General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Chapter 3, Problem 3.88SP
Interpretation Introduction
Interpretation:
The total energy change during formation of calciumchloride from calciumand chlorinehas to be calculated.
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Given the following enthalpy values for Na and Cl, calculate the lattice energy of NaCl using the Born-
Haber cycle.
for Na = 107.5 kJ/mole
for Na = 495.8 kJ/mole
for Cl, = 242.6 kJ/mole
AHO
sublimation
AH
ionization energy
AHO
dissociation energy
ΔΗΡ
electron affinity TOr Cl, = -348.6 kJ/mole
AH
formation
for NaCl(s) = -4l1.2 kJ/mole
P
00
R
Consider an ionic compound, MX, composed of generic metal M and generic, gaseous halogen X.
• The enthalpy of formation of MX is AH; = -477 kJ/mol.
• The enthalpy of sublimation of M is AHsub = 157 kJ/mol.
• The ionization energy of M is IE = 435 kJ/mol.
• The electron affinity of X is AHEA = -303 kJ/mol. (Refer to the hint).
• The bond energy of X, is BE = 165 kJ/mol.
Determine the lattice energy of MX.
AHjattice
kJ/mol
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Consider an ionic compound, MX, composed of generic metal M and generic, gaseous halogen X.
• The enthalpy of formation of MX is AH;
= -513 kJ/mol.
• The enthalpy of sublimation of M is AHsub =
123 kJ/mol.
• The ionization energy of M is IE
= 465 kJ/mol.
• The electron affinity of X is AHEA
= -325 kJ/mol. (Refer to the hint).
• The bond energy of X, is BE =
187 kJ/mol.
Determine the lattice energy of MX.
AHjattice
-795.5
kJ/mol
Incorrect
Chapter 3 Solutions
General Chemistry: Atoms First
Ch. 3.1 - Prob. 3.1PCh. 3.1 - Which of the following drawings is most likely to...Ch. 3.2 - Give systematic names for the following compounds:...Ch. 3.2 - Write formulas for the following compounds: (a)...Ch. 3.2 - Prob. 3.5CPCh. 3.2 - Give systematic names for the following compounds:...Ch. 3.2 - Prob. 3.7PCh. 3.2 - Prob. 3.8CPCh. 3.3 - Predict the ground-state electron configuration...Ch. 3.3 - What doubly positive ion has the following...
Ch. 3.4 - Prob. 3.11PCh. 3.4 - which of the following spheres represents a K+...Ch. 3.5 - Using the periodic table as your guide, predict...Ch. 3.6 - (a) Which has the larger third ionization energy,...Ch. 3.6 - Three atoms have the following electron...Ch. 3.6 - Order the indicated three elements according to...Ch. 3.7 - Prob. 3.17PCh. 3.7 - Which of the indicated three elements has the...Ch. 3.8 - What noble-gas configurations are the following...Ch. 3.8 - Prob. 3.20PCh. 3.9 - Calculate the net energy change in kilojoules per...Ch. 3.10 - Which substance in each of the following pairs has...Ch. 3.10 - One of the following pictures represents NaCl and...Ch. 3.11 - Prob. 3.24PCh. 3.11 - Complete the following equations so that the same...Ch. 3.12 - Prob. 3.26PCh. 3.12 - Prob. 3.27PCh. 3.14 - Prob. 3.28PCh. 3 - In the following drawings, red spheres represent...Ch. 3 - Which of the following drawings is more likely to...Ch. 3 - Prob. 3.31CPCh. 3 - Prob. 3.32CPCh. 3 - Prob. 3.33CPCh. 3 - Prob. 3.34CPCh. 3 - Prob. 3.35CPCh. 3 - Prob. 3.36CPCh. 3 - Prob. 3.37CPCh. 3 - Prob. 3.38SPCh. 3 - Prob. 3.39SPCh. 3 - Prob. 3.40SPCh. 3 - Prob. 3.41SPCh. 3 - Prob. 3.42SPCh. 3 - Prob. 3.43SPCh. 3 - Prob. 3.44SPCh. 3 - Prob. 3.45SPCh. 3 - Prob. 3.46SPCh. 3 - Prob. 3.47SPCh. 3 - Prob. 3.48SPCh. 3 - Prob. 3.49SPCh. 3 - Prob. 3.50SPCh. 3 - Prob. 3.51SPCh. 3 - Prob. 3.52SPCh. 3 - What is the identity of the element X in the...Ch. 3 - Prob. 3.54SPCh. 3 - Prob. 3.55SPCh. 3 - Prob. 3.56SPCh. 3 - Prob. 3.57SPCh. 3 - Prob. 3.58SPCh. 3 - Prob. 3.59SPCh. 3 - Prob. 3.60SPCh. 3 - Prob. 3.61SPCh. 3 - Prob. 3.62SPCh. 3 - Prob. 3.63SPCh. 3 - Prob. 3.64SPCh. 3 - Prob. 3.65SPCh. 3 - Prob. 3.66SPCh. 3 - Prob. 3.67SPCh. 3 - Which element in each of the following sets has...Ch. 3 - Prob. 3.69SPCh. 3 - Prob. 3.70SPCh. 3 - Prob. 3.71SPCh. 3 - Prob. 3.72SPCh. 3 - Prob. 3.73SPCh. 3 - Prob. 3.74SPCh. 3 - Prob. 3.75SPCh. 3 - Prob. 3.76SPCh. 3 - Prob. 3.77SPCh. 3 - Prob. 3.78SPCh. 3 - Order the following compounds according to their...Ch. 3 - Calculate the energy change in kilojoules per mole...Ch. 3 - Prob. 3.81SPCh. 3 - Prob. 3.82SPCh. 3 - Prob. 3.83SPCh. 3 - Prob. 3.84SPCh. 3 - Prob. 3.85SPCh. 3 - Calculate the overall energy change in kilojoules...Ch. 3 - The estimated lattice energy for CsF2(s) is +2347...Ch. 3 - Prob. 3.88SPCh. 3 - Prob. 3.89SPCh. 3 - Prob. 3.90SPCh. 3 - Prob. 3.91SPCh. 3 - Prob. 3.92SPCh. 3 - Prob. 3.93SPCh. 3 - Prob. 3.94SPCh. 3 - Prob. 3.95SPCh. 3 - Prob. 3.96SPCh. 3 - Prob. 3.97SPCh. 3 - Prob. 3.98SPCh. 3 - Prob. 3.99SPCh. 3 - Prob. 3.100CHPCh. 3 - Prob. 3.101CHPCh. 3 - Prob. 3.102CHPCh. 3 - Prob. 3.103CHPCh. 3 - Prob. 3.104CHPCh. 3 - Prob. 3.105CHPCh. 3 - Prob. 3.106CHPCh. 3 - Prob. 3.107CHPCh. 3 - Prob. 3.108CHPCh. 3 - Prob. 3.109CHPCh. 3 - Prob. 3.110CHPCh. 3 - Prob. 3.111CHPCh. 3 - Prob. 3.112CHPCh. 3 - Prob. 3.113CHPCh. 3 - Prob. 3.114CHPCh. 3 - Given the following information, construct a...Ch. 3 - Given the following information, construct a...Ch. 3 - Consider the electronic structure of the element...Ch. 3 - Prob. 3.118MPCh. 3 - Prob. 3.119MP
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- Compare the electron affinity of fluorine to the ionization energy of sodium. Does the process of an electron being pulled from the sodium atom to the fluorine atom have a negative or a positive E? Why is NaF a stable compound? Does the overall formation of NaF have a negative or a positive E? How can this be?arrow_forwardIN Consider an ionic compound, MX, composed of generic metal M and generic, gaseous halogen X. • The enthalpy of formation of MX is AH; = -439 kJ/mol. • The enthalpy of sublimation of M is AHgub = 127 kJ/mol. • The ionization energy of M is IE = 433 kJ/mol. • The electron affinity of X is AHEA = -303 kJ/mol, (Refer to the hint). • The bond energy of X, is BE = 183 kJ/mol. Determine the lattice energy of MX. kJ/mol AHjattice = MacBook Pro 080 24 7. 6. 5. P. 4. K. H B. C.arrow_forwardConsider an ionic compound, MX, composed of generic metal M and generic, gaseous halogen X. • The enthalpy of formation of MX is AH; -517 kJ/mol. • The enthalpy of sublimation of M is AH sub = 141 kJ/mol. • The ionization energy of M is IE = 449 kJ/mol. • The electron affinity of X is AHEA = -323 kJ/mol. (Refer to the hint). • The bond energy of X, is BE = 217 kJ/mol. Determine the lattice energy of MX. AHjattice kJ/molarrow_forward
- Given the following information: Li(s) → Li(g) Li(s) = 161 kJ/mol Heat of sublimation of HCI(g) → H(g) + Cl(g) Bond energy of HCI = 427 kJ/mol Li(g) → Li+(g) + e- lonization energy of Li(g) = 520. kJ/mol CI(g) + e- → CI-(g) Electron affinity of Cl(g) = -349 kJ/mol Li+(g) + Cl-(g) →→ LiC(s) Lattice energy of LİCI(s) = -829 kJ/mol H2(g) → 2H(g) Bond energy of H2 = 432 kJ/mol calculate the net change in energy for the reaction 2Li(s) + 2HCI(g) → 2LİCI(s) + H2(g) -179 kJ 362 kJ -70 kJ -572 kJ None esearrow_forwardGiven the following information, construct a Born-Haber cycle to calculate the lattice energy of CrCl₂I(s): Net energy change for the formation of CrCl₂I(s) = -420 kJ/mol Bond dissociation energy for I2(g) = +243 kJ/mol Bond dissociation energy for Cl2(g) for Cl2(g) for 12(g) = +151 kJ/mol Heat of sublimation for I2(s) = +62 kJ/mol Heat of sublimation for Cr(s) = +397 kJ/mol = E₁₁ for Cr(g) = 652 kJ/mol E₁₂ for Cr(g) == 1588 kJ/mol E₁3 for Cr(g) = 2882 kJ/mol Eea for Cl(g)=-349 kJ/mol === Eea for I(g) = -295 kJ/molarrow_forwardConsider an ionic compound, MX₂, composed of generic metal M and generic, gaseous halogen X. • The enthalpy of formation of MX₂ is AH; = -905 kJ/mol. • The enthalpy of sublimation of M is AHsub = 111 kJ/mol. • The first and second ionization energies of M are IE₁ = 627 kJ/mol and IE₂ = 1362 kJ/mol. • The electron affinity of X is AHEA = -313 kJ/mol. (Refer to the hint). • The bond energy of X₂ is BE = 165 kJ/mol. Determine the lattice energy of MX₂. AH lattice = kJ/molarrow_forward
- Write the equations for the Born-Haber cycle for MgO(s) and use a Born-Häber cycle to calculate the electron affinity to O(g) to form O2-(g). DeltaHf of MgO(s) = -602 kJ/mol; DeltaHvap of Mg = 150.2 kJ/mol; DeltaHdiss of O2 497.4kJ/mol; DeltaHion(1) + DHion(2) for Mg = 2188 kJ/mol.arrow_forwardConsider an ionic compound, MX3, composed of generic metal M and generic gaseous halogen X. • The enthalpy of formation of MX3 is AH; = -885 kJ/mol. • The enthalpy of sublimation of M is AH sub = 121 kJ/mol. • The first, second, and third ionization energies of M are IE₁ = 649 kJ/mol, IE2 = 1635 kJ/mol, and IE3 = 2689 kJ/mol. • The electron affinity of X is AHEA = -319 kJ/mol. (Refer to the hint). • The bond energy of X₂ is BE = 191 kJ/mol. Determine the lattice energy of MX3. ΔΗ kJ/mol = latticearrow_forwardConsider an ionic compound, MX, composed of generic metal M and generic, gaseous halogen X. • The enthalpy of formation of MX is AH; = -517 kJ/mol. • The enthalpy of sublimation of M is AHub 141 kJ/mol. • The ionization energy of M is IE = 449 kJ/mol. • The electron affinity of X is AHEA = -323 kJ/mol. (Refer to the hint). • The bond energy of X, is BE = 217 kJ/mol. Determine the lattice energy of MX. -33 AHjattice kJ/mol Incorrectarrow_forward
- Use the data provided below to calculate the lattice energy of RbCl. Is this value greater or less than thelattice energy of NaCl? Explain.Electron affinity of Cl = –349 kJ/mol1st ionization energy of Rb = 403 kJ/molBond energy of Cl2 = 242 kJ/molSublimation energy of Rb = 86.5 kJ/molΔHf [RbCl (s)] = –430.5 kJ/molarrow_forwardConsider an ionic compound, MX₂, composed of generic metal M and generic, gaseous halogen X. • The enthalpy of formation of MX, is AH; = -895 kJ/mol. • The enthalpy of sublimation of M is AH, sub = 153 kJ/mol. • The first and second ionization energies of M are IE₁ = 659 kJ/mol and IE₂ = 1438 kJ/mol. The electron affinity of X is AHEA=-313 kJ/mol. (Refer to the hint.) • The bond energy of X₂ is BE 197 kJ/mol. Determine the lattice energy of MX₂. AH lattice = -2416 Incorrect kJ/molarrow_forwardConsider the following data for osmium: atomic mass electronegativity electron affinity ionization energy heat of fusion 190.23 106.1 2.20 840. 31. g mol (1) Os (g) → Os (g) + e kJ mol kJ mol You may find additional useful data in the ALEKS Data tab. kJ mol Does the following reaction absorb or release energy? + (2) Os (g) + e → Os (g) Is it possible to calculate the amount of energy absorbed or released by reaction (1) using only the data above? If you answered yes to the previous question, enter the amount of energy absorbed or released by reaction (1): Does the following reaction absorb or release energy? Is it possible to calculate the amount of energy absorbed or released by reaction (2) using only the data above? If you answered yes to the previous question, enter the amount of energy absorbed or released by reaction (2): release absorb Can't be decided with the data given. yes no kJ/mol release absorb Can't be decided with the data given. yes no kJ/molarrow_forward
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