The major product, when the given amine undergoes exhaustive methylation, treatment with Ag 2 O , and heating is to be predicted. Concept introduction: Hofmann elimination reactions comprise the conversion of an amine into an alkene . The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

Question

The hydrolysis of an amide in acidic conditions forms A. a carboxylate salt and an alcohol B. a carboxylate salt and an amine C. an alcohol and an amine salt (an ammonium ion) D. a carboxylic acid and an amine salt (an ammonium ion)

Answer 1

Question

Chapter 19.14, Problem 19.20P

(a)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(b)

Interpretation Introduction

Interpretation:

The formation of major product, when the given amine undergo exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(c)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(d)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(e)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(f)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

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The hydrolysis of an amide in acidic conditions forms A. a carboxylate salt and an alcohol B. a carboxylate salt and an amine C. an alcohol and an amine salt (an ammonium ion) D. a carboxylic acid and an amine salt (an ammonium ion)

Erythronolide B is the biological precursor of erythromycin, a broad-spectrum antibiotic. What functional group Erythronolide B does contain? a. b. H₂CH₂C C. H₂C 1 H₂C 2 3 4 O Amide d. Amine OH Erythronolide B Ketone Aldehyde a CH₂ b C d CH₂ OH JCH₂ 'OH OH

Which of the following statements is INCORRECT? a. Amines are electrophilic. Amines are stronger bases than alcohols, ethers, or water. Nitrogen atom is sp³-hybridized and is tetrahedral in shape. Solubility of amines decreases with increasing number of carbons. O b. O C. O d.

Answer 2

Question

Chapter 19.14, Problem 19.20P

(a)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(b)

Interpretation Introduction

Interpretation:

The formation of major product, when the given amine undergo exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(c)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(d)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(e)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(f)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

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Answer 3

Question

Chapter 19.14, Problem 19.20P

(a)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(b)

Interpretation Introduction

Interpretation:

The formation of major product, when the given amine undergo exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(c)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(d)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(e)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(f)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

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Answer 4

Question

Chapter 19.14, Problem 19.20P

(a)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(b)

Interpretation Introduction

Interpretation:

The formation of major product, when the given amine undergo exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(c)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(d)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(e)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(f)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

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Answer 5

Chapter 19.14, Problem 19.20P

(a)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(b)

Interpretation Introduction

Interpretation:

The formation of major product, when the given amine undergo exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(c)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(d)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(e)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(f)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

Answer 6

Chapter 19.14, Problem 19.20P

(a)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

Answer 7

Chapter 19.14, Problem 19.20P

(a)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The formation of major product, when the given amine undergo exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The formation of major product, when the given amine undergo exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

Answer 14

(e)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

Answer 15

(e)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

Answer 16

(f)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

Answer 17

(f)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

Answer 18

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Answer 19

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Answer 29

Ch. 19.2A - Prob. 19.1P Ch. 19.2B - Prob. 19.2P Ch. 19.2B - Give correct names for the following amines:Ch. 19.3 - Prob. 19.4P Ch. 19.4 - Prob. 19.5P Ch. 19.6 - Rank each set of compounds in order of increasing...Ch. 19.8A - Prob. 19.7P Ch. 19.8C - Prob. 19.8P Ch. 19.8C - Prob. 19.9P Ch. 19.8D - a. Show how fragmentation occurs to give the base...

Solution Summary: The author explains how Hofmann elimination reactions comprise the conversion of an amine into an alkene.

Chapter 19 Solutions