Atkins' Physical Chemistry
Atkins' Physical Chemistry
11th Edition
ISBN: 9780198769866
Author: ATKINS, P. W. (peter William), De Paula, Julio, Keeler, JAMES
Publisher: Oxford University Press
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Chapter 4, Problem 4B.6BE
Interpretation Introduction

Interpretation: The temperature where the vapour pressure is 70.0kPa has to be calculated.

Concept introduction: Clausius-Clapeyron expression shows the correlation of pressure and temperature for the phase transition process.  Clausius-Clapeyron equation is shown below.

    ln(p2p1)=ΔHvaporizationR(1T21T1)

Where,

  • p1andp2 are the pressures at two different temperature T1andT2 respectively.
  • ΔHvaporization is the enthalpy of vaporization.

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