Organic Chemistry: Principles and Mechanisms (Second Edition)
Organic Chemistry: Principles and Mechanisms (Second Edition)
2nd Edition
ISBN: 9780393663556
Author: Joel Karty
Publisher: W. W. Norton & Company
Question
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Chapter 9, Problem 9.68P
Interpretation Introduction

(a)

Interpretation:

For the given substrate, when NaOH is used as the base, the major E2 product is to be drawn.

Concept introduction:

In an E2 reaction, the base pulls off the proton from the substrate, thus forcing the leaving group to leave. Elimination usually takes place so as to produce the most stable, meaning highly alkyl substituted, alkene. The major elimination product is the one produced by deprotonating the carbon atom initially attached to the fewest hydrogen atoms.

Interpretation Introduction

(b)

Interpretation:

For the given substrate, when NaOH is used as the base, the major E2 product is to be drawn.

Concept introduction:

In an E2 reaction, the base pulls off the proton from the substrate, thus forcing the leaving group to leave. Elimination usually takes place so as to produce the most stable, meaning highly alkyl substituted, alkene. The major elimination product is the one produced by deprotonating the carbon atom initially attached to the fewest hydrogen atoms. In a ring with limited rotation, the leaving group has to be trans to the proton.

Interpretation Introduction

(c)

Interpretation:

For the given substrate, when NaOH is used as the base, the major E2 product is to be drawn.

Concept introduction:

In an E2 reaction, the base pulls off the proton from the substrate, thus forcing the leaving group to leave. Elimination usually takes place so as to produce the most stable, meaning highly alkyl substituted, alkene. The major elimination product is the one produced by deprotonating the carbon atom initially attached to the fewest hydrogen atoms. In a ring with limited rotation, the leaving group has to be trans to the proton.

Interpretation Introduction

(d)

Interpretation:

For the given substrate, when NaOH is used as the base, the major E2 product is to be drawn.

Concept introduction:

In an E2 reaction, the base pulls off the proton from the substrate, thus forcing the leaving group to leave. Elimination usually takes place so as to produce the most stable, meaning highly alkyl substituted, alkene. The major elimination product is the one produced by deprotonating the carbon atom initially attached to the fewest hydrogen atoms. In a ring with limited rotation, the leaving group has to be trans to the proton.

Interpretation Introduction

(e)

Interpretation:

For the given substrate, when NaOH is used as the base, the major E2 product is to be drawn.

Concept introduction:

In an E2 reaction, the base pulls off the proton from the substrate, thus forcing the leaving group to leave. Elimination usually takes place so as to produce the most stable, meaning highly alkyl substituted, alkene. The major elimination product is the one produced by deprotonating the carbon atom initially attached to the fewest hydrogen atoms. In a ring with limited rotation, the leaving group has to be trans to the proton.

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Chapter 9 Solutions

Organic Chemistry: Principles and Mechanisms (Second Edition)

Ch. 9 - Prob. 9.11PCh. 9 - Prob. 9.12PCh. 9 - Prob. 9.13PCh. 9 - Prob. 9.14PCh. 9 - Prob. 9.15PCh. 9 - Prob. 9.16PCh. 9 - Prob. 9.17PCh. 9 - Prob. 9.18PCh. 9 - Prob. 9.19PCh. 9 - Prob. 9.20PCh. 9 - Prob. 9.21PCh. 9 - Prob. 9.22PCh. 9 - Prob. 9.23PCh. 9 - Prob. 9.24PCh. 9 - Prob. 9.25PCh. 9 - Prob. 9.26PCh. 9 - Prob. 9.27PCh. 9 - Prob. 9.28PCh. 9 - Prob. 9.29PCh. 9 - Prob. 9.30PCh. 9 - Prob. 9.31PCh. 9 - Prob. 9.32PCh. 9 - Prob. 9.33PCh. 9 - Prob. 9.34PCh. 9 - Prob. 9.35PCh. 9 - Prob. 9.36PCh. 9 - Prob. 9.37PCh. 9 - Prob. 9.38PCh. 9 - Prob. 9.39PCh. 9 - Prob. 9.40PCh. 9 - Prob. 9.41PCh. 9 - Prob. 9.42PCh. 9 - Prob. 9.43PCh. 9 - Prob. 9.44PCh. 9 - Prob. 9.45PCh. 9 - Prob. 9.46PCh. 9 - Prob. 9.47PCh. 9 - Prob. 9.48PCh. 9 - Prob. 9.49PCh. 9 - Prob. 9.50PCh. 9 - Prob. 9.51PCh. 9 - Prob. 9.52PCh. 9 - Prob. 9.53PCh. 9 - Prob. 9.54PCh. 9 - Prob. 9.55PCh. 9 - Prob. 9.56PCh. 9 - Prob. 9.57PCh. 9 - Prob. 9.58PCh. 9 - Prob. 9.59PCh. 9 - Prob. 9.60PCh. 9 - Prob. 9.61PCh. 9 - Prob. 9.62PCh. 9 - Prob. 9.63PCh. 9 - Prob. 9.64PCh. 9 - Prob. 9.65PCh. 9 - Prob. 9.66PCh. 9 - Prob. 9.67PCh. 9 - Prob. 9.68PCh. 9 - Prob. 9.69PCh. 9 - Prob. 9.70PCh. 9 - Prob. 9.71PCh. 9 - Prob. 9.72PCh. 9 - Prob. 9.73PCh. 9 - Prob. 9.74PCh. 9 - Prob. 9.75PCh. 9 - Prob. 9.76PCh. 9 - Prob. 9.77PCh. 9 - Prob. 9.78PCh. 9 - Prob. 9.79PCh. 9 - Prob. 9.80PCh. 9 - Prob. 9.81PCh. 9 - Prob. 9.82PCh. 9 - Prob. 9.83PCh. 9 - Prob. 9.84PCh. 9 - Prob. 9.1YTCh. 9 - Prob. 9.2YTCh. 9 - Prob. 9.3YTCh. 9 - Prob. 9.4YTCh. 9 - Prob. 9.5YTCh. 9 - Prob. 9.6YTCh. 9 - Prob. 9.7YTCh. 9 - Prob. 9.8YTCh. 9 - Prob. 9.9YTCh. 9 - Prob. 9.10YTCh. 9 - Prob. 9.11YTCh. 9 - Prob. 9.12YTCh. 9 - Prob. 9.13YTCh. 9 - Prob. 9.14YTCh. 9 - Prob. 9.15YT