Chemistry: Structure and Properties
1st Edition
ISBN: 9780321834683
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 23, Problem 57E
Interpretation Introduction
Introduction: Electronic configurations of elements can be reliably predicted with Aufbau principle.As the
To determine:
The ground state configuration of the following species of Cr and Cu which are exceptions to normal orbital filing
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20. Which absorbs photons of the longest
wavelength?
A. [COCI4]²-
B. [Co(H20)6]*
C. [Co(NH3)6]?*
D. [Cola]2-
Draw the d orbital diagram for the following molecules/ions and calculate CFSE energy.
a. Cr(H2O)62+
b. Co(NH3)62+
c. Mn(NH3)62+
d. NiI42-
e. Mn(CN)63-
f. PtCl42-
Which of the following orbitals will have the lowest (most negative) energy if we are considering the
5
20.
electron configuration for a transition metal?
А.
5s
4px
3dx2-y2
В.
С.
D.
4s
Е.
4fxyz
Chapter 23 Solutions
Chemistry: Structure and Properties
Ch. 23 - What is the electron configuration of the Cu+ ion?...Ch. 23 - Prob. 2SAQCh. 23 - Prob. 3SAQCh. 23 - Prob. 4SAQCh. 23 - Prob. 5SAQCh. 23 - Prob. 6SAQCh. 23 - Prob. 7SAQCh. 23 - Estimate the crystal field splitting energy (in...Ch. 23 - Use crystal field theory to determine the number...Ch. 23 - Prob. 10SAQ
Ch. 23 - When a transition metal atom forms an ion, which...Ch. 23 - Explain why transition metals exhibit multiple...Ch. 23 - Why is the +2 oxidation state so common for...Ch. 23 - Explain why atomic radii of elements in the third...Ch. 23 - Gold is the most electronegative transition metal....Ch. 23 - Prob. 6ECh. 23 - Prob. 7ECh. 23 - Explain the differences between each pair of...Ch. 23 - Prob. 9ECh. 23 - Prob. 10ECh. 23 - Prob. 11ECh. 23 - Prob. 12ECh. 23 - Prob. 13ECh. 23 - Prob. 14ECh. 23 - Prob. 15ECh. 23 - Prob. 16ECh. 23 - Prob. 17ECh. 23 - Write the ground state electron configuration for...Ch. 23 - Determine the highest possible oxidation state for...Ch. 23 - Prob. 20ECh. 23 - Prob. 21ECh. 23 - Prob. 22ECh. 23 - Prob. 23ECh. 23 - Prob. 24ECh. 23 - Prob. 25ECh. 23 - Prob. 26ECh. 23 - Prob. 27ECh. 23 - Write the formula and the name of each complex ion...Ch. 23 - Prob. 29ECh. 23 - Prob. 30ECh. 23 - Prob. 31ECh. 23 - Prob. 32ECh. 23 - Prob. 33ECh. 23 - Prob. 34ECh. 23 - Prob. 35ECh. 23 - Prob. 36ECh. 23 - Prob. 37ECh. 23 - Prob. 38ECh. 23 - Prob. 39ECh. 23 - Prob. 40ECh. 23 - Prob. 41ECh. 23 - Prob. 42ECh. 23 - Prob. 43ECh. 23 - Prob. 44ECh. 23 - Prob. 45ECh. 23 - Prob. 46ECh. 23 - Prob. 47ECh. 23 - Prob. 48ECh. 23 - Prob. 49ECh. 23 - Prob. 50ECh. 23 - Prob. 51ECh. 23 - Prob. 52ECh. 23 - Prob. 53ECh. 23 - Prob. 54ECh. 23 - Prob. 55ECh. 23 - Prob. 56ECh. 23 - Prob. 57ECh. 23 - Most of the second-row transition metals do not...Ch. 23 - Prob. 59ECh. 23 - Prob. 60ECh. 23 - Prob. 61ECh. 23 - Prob. 62ECh. 23 - Prob. 63ECh. 23 - Prob. 64ECh. 23 - Hexacyanomanganate(III) ion is a low-spin complex....Ch. 23 - Prob. 66ECh. 23 - Prob. 67ECh. 23 - Prob. 68ECh. 23 - Prob. 69ECh. 23 - Prob. 70ECh. 23 - Prob. 71ECh. 23 - Prob. 72ECh. 23 - Prob. 73ECh. 23 - Calculate the solubility of Zn(OH)2(s) in 2.0 M...Ch. 23 - Prob. 75ECh. 23 - Prob. 76ECh. 23 - Prob. 77ECh. 23 - Prob. 78ECh. 23 - Prob. 79ECh. 23 - Prob. 80E
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- Would you expect the Mg3[Cr(CN)5]2 to be diamagnetic or paramagnetic? Explain your reasoning.arrow_forwardDraw the d orbital diagram for the following molecules/ions and calculate CFSE energy. d. NiI42- e. Mn(CN)63- f. PtCl42-arrow_forwardQ 1: Iron as for a transition metal and it can adopt different oxidation states.One of the most common oxidation state for Fe is +2.How many unpaired electrons are there in their electronic configuration of Fe in the ground state? enquiry 1:PLEASE help me answer this questions and prove some detailed explanation,'Cause I don't quite get the meaning in this question. Q 2: Fe is able to form a bond with chloride with its d orbitals.Sketch a diagram to illustrate the overlap between orbitals Fe and Cl, and indicate the mode of orbital overlap. enquiry 2: Can you please explain what is called "d orbital "can be with some specific examples? Is there any other orbital besides it?Is there any relationship/different between different orbital? What is the specific meaning of overlapping orbits and what does it will do? Why do orbits will be overlap, and does overlap have any meaning between the elements?Is there any other mode besides overlap can be example?arrow_forward
- 4 Illustrate how complex formation between Fe³* and SCN occurs by presenting electrons by arrows (1) in two colors (one color for Fe³+ and another color for SCN) in the orbital diagram below (only from 3d-orbital of Fe³+) 3d 4s 4parrow_forwardThe electronic configuration of 15 X 3- ion is a. [Ne]3s23p2 b. [Ne]3s2 c. [Ne]3s23p6 d. [Ne]3s23p1arrow_forwardWhich of the following is the electronic configuration of the Chromium(III)? Cr3+ [Ar] 3d3 .a O Cr3+ [Ar] 4s1 3d5 .BO Cr3+ [Ar] 4s2 3d4. .CO C3+ [Ar] 3d° DOarrow_forward
- Square planar complexes are often associated with: а. d3 configuration b. High spin d4 configuration С. d® configuration d. low spin d4 configurationarrow_forwardChemistry With respect to the selection rules, transitions in [Cu(OH2)6]2+ are… a. Spin- and Laporte-allowed b. Spin- and Laporte-forbidden c. Spin-allowed only d. Laporte-allowed onlyarrow_forwardWrite the ground-state electron configuration for each atomand ion pair. Ni, Ni2+ b. Mn, Mn4+, Mn, Mn4+, Y, Y+?arrow_forward
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