Organic Chemistry: Principles and Mechanisms (Second Edition)
Organic Chemistry: Principles and Mechanisms (Second Edition)
2nd Edition
ISBN: 9780393663556
Author: Joel Karty
Publisher: W. W. Norton & Company
Question
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Chapter 9, Problem 9.74P
Interpretation Introduction

(a)

Interpretation:

Considering the factor of charge stability, it is to be determined whether the given elementary step is reversible or irreversible.

Concept introduction:

The stability of charged species on both sides of a reaction decides if the products are more stable than the reactants or vice versa. A reaction is irreversible if it’s ΔG0rxn is negative i.e. if the products are much more stable than the reactants. Otherwise, the reaction tends to be reversible. In general, unstable reactants and stable products make the reaction irreversible. If the stability of reactants and products is comparable, then the reaction is said to be reversible. A proton transfer reaction is usually reversible.

Interpretation Introduction

(b)

Interpretation:

Considering the factor of charge stability, it is to be determined whether the given elementary step is reversible or irreversible.

Concept introduction:

The stability of charged species on both sides of a reaction decides if the products are more stable than the reactants or vice versa. A reaction is irreversible if it’s ΔG0rxn is negative i.e. if the products are much more stable than the reactants. Otherwise, the reaction tends to be reversible. In general, unstable reactants and stable products make the reaction irreversible. If the stability of reactants and products is comparable, then the reaction is said to be reversible.

Interpretation Introduction

(c)

Interpretation:

Considering the factor of charge stability, it is to be determined whether the given elementary step is reversible or irreversible.

Concept introduction:

The stability of charged species on both sides of a reaction decides if the products are more stable than the reactants or vice versa. A reaction is irreversible if it’s ΔG0rxn is negative i.e. if the products are much more stable than the reactants. Otherwise, the reaction tends to be reversible. In general, unstable reactants and stable products make the reaction irreversible. If the stability of reactants and products is comparable, then the reaction is said to be reversible.

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Chapter 9 Solutions

Organic Chemistry: Principles and Mechanisms (Second Edition)

Ch. 9 - Prob. 9.11PCh. 9 - Prob. 9.12PCh. 9 - Prob. 9.13PCh. 9 - Prob. 9.14PCh. 9 - Prob. 9.15PCh. 9 - Prob. 9.16PCh. 9 - Prob. 9.17PCh. 9 - Prob. 9.18PCh. 9 - Prob. 9.19PCh. 9 - Prob. 9.20PCh. 9 - Prob. 9.21PCh. 9 - Prob. 9.22PCh. 9 - Prob. 9.23PCh. 9 - Prob. 9.24PCh. 9 - Prob. 9.25PCh. 9 - Prob. 9.26PCh. 9 - Prob. 9.27PCh. 9 - Prob. 9.28PCh. 9 - Prob. 9.29PCh. 9 - Prob. 9.30PCh. 9 - Prob. 9.31PCh. 9 - Prob. 9.32PCh. 9 - Prob. 9.33PCh. 9 - Prob. 9.34PCh. 9 - Prob. 9.35PCh. 9 - Prob. 9.36PCh. 9 - Prob. 9.37PCh. 9 - Prob. 9.38PCh. 9 - Prob. 9.39PCh. 9 - Prob. 9.40PCh. 9 - Prob. 9.41PCh. 9 - Prob. 9.42PCh. 9 - Prob. 9.43PCh. 9 - Prob. 9.44PCh. 9 - Prob. 9.45PCh. 9 - Prob. 9.46PCh. 9 - Prob. 9.47PCh. 9 - Prob. 9.48PCh. 9 - Prob. 9.49PCh. 9 - Prob. 9.50PCh. 9 - Prob. 9.51PCh. 9 - Prob. 9.52PCh. 9 - Prob. 9.53PCh. 9 - Prob. 9.54PCh. 9 - Prob. 9.55PCh. 9 - Prob. 9.56PCh. 9 - Prob. 9.57PCh. 9 - Prob. 9.58PCh. 9 - Prob. 9.59PCh. 9 - Prob. 9.60PCh. 9 - Prob. 9.61PCh. 9 - Prob. 9.62PCh. 9 - Prob. 9.63PCh. 9 - Prob. 9.64PCh. 9 - Prob. 9.65PCh. 9 - Prob. 9.66PCh. 9 - Prob. 9.67PCh. 9 - Prob. 9.68PCh. 9 - Prob. 9.69PCh. 9 - Prob. 9.70PCh. 9 - Prob. 9.71PCh. 9 - Prob. 9.72PCh. 9 - Prob. 9.73PCh. 9 - Prob. 9.74PCh. 9 - Prob. 9.75PCh. 9 - Prob. 9.76PCh. 9 - Prob. 9.77PCh. 9 - Prob. 9.78PCh. 9 - Prob. 9.79PCh. 9 - Prob. 9.80PCh. 9 - Prob. 9.81PCh. 9 - Prob. 9.82PCh. 9 - Prob. 9.83PCh. 9 - Prob. 9.84PCh. 9 - Prob. 9.1YTCh. 9 - Prob. 9.2YTCh. 9 - Prob. 9.3YTCh. 9 - Prob. 9.4YTCh. 9 - Prob. 9.5YTCh. 9 - Prob. 9.6YTCh. 9 - Prob. 9.7YTCh. 9 - Prob. 9.8YTCh. 9 - Prob. 9.9YTCh. 9 - Prob. 9.10YTCh. 9 - Prob. 9.11YTCh. 9 - Prob. 9.12YTCh. 9 - Prob. 9.13YTCh. 9 - Prob. 9.14YTCh. 9 - Prob. 9.15YT
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