Introduction To Quantum Mechanics
3rd Edition
ISBN: 9781107189638
Author: Griffiths, David J., Schroeter, Darrell F.
Publisher: Cambridge University Press
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Question
Chapter 3, Problem 3.41P
To determine
The maximum value of
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Consider the function
v(1,2) =(
[1s(1) 3s(2) + 3s(1) 1s(2)]
[x(1) B(2) + B(1) a(2)]
Which of the following statements is incorrect concerning p(1,2) ?
a.
W(1,2) is normalized.
Ob.
The function W(1,2) is symmetric with respect to the exchange of the space and the spin coordinates of the two electrons.
OC.
y(1,2) is an eigenfunction of the reference (or zero-order) Hamiltonian (in which the electron-electron repulsion term is ignored) of Li with
eigenvalue = -5 hartree.
d.
The function y(1,2) is an acceptable wave function to describe the properties of one of the excited states of Lit.
Oe.
The function 4(1,2) is an eigenfunction of the operator S,(1,2) = S;(1) + S,(2) with eigenvalue zero.
Determine the probability distribution function in the phase space for a relativistic
particle in a volume V and with energy ε(p) = √√√/m²c²+p²c², where p is the ab-
solute value of the momentum, m the mass, and c the speed of light. Give the final
result in terms of the modified Bessel functions
r+∞
Ky (z) = ™
(v-1)!
2
-zcosht
e cosh (vt) dt
Ky(z) ~
Check what happens in the limit ² →0.
mc²
kT
z 0.
Problem 1:
(a) A non-relativistic, free particle of mass m is bouncing back and forth between two perfectly reflecting
walls separated by a distance L. Imagine that the two oppositely directed matter waves associated with this
particle interfere to create a standing wave with a node at each of the walls. Find the kinetic energies of the
ground state (first harmonic, n = 1) and first excited state (second harmonic, n = 2). Find the formula for
the kinetic energy of the n-th harmonic.
(b) If an electron and a proton have the same non-relativistic kinetic energy, which particle has the larger
de Broglie wavelength?
(c) Find the de Broglie wavelength of an electron that is accelerated from rest through a small potential
difference V.
(d) If a free electron has a de Broglie wavelength equal to the diameter of Bohr's model of the hydrogen
atom (twice the Bohr radius), how does its kinetic energy compare to the ground-state energy of an electron
bound to a Bohr model hydrogen atom?
Chapter 3 Solutions
Introduction To Quantum Mechanics
Ch. 3.1 - Prob. 3.1PCh. 3.1 - Prob. 3.2PCh. 3.2 - Prob. 3.3PCh. 3.2 - Prob. 3.4PCh. 3.2 - Prob. 3.5PCh. 3.2 - Prob. 3.6PCh. 3.3 - Prob. 3.7PCh. 3.3 - Prob. 3.8PCh. 3.3 - Prob. 3.9PCh. 3.3 - Prob. 3.10P
Ch. 3.4 - Prob. 3.11PCh. 3.4 - Prob. 3.12PCh. 3.4 - Prob. 3.13PCh. 3.5 - Prob. 3.14PCh. 3.5 - Prob. 3.15PCh. 3.5 - Prob. 3.16PCh. 3.5 - Prob. 3.17PCh. 3.5 - Prob. 3.18PCh. 3.5 - Prob. 3.19PCh. 3.5 - Prob. 3.20PCh. 3.5 - Prob. 3.21PCh. 3.5 - Prob. 3.22PCh. 3.6 - Prob. 3.23PCh. 3.6 - Prob. 3.24PCh. 3.6 - Prob. 3.25PCh. 3.6 - Prob. 3.26PCh. 3.6 - Prob. 3.27PCh. 3.6 - Prob. 3.28PCh. 3.6 - Prob. 3.29PCh. 3.6 - Prob. 3.30PCh. 3 - Prob. 3.31PCh. 3 - Prob. 3.32PCh. 3 - Prob. 3.33PCh. 3 - Prob. 3.34PCh. 3 - Prob. 3.35PCh. 3 - Prob. 3.36PCh. 3 - Prob. 3.37PCh. 3 - Prob. 3.38PCh. 3 - Prob. 3.39PCh. 3 - Prob. 3.40PCh. 3 - Prob. 3.41PCh. 3 - Prob. 3.42PCh. 3 - Prob. 3.43PCh. 3 - Prob. 3.44PCh. 3 - Prob. 3.45PCh. 3 - Prob. 3.47PCh. 3 - Prob. 3.48P
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