Physical Chemistry
Physical Chemistry
3rd Edition
ISBN: 9780321812001
Author: ENGEL, Thomas/ Reid
Publisher: Pearson College Div
Question
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Chapter 3, Problem 3.25NP
Interpretation Introduction

Interpretation:

This is to be proved that dρ/ρ=βdT+kdP where ρ is the density ρ=m/V , assuming mass m as constant.

Concept Introduction :

The equation for the isobaric volumetric expansion coefficient and isothermal compressibility are as follows:

  β=1V( V T)Pk=1V( V P)T

Here,

  β = isobaric volumetric expansion coefficient

k = isothermal compressibility

  V = change in volume

  P = change in pressure

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