(a) Interpretation: The mechanism for formation of limonene from the given carbocation is to be stated. Concept introduction: Isoprene unit contains five carbon atoms. The carbon atoms of isoprene unit are connected by sigma bond or pi bond. Terpenes and terpenoids contain unequal number of isoprene units. Limonene contains a cyclic monoterpene unit. The oil extracted from citrus peels majorly contains limonene.

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Answer 1

Question

Chapter 17, Problem 17.18P

Interpretation Introduction

(a)

Interpretation:

The mechanism for formation of limonene from the given carbocation is to be stated.

Concept introduction:

Isoprene unit contains five carbon atoms. The carbon atoms of isoprene unit are connected by sigma bond or pi bond. Terpenes and terpenoids contain unequal number of isoprene units. Limonene contains a cyclic monoterpene unit. The oil extracted from citrus peels majorly contains limonene.

Interpretation Introduction

(b)

Interpretation:

The curved arrow mechanism for the synthesis of carbocation intermediate from a geranyl pyrophosphate is to be stated.

Concept introduction:

Isoprene unit contains five carbon atoms. The carbon atoms of isoprene unit are connected by sigma bond or pi bond. Terpenes and terpenoids contain unequal number of isoprene units. Limonene contains a cyclic monoterpene unit. The oil extracted from citrus peels majorly contains limonene.

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Answer 2

Question

Chapter 17, Problem 17.18P

Interpretation Introduction

(a)

Interpretation:

The mechanism for formation of limonene from the given carbocation is to be stated.

Concept introduction:

Isoprene unit contains five carbon atoms. The carbon atoms of isoprene unit are connected by sigma bond or pi bond. Terpenes and terpenoids contain unequal number of isoprene units. Limonene contains a cyclic monoterpene unit. The oil extracted from citrus peels majorly contains limonene.

Interpretation Introduction

(b)

Interpretation:

The curved arrow mechanism for the synthesis of carbocation intermediate from a geranyl pyrophosphate is to be stated.

Concept introduction:

Isoprene unit contains five carbon atoms. The carbon atoms of isoprene unit are connected by sigma bond or pi bond. Terpenes and terpenoids contain unequal number of isoprene units. Limonene contains a cyclic monoterpene unit. The oil extracted from citrus peels majorly contains limonene.

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Answer 3

Question

Chapter 17, Problem 17.18P

Interpretation Introduction

(a)

Interpretation:

The mechanism for formation of limonene from the given carbocation is to be stated.

Concept introduction:

Isoprene unit contains five carbon atoms. The carbon atoms of isoprene unit are connected by sigma bond or pi bond. Terpenes and terpenoids contain unequal number of isoprene units. Limonene contains a cyclic monoterpene unit. The oil extracted from citrus peels majorly contains limonene.

Interpretation Introduction

(b)

Interpretation:

The curved arrow mechanism for the synthesis of carbocation intermediate from a geranyl pyrophosphate is to be stated.

Concept introduction:

Isoprene unit contains five carbon atoms. The carbon atoms of isoprene unit are connected by sigma bond or pi bond. Terpenes and terpenoids contain unequal number of isoprene units. Limonene contains a cyclic monoterpene unit. The oil extracted from citrus peels majorly contains limonene.

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Answer 4

Question

Chapter 17, Problem 17.18P

Interpretation Introduction

(a)

Interpretation:

The mechanism for formation of limonene from the given carbocation is to be stated.

Concept introduction:

Isoprene unit contains five carbon atoms. The carbon atoms of isoprene unit are connected by sigma bond or pi bond. Terpenes and terpenoids contain unequal number of isoprene units. Limonene contains a cyclic monoterpene unit. The oil extracted from citrus peels majorly contains limonene.

Interpretation Introduction

(b)

Interpretation:

The curved arrow mechanism for the synthesis of carbocation intermediate from a geranyl pyrophosphate is to be stated.

Concept introduction:

Isoprene unit contains five carbon atoms. The carbon atoms of isoprene unit are connected by sigma bond or pi bond. Terpenes and terpenoids contain unequal number of isoprene units. Limonene contains a cyclic monoterpene unit. The oil extracted from citrus peels majorly contains limonene.

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Answer 5

Chapter 17, Problem 17.18P

Interpretation Introduction

(a)

Interpretation:

The mechanism for formation of limonene from the given carbocation is to be stated.

Concept introduction:

Isoprene unit contains five carbon atoms. The carbon atoms of isoprene unit are connected by sigma bond or pi bond. Terpenes and terpenoids contain unequal number of isoprene units. Limonene contains a cyclic monoterpene unit. The oil extracted from citrus peels majorly contains limonene.

Interpretation Introduction

(b)

Interpretation:

The curved arrow mechanism for the synthesis of carbocation intermediate from a geranyl pyrophosphate is to be stated.

Concept introduction:

Isoprene unit contains five carbon atoms. The carbon atoms of isoprene unit are connected by sigma bond or pi bond. Terpenes and terpenoids contain unequal number of isoprene units. Limonene contains a cyclic monoterpene unit. The oil extracted from citrus peels majorly contains limonene.

Answer 6

Chapter 17, Problem 17.18P

Interpretation Introduction

(a)

Interpretation:

The mechanism for formation of limonene from the given carbocation is to be stated.

Concept introduction:

Isoprene unit contains five carbon atoms. The carbon atoms of isoprene unit are connected by sigma bond or pi bond. Terpenes and terpenoids contain unequal number of isoprene units. Limonene contains a cyclic monoterpene unit. The oil extracted from citrus peels majorly contains limonene.

Answer 7

Chapter 17, Problem 17.18P

Interpretation Introduction

(a)

Interpretation:

The mechanism for formation of limonene from the given carbocation is to be stated.

Concept introduction:

Isoprene unit contains five carbon atoms. The carbon atoms of isoprene unit are connected by sigma bond or pi bond. Terpenes and terpenoids contain unequal number of isoprene units. Limonene contains a cyclic monoterpene unit. The oil extracted from citrus peels majorly contains limonene.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The curved arrow mechanism for the synthesis of carbocation intermediate from a geranyl pyrophosphate is to be stated.

Concept introduction:

Isoprene unit contains five carbon atoms. The carbon atoms of isoprene unit are connected by sigma bond or pi bond. Terpenes and terpenoids contain unequal number of isoprene units. Limonene contains a cyclic monoterpene unit. The oil extracted from citrus peels majorly contains limonene.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The curved arrow mechanism for the synthesis of carbocation intermediate from a geranyl pyrophosphate is to be stated.

Concept introduction:

Isoprene unit contains five carbon atoms. The carbon atoms of isoprene unit are connected by sigma bond or pi bond. Terpenes and terpenoids contain unequal number of isoprene units. Limonene contains a cyclic monoterpene unit. The oil extracted from citrus peels majorly contains limonene.

Answer 10

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Answer 12

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Answer 13

Ch. 17 - Prob. 17.1P Ch. 17 - Prob. 17.2P Ch. 17 - Prob. 17.3P Ch. 17 - Prob. 17.4P Ch. 17 - Prob. 17.5P Ch. 17 - Prob. 17.6P Ch. 17 - Prob. 17.7P Ch. 17 - Prob. 17.8P Ch. 17 - Prob. 17.9P Ch. 17 - Prob. 17.10P

Solution Summary: The author explains the mechanism for formation of limonene from the given carbocation.

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