysis of the enamine gives ketone.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The equations that corresponds to the expected products of given enamination alkylation and the final products expected after hydrolysis of the iminium salts are to be stated

Concept introduction:

In Stork enamine alkylation, an enamine adds to the α,β-unsaturated carbonyl compounds. This reaction is similar to Michael addition. Hydrolysis of the enamine gives ketone.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The equations that corresponds to the expected products of given enamination alkylation and the final products expected after hydrolysis of the iminium salts are to be stated

Concept introduction:

In Stork enamine alkylation, an enamine adds to the α,β-unsaturated carbonyl compounds. This reaction is similar to Michael addition. Hydrolysis of the enamine gives ketone.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The equations that corresponds to the expected products of given enamination alkylation and the final products expected after hydrolysis of the iminium salts are to be stated

Concept introduction:

In Stork enamine alkylation, an enamine adds to the α,β-unsaturated carbonyl compounds. This reaction is similar to Michael addition. Hydrolysis of the enamine gives ketone.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The equations that corresponds to the expected products of given enamination alkylation and the final products expected after hydrolysis of the iminium salts are to be stated

Concept introduction:

In Stork enamine alkylation, an enamine adds to the α,β-unsaturated carbonyl compounds. This reaction is similar to Michael addition. Hydrolysis of the enamine gives ketone.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 22.2A - Prob. 22.2P Ch. 22.4 - Without looking back, propose a mechanism for the...Ch. 22.4 - Prob. 22.8P Ch. 22.4 - Prob. 22.9P Ch. 22.5A - Prob. 22.10P Ch. 22.5A - Prob. 22.11P Ch. 22.5B - Prob. 22.12P Ch. 22.5B - Predict the products of the following reactions....Ch. 22.5B - Which compounds will give positive iodoform tests?...Ch. 22.5C - Propose a mechanism for the acid-catalyzed...

Solution Summary: The author illustrates the equations that correspond to the expected products of given enamination alkylation and the final products expected after hydrolysis of the iminium salts.

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