General Chemistry: Atoms First
General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Chapter 10.1, Problem 10.3CP
Interpretation Introduction

Interpretation:

With the help of arrows, the direction in which the electrons are displaced in Methanol has to be indicated.

Concept Introduction:

Dipole moment:

Dipole moment is quantity that is used to measure net molecular polarity. It is represented as μ, and can be defined as magnitude of charge Q present at either end of specific dipole times the distance r seen between the charges.  The dipole moment is expressed using formula,

μ = Q × r

Debye is the unit of dipole moment.

One Debye is equal to 3.336×10-30coulombmeters(c.m) in S.I units.

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The molecule AX2, where A and X are different elements that form polar covalent bonds, will have a dipole moment if the molecule is linear. true or false?
The ammonia molecule (NH3) has three identical polar N-H bonds that are equally spaced around the nitrogen atom. Ammonia has a net dipole moment of 1.4 D, similar to that of water 1.85 D). Based on this information, do you think ammonia is a planer molecule or not? Briefly justify your response.
Molecules can be polar because of the unsymmetrical distribution of electrons. The dipole moment, μ Q r μ=Q×r The SI unit of dipole moment is the coulomb-meter (C⋅m), but another common unit is the debye (D). The two are related as 3.336×10^−30 C⋅m=1 D The percent ionic character is a comparison of the measured dipole moment of the bond to the expected dipole moment if electrons are instead transferred: %ionic character=measured dipole/if electrons transferred×100% The dipole moment if electrons are completely transferred is one for which a full unit of charge (1.60×10^−19 C) exists on each end of the bond. The dipole measured for HI is 0.380 D. The bond distance is 161 pm. What is the percent ionic character of the HI bond? Express your answer as a percent to three significant figures.   Describe the molecular dipole of OCl2.

Chapter 10 Solutions

General Chemistry: Atoms First

Ch. 10.8 - Prob. 10.11PCh. 10.8 - Prob. 10.12PCh. 10.8 - Prob. 10.13PCh. 10.8 - Prob. 10.14CPCh. 10.9 - Prob. 10.15PCh. 10.9 - Prob. 10.16CPCh. 10.11 - Prob. 10.17PCh. 10.11 - Prob. 10.18PCh. 10.11 - Prob. 10.19CPCh. 10.11 - Prob. 10.20PCh. 10.11 - Prob. 10.21PCh. 10 - Prob. 10.22CPCh. 10 - Prob. 10.23CPCh. 10 - Zinc sulfide, or sphalerite, crystallizes in the...Ch. 10 - Perovskite, a mineral containing calcium, oxygen,...Ch. 10 - Prob. 10.26CPCh. 10 - Prob. 10.27CPCh. 10 - Prob. 10.28CPCh. 10 - Prob. 10.30CPCh. 10 - Prob. 10.31CPCh. 10 - Why dont all molecules with polar covalent bonds...Ch. 10 - Prob. 10.33SPCh. 10 - Prob. 10.34SPCh. 10 - Prob. 10.35SPCh. 10 - Methanol (CH3OH; bp = 65 C) boils nearly 230 C...Ch. 10 - Prob. 10.37SPCh. 10 - Which of the following substances would you expect...Ch. 10 - Prob. 10.39SPCh. 10 - Prob. 10.40SPCh. 10 - The dipole moment of ClF is 0.887 D and the...Ch. 10 - Prob. 10.42SPCh. 10 - Prob. 10.43SPCh. 10 - The class of ions PtX42, where X is a halogen, has...Ch. 10 - Prob. 10.45SPCh. 10 - Prob. 10.46SPCh. 10 - Prob. 10.47SPCh. 10 - Prob. 10.48SPCh. 10 - Prob. 10.49SPCh. 10 - Prob. 10.50SPCh. 10 - Prob. 10.51SPCh. 10 - Mercury has mp = 38.8 C and bp = 356.6 C. What, if...Ch. 10 - Prob. 10.53SPCh. 10 - Prob. 10.54SPCh. 10 - Prob. 10.55SPCh. 10 - Prob. 10.56SPCh. 10 - Prob. 10.57SPCh. 10 - Prob. 10.58SPCh. 10 - How much energy in kilojoules is released when...Ch. 10 - Draw a molar heating curve for ethanol, C2H5OH,...Ch. 10 - Prob. 10.61SPCh. 10 - Prob. 10.62SPCh. 10 - Prob. 10.63SPCh. 10 - Prob. 10.64SPCh. 10 - Prob. 10.65SPCh. 10 - Prob. 10.66SPCh. 10 - Prob. 10.67SPCh. 10 - Prob. 10.68SPCh. 10 - Prob. 10.69SPCh. 10 - Prob. 10.70SPCh. 10 - Prob. 10.71SPCh. 10 - Prob. 10.72SPCh. 10 - Prob. 10.73SPCh. 10 - Prob. 10.74SPCh. 10 - Prob. 10.75SPCh. 10 - Prob. 10.76SPCh. 10 - Which of the substances diamond, Hg, Cl2, glass,...Ch. 10 - Prob. 10.78SPCh. 10 - Prob. 10.79SPCh. 10 - Prob. 10.80SPCh. 10 - Prob. 10.81SPCh. 10 - Prob. 10.82SPCh. 10 - Prob. 10.83SPCh. 10 - Prob. 10.84SPCh. 10 - Prob. 10.85SPCh. 10 - Prob. 10.86SPCh. 10 - Prob. 10.87SPCh. 10 - Prob. 10.88SPCh. 10 - Sodium has a density of 0.971 g/cm3 and...Ch. 10 - Prob. 10.90SPCh. 10 - Prob. 10.91SPCh. 10 - Prob. 10.92SPCh. 10 - Prob. 10.93SPCh. 10 - Prob. 10.94SPCh. 10 - Prob. 10.95SPCh. 10 - Look at the phase diagram of CO2 in Figure 10.29,...Ch. 10 - Prob. 10.97SPCh. 10 - Prob. 10.98SPCh. 10 - Prob. 10.99SPCh. 10 - Prob. 10.100SPCh. 10 - Prob. 10.101SPCh. 10 - Does solid oxygen (Problem 10.99) melt when...Ch. 10 - Prob. 10.103SPCh. 10 - Prob. 10.104SPCh. 10 - Prob. 10.105SPCh. 10 - Prob. 10.106SPCh. 10 - Prob. 10.107SPCh. 10 - Prob. 10.108CHPCh. 10 - Prob. 10.109CHPCh. 10 - Prob. 10.110CHPCh. 10 - Prob. 10.111CHPCh. 10 - Prob. 10.112CHPCh. 10 - Prob. 10.113CHPCh. 10 - Prob. 10.114CHPCh. 10 - Prob. 10.115CHPCh. 10 - Magnesium metal has Hfusion = 9.037 kJ/mol and...Ch. 10 - Prob. 10.117CHPCh. 10 - Prob. 10.118CHPCh. 10 - Prob. 10.119CHPCh. 10 - Prob. 10.120CHPCh. 10 - Prob. 10.121CHPCh. 10 - Prob. 10.122CHPCh. 10 - Prob. 10.123CHPCh. 10 - Calculate the percent volume occupied by the...Ch. 10 - Prob. 10.125CHPCh. 10 - Prob. 10.126CHPCh. 10 - Prob. 10.127CHPCh. 10 - A drawing of the NaCl unit cell is shown in Figure...Ch. 10 - Niobium oxide crystallizes in the following cubic...Ch. 10 - Prob. 10.130CHPCh. 10 - One form of silver telluride (Ag2Te) crystallizes...Ch. 10 - Prob. 10.132CHPCh. 10 - Prob. 10.133MPCh. 10 - Prob. 10.134MPCh. 10 - A group 3A metal has a density of 2.70 g/cm3 and a...Ch. 10 - Prob. 10.136MP
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