Physical Chemistry
Physical Chemistry
3rd Edition
ISBN: 9780321812001
Author: ENGEL, Thomas/ Reid
Publisher: Pearson College Div
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Chapter 3, Problem 3.24NP
Interpretation Introduction

Interpretation: The differential dz = 2xydx + x2dy is to be shown as exact by integrating dz along the following paths:

  (1,1)(1,8)(6,8) and (1,1)(1,3)(4,3)(4,8)(6,8)

Concept Introduction: A differential is said to be exact only if the integral of the function is path independent. (Independent of path means that the system depends only on starting and finishing points and not on the path followed to reach the finishing point.) So,

for a differential, dz = f(x,y)dx + g(x,y)dy to be exact in then its integral f(x,y)dx + g(x,y)dy is independent of the path.

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