Organic Chemistry
Organic Chemistry
6th Edition
ISBN: 9781936221349
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 5, Problem 5.10P
Interpretation Introduction

(a)

Interpretation:

The alkene and the method by which formation of given alcohol take place is to be predicted.

Concept introduction:

Oxymercuration-reduction is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Interpretation Introduction

(b)

Interpretation:

The alkene and the method by which formation of given alcohol take place is to be predicted.

Concept introduction:

Oxymercuration-reduction is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Interpretation Introduction

(c)

Interpretation:

The alkene and the method by which formation of given alcohol take place is to be predicted.

Concept introduction:

Oxymercuration-reduction is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

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(a) How will you convert:(i) Benzene to acetophenone                 (ii) Propanone to 2-Methylpropan-2-ol(b) Give reasons :(i) Electrophilic substitution in benzoic acid takes place at meta position.(ii) Carboxylic acids are higher boiling liquids than aldehydes, ketones and alcohols of comparable molecular masses.(iii) Propanal is more reactive than propanone in nucleophilic addition reactions.
The name of the parent six-membered sulfur-containing heterocycle is thiane. It is numbered beginning at sulfur. Multiple incorporation of sulfur in the ring is indicated by the prefixes di-, tri-, and so on. (a) How many methyl-substituted thianes are there? Which ones are chiral? (b) Write structural formulas for 1,4-dithiane and 1,3,5-trithiane. (c) Which dithiane isomer (1,2-, 1,3-, or 1,4-) is a disulfide?(d) Draw the two most stable conformations of the sulfoxide derived from thiane.
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