(a) Interpretation: The structure of the starting compound that gives the given product on oxidation with MnO 2 , is to be stated. Concept introduction: Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO 2 . In presence of MnO 2 , primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones .

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 17, Problem 17.11P

Interpretation Introduction

(a)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

Interpretation Introduction

(b)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

Interpretation Introduction

(c)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

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Acidified potassium bromate(V), KBrO3, reacts with hydrogen sulfide, H2S, to give a yellow solid and an orange solution. On shaking the solution with trichloroethane, the trichloroethane layer turned orange-red. (a) Suggest the identity of yellow solid and the orange solution. Describe the type of reaction taking place. (b) Construct a balanced equation for the reaction between KBrO3 and H2S. (C) BrO3- is the conjugate base of HBrO3. Draw the dot and cross structure of HBrO3. (d) HBr is a stronger acid than HCl. However, HBrO3 is a weaker acid than HCIO3. Explain the difference in acidities.

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Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 17, Problem 17.11P

Interpretation Introduction

(a)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

Interpretation Introduction

(b)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

Interpretation Introduction

(c)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 17, Problem 17.11P

Interpretation Introduction

(a)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

Interpretation Introduction

(b)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

Interpretation Introduction

(c)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

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Check out a sample textbook solution

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 17, Problem 17.11P

Interpretation Introduction

(a)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

Interpretation Introduction

(b)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

Interpretation Introduction

(c)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

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Answer 5

Chapter 17, Problem 17.11P

Interpretation Introduction

(a)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

Interpretation Introduction

(b)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

Interpretation Introduction

(c)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

Answer 6

Chapter 17, Problem 17.11P

Interpretation Introduction

(a)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

Answer 7

Chapter 17, Problem 17.11P

Interpretation Introduction

(a)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 17 - Prob. 17.1P Ch. 17 - Prob. 17.2P Ch. 17 - Prob. 17.3P Ch. 17 - Prob. 17.4P Ch. 17 - Prob. 17.5P Ch. 17 - Prob. 17.6P Ch. 17 - Prob. 17.7P Ch. 17 - Prob. 17.8P Ch. 17 - Prob. 17.9P Ch. 17 - Prob. 17.10P

Solution Summary: The author explains the structure of the starting compound that gives the given product on oxidation with MnO_ 2.

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