Introduction To Quantum Mechanics
3rd Edition
ISBN: 9781107189638
Author: Griffiths, David J., Schroeter, Darrell F.
Publisher: Cambridge University Press
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Question
Chapter 2, Problem 2.46P
To determine
The allowed energies corresponding to the stationary states and the basis for degeneracy.
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(A) Consider a particle in a cubic box. What is the degeneracy of the level it hasenergy three times greater than that of the lowest level? (Explain the combinations of n that led you to the answer given).
(B) The addition of sodium to ammonia generates a solvated electron that is trapped in a cavity of 0.3 nm in diameter, formed by ammonia molecules. The solvated electron can be modeled as a particle that moves freely inside the cubic box with ammonia molecules in the cube surface. If the length of the box is 0.3 nm, what energy is needed for the electron undergo a transition from a lower energy state to the subsequent state?
(b) If a micro-system is in a state [a), then we can expand [a) using the orthogonal-
normalized eigenvectors of the operator F for the discrete and continuous system
respectively
|a) = [c₁|f)}df
i. show that c₂ = (ia)
ii. show that cf = (fla)
|a) = Σli),
i=1
A point particle moves in space under the influence of a force derivablefrom a generalized potential of the formU(r, v) = V (r) + σ · L,where r is the radius vector from a fixed point, L is the angular momentumabout that point, and σ is the fixed vector in space.
Find the components of the force on the particle in Cartesian coordinates, on the basis of the equation for the components of the generalized force Qj:
Qj = −∂U/∂qj + d/dt (∂U/∂q˙j)
Chapter 2 Solutions
Introduction To Quantum Mechanics
Ch. 2.1 - Prob. 2.1PCh. 2.1 - Prob. 2.2PCh. 2.2 - Prob. 2.3PCh. 2.2 - Prob. 2.4PCh. 2.2 - Prob. 2.5PCh. 2.2 - Prob. 2.6PCh. 2.2 - Prob. 2.7PCh. 2.2 - Prob. 2.8PCh. 2.2 - Prob. 2.9PCh. 2.3 - Prob. 2.10P
Ch. 2.3 - Prob. 2.11PCh. 2.3 - Prob. 2.12PCh. 2.3 - Prob. 2.13PCh. 2.3 - Prob. 2.14PCh. 2.3 - Prob. 2.15PCh. 2.3 - Prob. 2.16PCh. 2.4 - Prob. 2.17PCh. 2.4 - Prob. 2.18PCh. 2.4 - Prob. 2.19PCh. 2.4 - Prob. 2.20PCh. 2.4 - Prob. 2.21PCh. 2.5 - Prob. 2.22PCh. 2.5 - Prob. 2.23PCh. 2.5 - Prob. 2.24PCh. 2.5 - Prob. 2.25PCh. 2.5 - Prob. 2.26PCh. 2.5 - Prob. 2.27PCh. 2.5 - Prob. 2.28PCh. 2.6 - Prob. 2.29PCh. 2.6 - Prob. 2.30PCh. 2.6 - Prob. 2.31PCh. 2.6 - Prob. 2.32PCh. 2.6 - Prob. 2.34PCh. 2.6 - Prob. 2.35PCh. 2 - Prob. 2.36PCh. 2 - Prob. 2.37PCh. 2 - Prob. 2.38PCh. 2 - Prob. 2.39PCh. 2 - Prob. 2.40PCh. 2 - Prob. 2.41PCh. 2 - Prob. 2.42PCh. 2 - Prob. 2.44PCh. 2 - Prob. 2.45PCh. 2 - Prob. 2.46PCh. 2 - Prob. 2.47PCh. 2 - Prob. 2.49PCh. 2 - Prob. 2.50PCh. 2 - Prob. 2.51PCh. 2 - Prob. 2.52PCh. 2 - Prob. 2.53PCh. 2 - Prob. 2.54PCh. 2 - Prob. 2.58PCh. 2 - Prob. 2.63PCh. 2 - Prob. 2.64P
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