Organic Chemistry
Organic Chemistry
6th Edition
ISBN: 9781936221349
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 5, Problem 5.9P
Interpretation Introduction

(a)

Interpretation:

The alkene that is required for the formation of given alcohol is to be stated.

Concept introduction:

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Anti-Markovnikov’s rule states that the positive part of acid attached to that carbon atom in C=C bond which carries lesser number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has higher number of hydrogen atoms.

Interpretation Introduction

(b)

Interpretation:

The alkene that is required for the formation of given alcohol is to be stated.

Concept introduction:

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Anti-Markovnikov’s rule states that the positive part of acid attached to that carbon atom in C=C bond which carries lesser number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has higher number of hydrogen atoms.

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(a) When bromine is added to two beakers, one containing phenyl iso propyl ether and the other containing cyclohexene, the bromine color in both beakers disappears. What observation could you make while performing this test that would allow you to distinguish the alkene from the aryl ether? (b) Write any three methods in detail for the preparation of aldehyde from primary alcohol. (c) State the clemmenson reduction.
(A) Provide the major organic product for the reaction below (B) Would the product be optically active of optically in active?
Provide the reagents and solvents (where appropriate) needed to bring about the following transformations. (a) CI (b)
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