The name has to be given for the reactant ( C 3 H 7 OH ). Concept Introduction: Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts, namely Prefix, suffix and root word. Prefix - Represents the substituent present in the molecule and its position in the root name. Suffix - Denotes the presence of functional group if any in the molecule. It can be an alkene , alkyne , alcohol, carboxylic acid , alcohol etc. To add suffix to name a compound, the suffix “-ane” in the parent alkane is replaced by the respective suffix, which corresponds to the functional group present in the given compound. For carboxylic acid, suffix “-oic” will be added, for alcohol, suffix “-ol” will be added and so on Root word - Represents the longest continuous carbon skeleton of the organic molecule.

Question

Classify each of the following reactions as an addition, elimination, substitution, or rearrangement. (a) CH3B + KOH → CH3OH + KBr (b) CH3CH2Br — Н2С—СH2 + HBr (c) H2C=CH2 + H2 → CH3CH3

Answer 1

Question

Chapter 23, Problem 104IL

(a)

Interpretation Introduction

Interpretation:

The name has to be given for the reactant (C3H7OH).

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix- Denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc. To add suffix to name a compound, the suffix “-ane” in the parent alkane is replaced by the respective suffix, which corresponds to the functional group present in the given compound. For carboxylic acid, suffix “-oic” will be added, for alcohol, suffix “-ol” will be added and so on

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

(b)

Interpretation Introduction

Interpretation:

The structure of the isomer has to be drawn and the name has to be given

Concept Introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

(c)

Interpretation Introduction

Interpretation:

The name of product is to be identified in reaction A.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix- Denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc. To add suffix to name a compound, the suffix “-ane” in the parent alkane is replaced by the respective suffix, which corresponds to the functional group present in the given compound. For carboxylic acid, suffix “-oic” will be added, for alcohol, suffix “-ol” will be added and so on

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

(d)

Interpretation Introduction

Interpretation:

The name of product is to be identified in reaction B.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix- Denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc. To add suffix to name a compound, the suffix “-ane” in the parent alkane is replaced by the respective suffix, which corresponds to the functional group present in the given compound. For carboxylic acid, suffix “-oic” will be added, for alcohol, suffix “-ol” will be added and so on

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

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Classify each of the following reactions as an addition, elimination, substitution, or rearrangement. (a) CH3B + KOH → CH3OH + KBr (b) CH3CH2Br — Н2С—СH2 + HBr (c) H2C=CH2 + H2 → CH3CH3

(i) Draw the structural formula of compounds L, M, N and P (ii) Name the type of chemical reaction for the formation of compound N.

(1) Write a complete chemical equation showing reactants, products, and catalysts needed (if any) for the following reaction and (2) Draw and name the organic compound found in every reaction. (a) Complete hydrogenation of 2-Methylhexa-1,5-diene (b) Complete halogenation (Br2) of 3-Ethyl-2,2-dimethylhept-3-ene (c) Reaction of (4E)-2.4-Dimethylhexa-1,4-diene with a mole of water (d) Reaction of cis-3,3-Dimethyl-4-propylocta-1,5-diene with two mole of HBr (e) Reaction of trans-1-Bromo-3-chlorocyclopentane with potassium hydroxide (f) Formation of Gilman reagent using isopropyl bromide (g) Ozonolysis of 3,3-Dimethyloct-4-yne (h) Complete halogenation (Cl2) of 3-Ethyl-5-methyl-1,6,8-decatriyne (i) Partial hydrogenation using Lindlar's Catalyst 2,2,5,5-Tetramethylhex-3-yne (i) Reaction of 3.4-Dimethylcyclodecyne with sodium amide

Answer 2

Question

Chapter 23, Problem 104IL

(a)

Interpretation Introduction

Interpretation:

The name has to be given for the reactant (C3H7OH).

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix- Denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc. To add suffix to name a compound, the suffix “-ane” in the parent alkane is replaced by the respective suffix, which corresponds to the functional group present in the given compound. For carboxylic acid, suffix “-oic” will be added, for alcohol, suffix “-ol” will be added and so on

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

(b)

Interpretation Introduction

Interpretation:

The structure of the isomer has to be drawn and the name has to be given

Concept Introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

(c)

Interpretation Introduction

Interpretation:

The name of product is to be identified in reaction A.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix- Denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc. To add suffix to name a compound, the suffix “-ane” in the parent alkane is replaced by the respective suffix, which corresponds to the functional group present in the given compound. For carboxylic acid, suffix “-oic” will be added, for alcohol, suffix “-ol” will be added and so on

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

(d)

Interpretation Introduction

Interpretation:

The name of product is to be identified in reaction B.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix- Denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc. To add suffix to name a compound, the suffix “-ane” in the parent alkane is replaced by the respective suffix, which corresponds to the functional group present in the given compound. For carboxylic acid, suffix “-oic” will be added, for alcohol, suffix “-ol” will be added and so on

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

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Answer 3

Question

Chapter 23, Problem 104IL

(a)

Interpretation Introduction

Interpretation:

The name has to be given for the reactant (C3H7OH).

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix- Denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc. To add suffix to name a compound, the suffix “-ane” in the parent alkane is replaced by the respective suffix, which corresponds to the functional group present in the given compound. For carboxylic acid, suffix “-oic” will be added, for alcohol, suffix “-ol” will be added and so on

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

(b)

Interpretation Introduction

Interpretation:

The structure of the isomer has to be drawn and the name has to be given

Concept Introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

(c)

Interpretation Introduction

Interpretation:

The name of product is to be identified in reaction A.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix- Denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc. To add suffix to name a compound, the suffix “-ane” in the parent alkane is replaced by the respective suffix, which corresponds to the functional group present in the given compound. For carboxylic acid, suffix “-oic” will be added, for alcohol, suffix “-ol” will be added and so on

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

(d)

Interpretation Introduction

Interpretation:

The name of product is to be identified in reaction B.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix- Denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc. To add suffix to name a compound, the suffix “-ane” in the parent alkane is replaced by the respective suffix, which corresponds to the functional group present in the given compound. For carboxylic acid, suffix “-oic” will be added, for alcohol, suffix “-ol” will be added and so on

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

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Answer 4

Question

Chapter 23, Problem 104IL

(a)

Interpretation Introduction

Interpretation:

The name has to be given for the reactant (C3H7OH).

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix- Denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc. To add suffix to name a compound, the suffix “-ane” in the parent alkane is replaced by the respective suffix, which corresponds to the functional group present in the given compound. For carboxylic acid, suffix “-oic” will be added, for alcohol, suffix “-ol” will be added and so on

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

(b)

Interpretation Introduction

Interpretation:

The structure of the isomer has to be drawn and the name has to be given

Concept Introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

(c)

Interpretation Introduction

Interpretation:

The name of product is to be identified in reaction A.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix- Denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc. To add suffix to name a compound, the suffix “-ane” in the parent alkane is replaced by the respective suffix, which corresponds to the functional group present in the given compound. For carboxylic acid, suffix “-oic” will be added, for alcohol, suffix “-ol” will be added and so on

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

(d)

Interpretation Introduction

Interpretation:

The name of product is to be identified in reaction B.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix- Denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc. To add suffix to name a compound, the suffix “-ane” in the parent alkane is replaced by the respective suffix, which corresponds to the functional group present in the given compound. For carboxylic acid, suffix “-oic” will be added, for alcohol, suffix “-ol” will be added and so on

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

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Answer 5

Chapter 23, Problem 104IL

(a)

Interpretation Introduction

Interpretation:

The name has to be given for the reactant (C3H7OH).

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix- Denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc. To add suffix to name a compound, the suffix “-ane” in the parent alkane is replaced by the respective suffix, which corresponds to the functional group present in the given compound. For carboxylic acid, suffix “-oic” will be added, for alcohol, suffix “-ol” will be added and so on

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

(b)

Interpretation Introduction

Interpretation:

The structure of the isomer has to be drawn and the name has to be given

Concept Introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

(c)

Interpretation Introduction

Interpretation:

The name of product is to be identified in reaction A.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix- Denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc. To add suffix to name a compound, the suffix “-ane” in the parent alkane is replaced by the respective suffix, which corresponds to the functional group present in the given compound. For carboxylic acid, suffix “-oic” will be added, for alcohol, suffix “-ol” will be added and so on

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

(d)

Interpretation Introduction

Interpretation:

The name of product is to be identified in reaction B.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix- Denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc. To add suffix to name a compound, the suffix “-ane” in the parent alkane is replaced by the respective suffix, which corresponds to the functional group present in the given compound. For carboxylic acid, suffix “-oic” will be added, for alcohol, suffix “-ol” will be added and so on

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

Answer 6

Chapter 23, Problem 104IL

(a)

Interpretation Introduction

Interpretation:

The name has to be given for the reactant (C3H7OH).

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix- Denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc. To add suffix to name a compound, the suffix “-ane” in the parent alkane is replaced by the respective suffix, which corresponds to the functional group present in the given compound. For carboxylic acid, suffix “-oic” will be added, for alcohol, suffix “-ol” will be added and so on

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

Answer 7

Chapter 23, Problem 104IL

(a)

Interpretation Introduction

Interpretation:

The name has to be given for the reactant (C3H7OH).

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix- Denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc. To add suffix to name a compound, the suffix “-ane” in the parent alkane is replaced by the respective suffix, which corresponds to the functional group present in the given compound. For carboxylic acid, suffix “-oic” will be added, for alcohol, suffix “-ol” will be added and so on

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The structure of the isomer has to be drawn and the name has to be given

Concept Introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The structure of the isomer has to be drawn and the name has to be given

Concept Introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The name of product is to be identified in reaction A.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix- Denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc. To add suffix to name a compound, the suffix “-ane” in the parent alkane is replaced by the respective suffix, which corresponds to the functional group present in the given compound. For carboxylic acid, suffix “-oic” will be added, for alcohol, suffix “-ol” will be added and so on

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The name of product is to be identified in reaction A.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix- Denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc. To add suffix to name a compound, the suffix “-ane” in the parent alkane is replaced by the respective suffix, which corresponds to the functional group present in the given compound. For carboxylic acid, suffix “-oic” will be added, for alcohol, suffix “-ol” will be added and so on

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The name of product is to be identified in reaction B.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix- Denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc. To add suffix to name a compound, the suffix “-ane” in the parent alkane is replaced by the respective suffix, which corresponds to the functional group present in the given compound. For carboxylic acid, suffix “-oic” will be added, for alcohol, suffix “-ol” will be added and so on

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The name of product is to be identified in reaction B.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix- Denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc. To add suffix to name a compound, the suffix “-ane” in the parent alkane is replaced by the respective suffix, which corresponds to the functional group present in the given compound. For carboxylic acid, suffix “-oic” will be added, for alcohol, suffix “-ol” will be added and so on

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

Answer 14

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Ch. 23.2 - (a) Draw the nine isomers having the formula...Ch. 23.2 - Prob. 23.2CYU Ch. 23.2 - There are 17 possible alkene isomers with the...Ch. 23.2 - Prob. 23.4CYU Ch. 23.2 - Aniline, C6H5NH2, is the common name for...Ch. 23.3 - Draw the structure of 1-butanol and alcohols that...Ch. 23.4 - (a) Name each of the following compounds and its...Ch. 23.5 - Kevlar is a well-known polymer that is now used to...Ch. 23.5 - Prob. 1.1ACP Ch. 23.5 - Prob. 1.2ACP

Concept explainers

Interpretation:

The structure of the isomer has to be drawn and the name has to be given

Concept Introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Chapter 23 Solutions

Concept explainers

Interpretation: The structure of the isomer has to be drawn and the name has to be given Concept Introduction: Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Chapter 23 Solutions

Interpretation:

The structure of the isomer has to be drawn and the name has to be given

Concept Introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.