Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical. Concept Introduction : Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

Question

Want to see the full answer?

Answer 1

Question

Chapter 8.3, Problem 4E

(a)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(b)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(c)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(d)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(e)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compound is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(f)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

ClCH2CH2CH2Cl

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compound is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(g)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compound is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(h)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(i)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(j)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Predict what you expect to observe in the EPRspectrum of a species in which an unpaired electroninteracts with one 14N nucleus (I = 1) and one 1Hnucleus (I = 1/2) if the hyperfine coupling constantsare (a) A(14N) = A(1H)=30 G; (b) A(14N)= 30 G,A(1H)= 10 G.

Under which conditions (Δ, hϒ) 1,5- and 1,3- sigmatropic shifts takes place and why? Elaborate with the help of orbital analysis.

Predict 31PNMR spectrum of cis-[Pt(PR3)2Cl2]. Given that phosphorus-31 (100% abundant), platinum-95 (33% abundant), all have a nuclear spin quantum numbers of (I = ½)

Answer 2

Question

Chapter 8.3, Problem 4E

(a)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(b)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(c)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(d)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(e)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compound is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(f)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

ClCH2CH2CH2Cl

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compound is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(g)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compound is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(h)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(i)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(j)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 8.3, Problem 4E

(a)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(b)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(c)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(d)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(e)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compound is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(f)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

ClCH2CH2CH2Cl

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compound is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(g)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compound is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(h)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(i)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(j)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 8.3, Problem 4E

(a)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(b)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(c)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(d)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(e)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compound is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(f)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

ClCH2CH2CH2Cl

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compound is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(g)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compound is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(h)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(i)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(j)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 8.3, Problem 4E

(a)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(b)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(c)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(d)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(e)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compound is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(f)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

ClCH2CH2CH2Cl

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compound is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(g)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compound is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(h)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(i)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

(j)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

Answer 6

Chapter 8.3, Problem 4E

(a)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

Answer 7

Chapter 8.3, Problem 4E

(a)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

Answer 14

(e)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compound is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

Answer 15

(e)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compound is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

Answer 16

(f)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

ClCH2CH2CH2Cl

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compound is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

Answer 17

(f)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

ClCH2CH2CH2Cl

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compound is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

Answer 18

(g)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compound is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

Answer 19

(g)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compound is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

Answer 20

(h)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

Answer 21

(h)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

Answer 22

(i)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

Answer 23

(i)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

Answer 24

(j)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

Answer 25

(j)

Interpretation Introduction

Interpretation:

Whether the given compound is homotopic, enantiotopic or diastereotopic needs to be predicted and the chemical shifts in ( and its splitting patterns based on the hydrogen present needs to be determined, assuming that the coupling constant of all the neighboring atoms is identical.

Concept Introduction :

Compound is homotopic, if molecule has same elements which when interchanged is the same. Compound is enantiotopic, if the two groups in the molecule when replaced generates achiral compound and the resulting products formed are enantiomers. Compund is diasterotopic if the two groups in molecule when replaced would generate compounds which are diastereomers.

Answer 26

Expert Solution & Answer

Answer 27

Expert Solution & Answer

Answer 28

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 29

Ch. 8.2 - Prob. 1E Ch. 8.2 - Prob. 2E Ch. 8.2 - Prob. 3E Ch. 8.2 - Prob. 4E Ch. 8.2 - Prob. 5E Ch. 8.2 - Prob. 6E Ch. 8.2 - Prob. 7E Ch. 8.2 - Prob. 8E Ch. 8.2 - Prob. 9E Ch. 8.2 - Prob. 10E

Solution Summary: The author explains that a compound is homotopic and enantiotopic if it has the same elements and chemical shift values.

Want to see the full answer?

Chapter 8 Solutions