(a) Interpretation: The reason as to why the catalytic hydrogenation reaction of ( − ) -3-methyl-1-pentene results in the optically inactive product is to be stated. Concept introduction: A carbon atom that has four nonequivalent atoms or groups attached to it is known as the chiral carbon atom. Chiral carbon centers are also called asymmetric or stereogenic centers. The chiral atom sometimes results in the formation of enantiomers which are the non-superimposable mirror images of each other.

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Answer 1

Question

Chapter 6, Problem 6.47AP

Interpretation Introduction

(a)

Interpretation:

The reason as to why the catalytic hydrogenation reaction of (−)-3-methyl-1-pentene results in the optically inactive product is to be stated.

Concept introduction:

A carbon atom that has four nonequivalent atoms or groups attached to it is known as the chiral carbon atom. Chiral carbon centers are also called asymmetric or stereogenic centers. The chiral atom sometimes results in the formation of enantiomers which are the non-superimposable mirror images of each other.

Interpretation Introduction

(b)

Interpretation:

The absolute configuration of (+)-3-methylhexane is to be stated when catalytic hydrogenation of (S)-(+)-3-methyl-1-hexene gives (−)-3-methylhexane.

Concept introduction:

A carbon atom that has four nonequivalent atoms or groups attached to it is known as the chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. The chiral atom sometimes results in the formation of enantiomers which are the non-superimposable mirror images of each other.

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a) When (Z)-3-methylhex-3-ene undergoes hydroboration–oxidation, two isomeric products are formed. Give their structures, and label each asymmetric carbon atom as (R) or (S). What is the relationship between these isomers?

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Draw the structures of the following molecules: (a) (S)-sec-butylcyclopentane (b) p-benzyltoluene c) (Z)-5-phenyl-3-methyl-3-octene

Answer 2

Question

Chapter 6, Problem 6.47AP

Interpretation Introduction

(a)

Interpretation:

The reason as to why the catalytic hydrogenation reaction of (−)-3-methyl-1-pentene results in the optically inactive product is to be stated.

Concept introduction:

A carbon atom that has four nonequivalent atoms or groups attached to it is known as the chiral carbon atom. Chiral carbon centers are also called asymmetric or stereogenic centers. The chiral atom sometimes results in the formation of enantiomers which are the non-superimposable mirror images of each other.

Interpretation Introduction

(b)

Interpretation:

The absolute configuration of (+)-3-methylhexane is to be stated when catalytic hydrogenation of (S)-(+)-3-methyl-1-hexene gives (−)-3-methylhexane.

Concept introduction:

A carbon atom that has four nonequivalent atoms or groups attached to it is known as the chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. The chiral atom sometimes results in the formation of enantiomers which are the non-superimposable mirror images of each other.

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Answer 3

Question

Chapter 6, Problem 6.47AP

Interpretation Introduction

(a)

Interpretation:

The reason as to why the catalytic hydrogenation reaction of (−)-3-methyl-1-pentene results in the optically inactive product is to be stated.

Concept introduction:

A carbon atom that has four nonequivalent atoms or groups attached to it is known as the chiral carbon atom. Chiral carbon centers are also called asymmetric or stereogenic centers. The chiral atom sometimes results in the formation of enantiomers which are the non-superimposable mirror images of each other.

Interpretation Introduction

(b)

Interpretation:

The absolute configuration of (+)-3-methylhexane is to be stated when catalytic hydrogenation of (S)-(+)-3-methyl-1-hexene gives (−)-3-methylhexane.

Concept introduction:

A carbon atom that has four nonequivalent atoms or groups attached to it is known as the chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. The chiral atom sometimes results in the formation of enantiomers which are the non-superimposable mirror images of each other.

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Answer 4

Question

Chapter 6, Problem 6.47AP

Interpretation Introduction

(a)

Interpretation:

The reason as to why the catalytic hydrogenation reaction of (−)-3-methyl-1-pentene results in the optically inactive product is to be stated.

Concept introduction:

A carbon atom that has four nonequivalent atoms or groups attached to it is known as the chiral carbon atom. Chiral carbon centers are also called asymmetric or stereogenic centers. The chiral atom sometimes results in the formation of enantiomers which are the non-superimposable mirror images of each other.

Interpretation Introduction

(b)

Interpretation:

The absolute configuration of (+)-3-methylhexane is to be stated when catalytic hydrogenation of (S)-(+)-3-methyl-1-hexene gives (−)-3-methylhexane.

Concept introduction:

A carbon atom that has four nonequivalent atoms or groups attached to it is known as the chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. The chiral atom sometimes results in the formation of enantiomers which are the non-superimposable mirror images of each other.

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Answer 5

Chapter 6, Problem 6.47AP

Interpretation Introduction

(a)

Interpretation:

The reason as to why the catalytic hydrogenation reaction of (−)-3-methyl-1-pentene results in the optically inactive product is to be stated.

Concept introduction:

A carbon atom that has four nonequivalent atoms or groups attached to it is known as the chiral carbon atom. Chiral carbon centers are also called asymmetric or stereogenic centers. The chiral atom sometimes results in the formation of enantiomers which are the non-superimposable mirror images of each other.

Interpretation Introduction

(b)

Interpretation:

The absolute configuration of (+)-3-methylhexane is to be stated when catalytic hydrogenation of (S)-(+)-3-methyl-1-hexene gives (−)-3-methylhexane.

Concept introduction:

A carbon atom that has four nonequivalent atoms or groups attached to it is known as the chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. The chiral atom sometimes results in the formation of enantiomers which are the non-superimposable mirror images of each other.

Answer 6

Chapter 6, Problem 6.47AP

Interpretation Introduction

(a)

Interpretation:

The reason as to why the catalytic hydrogenation reaction of (−)-3-methyl-1-pentene results in the optically inactive product is to be stated.

Concept introduction:

A carbon atom that has four nonequivalent atoms or groups attached to it is known as the chiral carbon atom. Chiral carbon centers are also called asymmetric or stereogenic centers. The chiral atom sometimes results in the formation of enantiomers which are the non-superimposable mirror images of each other.

Answer 7

Chapter 6, Problem 6.47AP

Interpretation Introduction

(a)

Interpretation:

The reason as to why the catalytic hydrogenation reaction of (−)-3-methyl-1-pentene results in the optically inactive product is to be stated.

Concept introduction:

A carbon atom that has four nonequivalent atoms or groups attached to it is known as the chiral carbon atom. Chiral carbon centers are also called asymmetric or stereogenic centers. The chiral atom sometimes results in the formation of enantiomers which are the non-superimposable mirror images of each other.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The absolute configuration of (+)-3-methylhexane is to be stated when catalytic hydrogenation of (S)-(+)-3-methyl-1-hexene gives (−)-3-methylhexane.

Concept introduction:

A carbon atom that has four nonequivalent atoms or groups attached to it is known as the chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. The chiral atom sometimes results in the formation of enantiomers which are the non-superimposable mirror images of each other.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The absolute configuration of (+)-3-methylhexane is to be stated when catalytic hydrogenation of (S)-(+)-3-methyl-1-hexene gives (−)-3-methylhexane.

Concept introduction:

A carbon atom that has four nonequivalent atoms or groups attached to it is known as the chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. The chiral atom sometimes results in the formation of enantiomers which are the non-superimposable mirror images of each other.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 6 - Prob. 6.1P Ch. 6 - Prob. 6.2P Ch. 6 - Prob. 6.3P Ch. 6 - Prob. 6.4P Ch. 6 - Prob. 6.5P Ch. 6 - Prob. 6.6P Ch. 6 - Prob. 6.7P Ch. 6 - Prob. 6.8P Ch. 6 - Prob. 6.9P Ch. 6 - Prob. 6.10P

Solution Summary: The author explains the catalytic hydrogenation reaction of (-)-3-methyl-1-pentene produces an optically inactive product.

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